• 제목/요약/키워드: polymer fibers

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Optimal Design of Laminate Composites with Gradient Structure for Weight Reduction

  • Back, Sung-Ki;Kang, Tae-Jin;Lee, Kyung-Woo
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.68-72
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    • 1999
  • In an effort to construct a structure under the design principle of minimal use of materials for maximum performances, a discrete gradient structure has been introduced in laminate composite systems. Using a sequential linear programming method, the gradient structure of composites to maximize the buckling load was optimized in terms of fiber volume fraction and thickness of each layer. Theoretical optimization results were then verified with experimental ones. The buckling load of laminate composite showed maximum value with the outmost [$0^{\circ}$] layer concentrated by almost all the fibers when the ratio of length to width(aspect ratio) was less than 1.0. But when the aspect ratio was 2.0, the optimum was determined in a structure where the thickness and fiber volume fraction were well balanced in each layer. From the optimization of gradient structure, the optimal fiber volume fraction and thickness of each layer were proposed. Experimental results agreed well with the theoretical ones. Gradient structures have also shown an advantage in the weight reduction of composites compared with the conventional homogeneous structures.

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Spinodal Phase Separation and Isothermal Crystallization Behavior in Blends of VDF/TrFE(75/25) Copolymer and Poly(1,4-butylene adipate) (I) -Spinodal Phase Separation Behavior-

  • Kim, Kap Jin;Kyu, Thein
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.188-194
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    • 2003
  • Phase behavior and spinodal phase separation kinetics in binary blends of a random copolymer of vinylidene fluoride and trifluoroethylene (75/25) [P(VDF/TrFE)] and poly(l,4-butylene adipate) (PBA) have been investigated by means of optical microscopic observation and time-resolved light scattering. The blends exhibited a typical lower critical solution temperature (LCST)∼${34}^{\circ}C$ above the melting temperature of the P(VDF/TrFE) crystals over the entire blend composition range. P(VDF/TrFE) and PBA were totally miscible in the temperature gap between the melting point of P(VDF/TrFE) and the LCST. Temperature jump experiments of the 3/7 P(VDF/TrFE)/PBA blend were carried out on a light-scattering apparatus from a single-phase melt state (${180}^{\circ}C$) to a two-phase region (205∼${215}^{\circ}C$). Since the late stage of spinodal decomposition (SD) is prevalent in the 3/7 blend, SD was analyzed using a power law scheme. Self-similarity was preserved well in the late stage of SD in the 3/7 blend.

Polypropylene-Natural Fiber Composites: Rheological Properties during Mixing and Thermal Properties (폴리프로필렌-천연섬유 복합재료의 혼합시 유변학적 물성 및 열적 특성)

  • Kim, Sam-Jung;Yoo, Chong Sun;Kim, Gue-Hyun;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.9 no.4
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    • pp.24-29
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    • 2008
  • Polypropylene-natural fiber composites have been prepared and their rheological properties during mixing and thermal properties were investigated. Two types of natural fibers (cotton fiber and wood fiber) were compared. On increasing fiber contents, the torque values of composites were increased, where the cotton fiber exhibited higher increase in torques. The torque values of composites were higher as the MI of PP decreased. X-ray diffraction and differential scanning calorimetry results showed an increase in the crystallization temperature but a decrease of crystallinity of the PP/natural fiber composites on increasing fiber contents.

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Electrospinning of Asiaticoside/2-Hydroxypropyl-β-cyclodextrin Inclusion Complex-loaded Cellulose Acetate Fiber Mats: Release Characteristics and Potential for Use as Wound Dressing (Asiaticoside/2-Hydroxypropyl-β-cyclodextrin 포접화합물 함유 셀룰로오스 아세테이트 섬유 매트의 전기방사: 창상피복제로서 사용가능성과 방출특성)

  • Panichpakdee, Jate;Pavasant, Prasit;Supaphol, Pitt
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.338-350
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    • 2014
  • Cellulose acetate (CA) fiber mats containing inclusion complexes of asiaticoside (AC) in 2-hydroxypropyl-${\beta}$-cyclodextrin ($HP{\beta}CD$) for potential usage as wound dressings were developed. The AC/$HP{\beta}CD$ complex-loaded CA fibers at various $HP{\beta}CD$ to AC molar ratios of 0.5, 1, and 2 were prepared in 90:10 v/v mixture of 80% (v/v) acetic acid and N,N-dimethylacetamide (DMAc) via electrospinning. The maximum released amounts of AC depended on the $HP{\beta}CD$ content and were much greater than those released from the AC-loaded CA fiber mat. In the in vitro study, indirect cytotoxic evaluation with human dermal fibroblasts (HDFa) showed that these materials released no substances in the levels that were harmful to the cells and the cells appeared to attach and proliferate well on these substrates. However, only the CA fiber mats containing AC/$HP{\beta}CD$ complexes at the $HP{\beta}CD$ to AC molar ratio of 0.5 was effective in upregulating the production of collagen of the cultured cells.

Nanoparticle Size Effect on Mechanical Properties of Carbon Fiber-reinforced Polymer Composites (탄소섬유강화 에폭시수지의 기계적 성질에 미치는 나노입자크기의 영향)

  • Moon, Chang-Kwon;Kim, Bu-Ahn
    • Journal of Ocean Engineering and Technology
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    • v.29 no.2
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    • pp.186-190
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    • 2015
  • $TiO_2$ nanoparticles can be used to improve the performance of carbon fiber-reinforced epoxy resin composites. In this study, the effect of the size of $TiO_2$ nanoparticles on the mechanical properties of carbon fiber-reinforced epoxy resin composites was investigated. The size of the $TiO_2$ nanoparticles was easily controlled using heat treatment. The size of the $TiO_2$ nanoparticles for this study were20nm, 100nm, and 200nm. Three types of carbon fibers with different diameters were also used in this study. The carbon fiber-reinforced epoxy resin composites with 20-nm $TiO_2$ powder showed the highest tensile strength compared to the other types of CFRP, regardless of the fiber maker or fiber diameter. The size of the $TiO_2$ powder and the diameter of the carbon fiber strongly affected the interfacial properties of all kinds of CFRP in this study.

Experimental study of the behavior of composite timber columns confined with hollow rectangular steel sections under compression

  • Razavian, Leila;Naghipour, Morteza;Shariati, Mahdi;Safa, Maryam
    • Structural Engineering and Mechanics
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    • v.74 no.1
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    • pp.145-156
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    • 2020
  • There are separate merits and demerits to wood and steel. The combination of wood and steel as a compound section is able to improve the properties of both and ultimately increase their final bearing capacity. The composite cross-section made of steel and wood has higher hardness while showing more ductility and the local buckling of steel is delayed or completely prevented. The purpose of this study is to investigate the behavior of composite columns enclosed in wooden logs and the hollow sections of steel that will be examined in a laboratory environment under the axial load to determine the final bearing capacity and sample deformation. In terms of methodology, steel sheet and carbon fiber reinforced polymer sheet (FRP) are tested to construct hollow rectangular sections and reinforce timber. Besides, the method of connecting hollow sections and timber including glue and screw has been also investigated. As a result, timber lumber enclosed with carbon fiber-reinforced polymer sheets in which fibers are horizontally located at 90° are more resistant with better ductility.

Repair and Strengthening Methods for Concrete Structures using Sprayed Fiber Reinforced Polymers - Strengthening performance of Reinforced Concrete Shear Columns - (Sprayed FRP 공법에 의한 콘크리트 구조물의 보수.보강법 개발에 관한 연구 - 철근콘크리트 전단기둥의 보강성능 평가 -)

  • Lee, Kang-Seok;Byeon, In-Hee;Son, Young-Sun;Lee, Moon-Sung;Li, Cheng-Hao;Lee, Li-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.137-140
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    • 2006
  • In this study, a seismic performance of reinforced concrete columns strengthened by a sprayed fiber reinforced polymer (SFRP) is investigated. For this purpose, six column specimens approximately scaled into 2/3, are designed and tested under a constant axial load, 10% of the nominal axial strength of column, and pseudo-static reversed cyclic lateral loading system. Four specimens are strengthened by Sprayed FRP using different combinations of short fibers (carbon or glass fiber) and resins (epoxy or vinyl esther). For comparison, the test investigated in this study also includes a specimen strengthened using carbon fiber reinforced polymer (CFRP), and also a control specimen without strengthening. The results revealed that specimens strengthened using SFRP showed a improved structure behavior, compared to control specimen, in terms of strength, ductility, lateral drift capacity, and energy-absorbtion capacity. In addition, compared to the specimen strengthened using CFRP, Sprayed FRP-strengthened specimens reasonably showed a equivalent seismic performance.

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Organic Solvent Absorption Characteristics of Split-type Microfiber Fabrics

  • Lee Kwang Ju;Kim Seong Hun;Oh Kyung Wha
    • Fibers and Polymers
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    • v.5 no.4
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    • pp.280-288
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    • 2004
  • Split-type nylon/polyester microfiber and polyester microfiber fabrics possess drapeability, softness, bulkiness, and smoothness, so that they can be applied in various industrial fields. In particular, these fabrics are able to absorb various organic solvents, and can be used as clean room materials. To investigate the chemical affinity between solvents and the compositional materials of these fabrics, the contact angle of thermally pressed film fabrics was measured with different solvents. The thermally pressed nylon/polyester fabric films showed a chemical attraction to formamide. The sorption properties of the microfiber fabrics were investigated using a real time testing device, and these tests showed that the sorption behavior was more influenced by the structure of the fibrous assembly than by any chemical attraction. The effect of the fabric density, specific weight, and sample structure on the sorption capacity and rate was examined for various organic solvents. The sorption capacity was influenced by the density and the specific weight of the fibrous assembly, and knitted fabric showed a higher sorption capacity than woven fabric. However, the sorption rate was less affected in lower viscosity solvents. On applying Poiseuille's Law, the lower viscosity solvents showed higher initial sorption rates, and more easily penetrated into the fibrous assembly.

Analytic Formulation of Transmission Light Intensity of Hole Blockers in Intensity-based Polymer Optical Fiber Sensors

  • Kwon, Il-Bum;Kim, Chi-Yeop;Shim, Chan-Wook;Hwang, Du-Sun;Chung, Yung-Joo
    • Journal of Sensor Science and Technology
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    • v.20 no.4
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    • pp.221-225
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    • 2011
  • Intensity-based optical fiber sensors are devised using a blocker which is located between two polymer optical fibers(POFs), one fiber is light-in and the other is light-out. This blocker is moved by an external displacement. Therefore, finding a general formulation of the relation between this displacement and transmission light intensity of various blockers is important to help develop intensity-based optical fiber sensors. In this paper, we consider blockers with arbitrary shapes from circular holes to inclined angled blockers. The transmission light intensities of such blockers should be determined by this generalized equation. In order to verify this equation, the calculated intensities of the blockers are compared with the values acquired from experiment. In the comparison, it is shown that the analytic equation can give the exact values of the transmitted light intensities for the assorted blockers. The range of the displacement measurement is also shown to be about 6 times of the radius of the hole in the case of a 9 degree inclined angle blocker.

Synthesis and Electrochemical Properties of Li[Ni1/3Co1/3Mn1/3]O2 Nanowire by the Electrospinning Method (전기방사법을 이용한 Li[Ni1/3Co1/3Mn1/3]O2 나노 섬유의 합성 및 전기화학적 특성)

  • Kang, Chung-Soo;Son, Jong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.850-854
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    • 2011
  • Nano-fibers of the $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ electrode were synthesized from a metal oxide precursor using the electrospun method. The XRD patterns of all prepared powders showed a hexagonal ${\alpha}$ - $NaFeO_2$ structure (space group: R-3 m, 166). Scanning electron microscopy showed that all the synthesized samples were comprised of nanofibers with a size of 100~800 nm. Among the samples tested, the calcined $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ nanowires in oxygen heating atmosphere showed a high charge and discharge capacity of 239.22 and 172.81 $mAhg^{-1}$ at the $1^{st}$ cycle, respectively. In addition, the charge transfer resistance was also improved significantly compared to the other samples.