• Title/Summary/Keyword: polymer solution

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Flexural Behavior of Polymer Mortar Permanent Forms Using Methyl Methacrylate Solution of Waste Expanded Polystyrene

  • Bhutta, M. Aamer Rafique;Tsuruta, Ken;Ohama, Yoshihiko
    • International Journal of Concrete Structures and Materials
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    • v.2 no.1
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    • pp.35-39
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    • 2008
  • This experimental study examines the applicability of polymer mortar permanent forms using a methyl methacrylate (MMA) solution of waste expanded polystyrene (EPS) to develop effective recycling processes for the EPS, referring to the flexural behavior of a polymer-impregnated mortar permanent form with almost the same performance as commercial products. An MMA solution of EPS is prepared by dissolving EPS in MMA, and unreinforced and steel fiber-reinforced polymer mortars are mixed using the EPS-MMA-based solution as a liquid resin or binder. Polymer mortar permanent forms (PMPFs) using the EPS-MMA-based polymer mortars without and with steel fiber and crimped wire cloth reinforcements and steel fiber-reinforced polymer-impregnated mortar permanent form (PIMPF) are prepared on trial, and tested for flexural behavior under four-point (third-point) loading. The EPS-MMAbased PMPFs are more ductile than the PIMPF, and have a high load-bearing capacity. Consequently, they can replace PIMPF in practical applications.

A Theory of Polymer Adsorption from Solution

  • Lee, Woong-Ki;Pak, Hyung-Suk
    • Bulletin of the Korean Chemical Society
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    • v.8 no.1
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    • pp.19-26
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    • 1987
  • A statistical thermodynamical treatment for polymer adsorption from solution is presented. The canonical partition function for the polymer solution in the presence of a surface or an impermeable interface is formulated on the basis of usual quasi-crystalline lattice model, Bragg-Williams approximation of random mixing, and Pak's simple treatment of liquid. The present theory gives the surface excess ${\Gamma}_{exc}$ and the surface coverage ${\phi}^s_2$ of the polymer as a function of the chain length x, the Flory-Huggins parameter x, the adsorption energy parameter $x_s$, and polymer concentration $v_2$. Present theory is also applicable to the calculation of interfacial tension of polymer solution against water. For the idealized flexible polymer, interfacial tensions according to our theory fit good to the experimental data to the agreeable degrees.

SOLUTION CHARACTERISTICS AND MEMBRANE FORMATION OF PARTIALLY IMIDIZED POLY (AMIC ACID)

  • Lee, Hyuck-Jai;Won, Jong-Ok;Park, Hyun-Chae;Lee, Hoo-Sung;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.83-86
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    • 1999
  • The imidization effect of a poly (amic acid) dope solution on membrane formation has been investigated. Poly (amic acid) solution in S-methyl-2-pyrrolidione hs been thermally imidized at $120^{\circ}C$ with different curing time and its degree of imidization was determined by infrared spectroscopy. The solution properties have been studied as a function of concentration and curing time by dynamic light scattering. The quality of a solvent was changed from good to poor with increasing imidization of poly(amic acid).The reduced polymer-solvent interaction diminishes the membrane formation time. The morphology of a membrane was able to be controlled by the characteristics of dope solution.

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Evaluation of Early Strength of Red Clay Soil with Polymer Aqueous Solution (폴리머수용액을 첨가한 황토의 초기강도 평가)

  • Kim, Jin-Sung;Lee, Bo-Kyeong;Lee, Dong-Eun;Choi, Hyeong-Gil
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.145-146
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    • 2019
  • In this study, we evaluated the early strength of red clay soil with the polymer aqueous solution at rammed earth construction. In order to satisfy the demolding strength of the formwork be due to the rammed of red clay soil, the polymer aqueous solution was added to evaluate the compressive strength at the early age according to the consolidation level. As a result, a high compressive strength was exhibited with the formulation to which the polymer aqueous solution was added.

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Fluorescent Silk Fibroin Nanoparticles Prepared Using a Reverse Microemulsion

  • Myung, Seung-Jun;Kim, Hun-Sik;Kim, Yeseul;Chen, Peng;Jin, Hyoung-Joon
    • Macromolecular Research
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    • v.16 no.7
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    • pp.604-608
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    • 2008
  • Color dye-doped silk fibroin nanoparticles were successfully fabricated using a microemulsion method. An aqueous silk fibroin solution was prepared by dissolving cocoons (Bombyx mori) in a concentrated lithium bromide solution followed by dialysis. A color dye solution was also mixed with the aqueous silk fibroin solution. The surfactants used for the microemulsion were then removed by methanol and ethanol, yielding color dye-doped silk fibroin nanoparticles, approximately 167 nm in diameter. The secondary structure of the nanoparticles showed a $\beta$-sheet conformation, as characterized by Fourier transform infrared spectroscopy. The morphology of the nanoparticles was determined by field emission scanning electron microscopy, transmission electron microscopy and atomic force microscopy, and their size and size distribution were measured by dynamic light scattering. The color dye-doped silk fibroin nanoparticles were examined by confocal laser scanning microscopy.

Experimental Study on Frictional Drag Reduction of Turbulent Flow by Polymer Solution Injection (폴리머 수용액 주입에 의한 난류마찰저항 감소에 대한 실험 연구)

  • 김형태;김덕수;김우전
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.3
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    • pp.9-15
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    • 2003
  • An experimental study has been carried out as a basic research for development of the friction drag reduction technology for ships by polymer injection. Experimental apparatus and procedures have been devised and prepared to measure the changes of the wall friction with injection of a polymer solution and basic experimental data on the friction drag reduction are obtained for a turbulent fiat-plate boundary layer and fully-developed channel flows. Variations of the friction drag reduction with some important parameters of polymer injection, such as the concentration of polymer solution, its injection flow rate and the measuring position downstream from the injection slot, are also investigated. Important experimental data and results obtained in the present study are presented. The amount of friction drag reduction up to 50% is observed.

The Study on Drag Reduction Rates and Degradation Effects in Synthetic Polymer Solution with Surfactant Additives (계면활성제를 이용한 합성고분자 수용액의 마찰저항감소 및 퇴화 특성 향상 연구)

  • 이동민;김남진;윤석만;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.3
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    • pp.194-199
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    • 2001
  • The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

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Characterization of Associating Polymers in Solution

  • Sato, Takahiro
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.118-119
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    • 2006
  • The characterization method for associating polymer solutions was briefly reviewed. The method has not yet established in comparison with the characterization method for molecularly dispersed polymers in solution. However, two examples of associating polymer systems, living polybutadiene anions and amphiphilic statistical copolymers, were successfully characterized on the basis of suitable model and theory.

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Preparation of Polymer Composites Containing Gold Nanonetworks Using an Amphiphilic Poly(oxyethylene) Brush

  • Cha, Sang-Ho;Kim, Jong-Uk;Lee, Jong-Chan
    • Macromolecular Research
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    • v.16 no.8
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    • pp.711-716
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    • 2008
  • We synthesized gold nanonetwork using the amphiphilic polymer brush, poly(oxyethylene) containing decyltri(oxyethylene)thiomethyl ($C_{10}H_{21}(OCH_2CH_2)_3SCH_2-$) side groups, as a stabilizer and/or a template. When tetrabutylammonium borohydride solution in THF was added to a mixture solution of the polymer and $LiAuCl_4$ in THF, 0-D gold nanomaterials were obtained. However, when an aqueous solution of sodium borohydride was added, gold nanonetworks were synthesized. The composites composed of polymer/0-D gold nanomaterials and polymer/gold nanonetworks showed electrical conductivities of ${\sim}10^{-9}$ and ${\sim}10^{-3}S/cm$, respectively, which indicated that the gold nanonetworks increased the electrical conductivity.

Integration of solution-processed polymer thin-film transistors for reflective liquid crystal applications

  • Kim, Sung-Jin;Kim, Min-Hoi;Suh, Min-Chul;Mo, Yeon-Gon;Chang, Seung-Wook;Lee, Sin-Doo
    • Journal of Information Display
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    • v.12 no.4
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    • pp.205-208
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    • 2011
  • Herein, the integration of solution-processed polymer thin-film transistors (TFTs) that were fabricated using selective wettability through ultraviolet (UV) exposure into a reflective liquid crystal display is demonstrated. From the experimental results of energy-dispersive spectroscopy, the composition of carbon and fluorine enhancing the hydrophobicity in the polymer chains was found to play a critical role in the wetting selectivity upon UV exposure. The polymer TFTs fabricated through the wettability-patterning process exhibited long-term stability and reliability. This wetting-selectivity-based patterning technique will be useful for constructing different types of solution-processed electronic and optoelectronic devices.