• 한국분말재료학회지
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• 제16권2호
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• pp.110-114
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• 2009

Mechanical coating process was applied to form 89 %-hydrolyzed poly vinyl alcohol (PVA) onto boron carbide ($B_4C$) nanopowder using one step high energy ball mill method. The polymer layer coated on the surface of B4C was changed to glass-like phase. The average particle size of core/shell structured $B_4C$/PVA was about 50 nm. The core/shell structured $B_4C$/PVA was formed by dry milling. However, the hydrolyzed PVA of $98{\sim}99%$ with high glass transition temperature ($T_g$) was rarely coated on the powder. The $T_g$ of polymer materials was one of keys for guest polymer coating on to the host powder by solvent free milling.

• Transactions on Electrical and Electronic Materials
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• 제10권4호
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• pp.116-120
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• 2009

Ceramic-polymer composites have been investigated for their suitability as embedded capacitor materials because they combine the processing ability of polymers with the desired dielectric properties of ceramics. This paper discusses the dielectric properties of the ceramic ($BaTiO_3$)-polymer (Epoxy) composition as a function of ceramic particle size at a ceramic loading of 40 vol%. The dielectric constant of these ceramic-polymer composites increases as the powder size decreases. Results show that ceramic-polymer composites have a high dielectric constant associated with the $BaTiO_3$ powder with a 200 nm particle size, high insulation resistance, high breakdown voltage (> 22 KV/mm), and low dielectric loss (0.018-0.024) at 1 MHz.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.252-255
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• 2003

Recently, there is a growing trend in the United States toward replacing latex additives in polymer-modified cement mortars with redispersible polymer powders. This movement is relatively new in the U.S. but is further advanced in Europe due to the more extensive use of cement and concrete in residential construction. Hitherto, in Korea - there is a very diminutive movement towards this growing trend. Thus, there is limited availability of data on redispersible polymer powders. This study investigates the effectiveness of redispersible polymer powder on improvement of the mechanical properties of modified mortar. It was concluded from the results of the experiments that the size of the dispersed polymer particles, variations in glass transition points (Tg), and variations in minimum film formation temperature (MFT) influenced the strength development of the modified mortars, and optimum strength in modified mortars using redispersible powders can be achieved when the Tg which accounts for the degree of powder flexibility is considered.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2002년도 춘계학술강연 및 발표대회
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• pp.18-19
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• 2002

No Abstract, See Full Text

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.464-465
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• 2006

Monodispersed and nano-sized Cu powders were synthesized from copper sulfate pentahydrate $(CuSO_4{\cdot}5H_2O)$ inside a nonionic polymer matrix by using wet chemical reduction process. The sucrose was used as a nonionic polymer network source. The influences of a nonionic polymer matrix on the particle size of the prepared Cu powders were characterized by means of X-ray diffraction), scanning electron microscopy), and particle size analysis). The smallen Cu powders with size of approximately 100 nm was obtained with adding of 0.04M sucrose at reaction temperature of $60\;^{\circ}C$. The particle size of the Cu powders prepared by the reduction inside polymer network was strongly dependent of the sucrose content and reaction temperature.

• 한국농공학회논문집
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• 제52권6호
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• pp.125-134
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• 2010

This study was performed to evaluate the workability, strengths and durability of polymer concrete using oyster shell that are reclaimed at public shore illegally or leaved on the surroundings of shore to prevent the environmental pollution. We investigated the effect of oyster shell powder (OSP) and $CaCO_3$. on the slump, compressive strength, flexural strength, acid sulfuric and freezing and thawing resistance as a filler of polymer concrete. Modified OSP obtained by crushing oyster shell (less than 0.15 mm size) consists of 60.47 wt% of $SiO_2$ and 39.5 wt% of $CaCO_3$. As a result of slump test by OSP and $CaCO_3$. contents, it is found that slump of specimen used OSP is lower than that used $CaCO_3$. and the more OSP contents are, its slump is increased. Compressive and flexural strength of polymer concrete using OSP are similar or slightly lower than that using $CaCO_3$. In acid sulfuric test for 5 % $H_2SO_4$ and freezing thawing test, regardless of kinds of fillers and contents are not found fatal defects in weight change, falling-off in surface and durability factor.

• 한국분말재료학회지
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• 제31권3호
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• pp.263-271
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• 2024

This study focused on improving the solubility of silodosin, a drug poorly soluble in water, by utilizing solid dispersions. Three types of dispersions were examined and compared against the drug powder: surface-attached (SA), solvent-wetted (SW), and solvent-evaporated (SE). Polyvinyl alcohol (PVA) was identified as the most effective polymer in enhancing solubility. These dispersions were prepared using spray-drying techniques with silodosin and PVA as the polymer, employing solvents such as water, ethanol, and a water-acetone mix. The physicochemical properties and solubility of the dispersions were evaluated. The surface-attached dispersions featured the polymer on a crystalline drug surface, the solvent-wetted dispersions had the amorphous drug on the polymer, and the solvent-evaporated dispersions produced nearly round particles with both components amorphous. Testing revealed that the order of improved solubility was: solvent-evaporated, solvent-wetted, and surface-attached. The results demonstrated that the preparation method of the solid dispersions significantly impacted their physicochemical properties and solubility enhancement.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 추계학술발표대회 논문집
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• pp.91-94
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• 2005

Polypropylene as a matrix has been used for wood polymer composites(WPC). In preparing WPC, the coupling agent, Polypropylene grafted Maleic Anhydride(PP-G-MA) was used in order to obtain a good interfacial bonding force between matrix and fillers and dispersion of wood powders. In this study, the effects of wood powder contents and water absorption on the mechanical properties were experimentally investigated. The tensile strength and flexural strength of composites reached its peak value when the wood powder content was around 60 wt%. However, the peak value of the impact was observed about 30 wt% of wood powder content. The tensile strength and flexural strength increase with increasing the wood power contents. But the impact strength decrease with increasing the wood powder contents. The slight change was observed with the water absorption in the WPC. The optimal condition of the compositions such as Anti-oxidant and UV stabilizers for the outdoor application was suggested in this research.

• 한국재료학회지
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• 제30권11호
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• pp.573-580
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• 2020

YAG (Yttrium Aluminum Garnet, Y₃Al₅O₁₂) has excellent plasma resistance and recently has been used as an alternative to Y₂O₃ as a chamber coating material in the semiconductor process. However, due to the presence of an impurity phase and difficulties in synthesis and densification, many studies on YAG are being conducted. In this study, YAG powder is synthesized by an organic-inorganic complex solution synthesis method using PVA polymer. The PVA solution is added to the sol in which the metal nitrate salts are dissolved, and the precursor is calcined into a porous and soft YAG powder. By controlling the molecular weight and the amount of PVA polymer, the effect on the particle size and particle shape of the synthesized YAG powder is evaluated. The sintering behavior of the YAG powder compact according to PVA type and grinding time is studied through an examination of its microstructure. Single phase YAG is synthesized at relatively low temperature of 1,000 ℃ and can be pulverized to sub-micron size by ball milling. In addition, sintered YAG with a relative density of about 98 % is obtained by sintering at 1,650 ℃.

• 한국건설순환자원학회논문집
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• 제9권3호
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• pp.330-337
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• 2021

3D 프린팅의 기술발전으로 대형물 제작이 가능하게 되면서 이를 건축물에 적용하기 위한 연구가 활발하게 진행되고 있다. 건축물에서는 구조재와 비구조재로 구분되고 비구조재는 비정형 구조물 및 내·외장패널에 적용하기 유리하다. 3D 프린팅 재료는 기본적으로 시멘트 모르타르의 압출과 적층이 가능해야하므로 시멘트 혼화용 폴리머 와 경량재료의 사용이 필수적이다. 본 연구는 3D 프린팅 적용을 위해 시멘트 모르타르에 EVA 재유화형 분말수지를 사용하였다. 경량재료 혼입 폴리머 시멘트 모르타르의 난연특성을 평가하기 위해 골재로는 규사8호와 경량재료로 경량골재, 중공글라스를 사용하여 난연 및 불연성능을 평가하였다. 연구결과, 규사8호 및 경량골재를 사용한 시험체가 충분한 난연 및 불연성능을 보였다. EVA 재유화형 분말수지를 혼입할 경우 5% 이하로 적용하여 사용하는 것이 유리하다.