• 폴리머
• /
• 제35권1호
• /
• pp.60-65
• /
• 2011

고분자 나노복합재의 성능을 극대화 하기 위해서는 나노업자 분산도의 향상과 더불어 분산상태가 물성 변화에 미치는 영향을 정확히 이해하는 것이 매우 중요하다. 본 연구에서는 탄소나노튜브 첨가 고분자 복합재의 분산상태를 정량적으로 평가할 수 있는 방법을 제시하고자 하였다. 자외선-가시광선 분광광도법을 이용하여 탄소나노튜브의 분산상태에 따른 투과도를 측정하였으며, 동일 농도에서 분산상태가 향상됨에 띠라 투과도가 감소하는 것을 확인하였다. 이러한 결과를 바탕으로 기존의 Beer-Lambert 투과도 법칙에 분산상태의 변화를 포함할 수 있는 새로운 분산도 평가인자인 유효 농도 인자를 제시하였다. 이를 통해 탄소나노튜브의 분산상태의 변화와 함께 다양한 탄소나노튜브의 농도 및 시편 두께에 따른 투과도 결과를 분석함으로써 제시한 분산도 평가방법과 유효 농도 인자의 유효성을 확인하였다.

• Macromolecular Research
• /
• 제15권3호
• /
• pp.244-255
• /
• 2007

Nucleation is the most sensitive stage in the preparation of highly cross-linked, monodisperse microspheres by dispersion polymerization, since the addition of a small amount of cross-linker results in particle deformation and coagulation. To overcome these problems, $5\;{\mu}m$ poly(methyl methacrylate) seed particles prepared by dispersion polymerization were used in the preparation of mono disperse, cross-linked PMMA particles containing up to 7 wt% divinylbenzene by seeded batch dispersion polymerization. Spherical particles with a narrow size distribution containing up to 8 wt% of EGDMA were prepared by seeded multi-batch dispersion polymerization processes. These particles were identified by scanning electron microscopy and DSC.

• 폴리머
• /
• 제35권2호
• /
• pp.113-118
• /
• 2011

고체분산체는 난용성약물의 용해도를 향상시키는 기술로 용출특성을 고분자의 성질, 고분자의 함량 및 물리화학적 성질에 의하여 변화한다. 본 연구에서는 이부프로펜과 셀룰로오스 아세테이트를 사용하여 분무건조와 로터리 증발법을 사용하여 고체분산체를 제조하였다. 제조한 고체분산체의 표면성질을 주사전자현미경(SEM)을 사용하여 분석하였으며, X선 회절기(X-RD)와 사치주사열량계(DSC)를 사용하여 결정성 변화를 관찰하였다. 고체분산체의 화학적 변화를 관찰하기 위하여 적외선 분광기(FTIR) 분석을 하였으며, 수분 친화도를 측정하기 위하여 수분접촉각 측정을 하였다. 용출 특성은 인공정액(pH 6.8) 및 인공위액 (pH 1.2)에서 관찰하였다. 실험결과 약물의 결정성은 고분자의 비율이 증가하면 결정성이 감소하였으며, 화학적 변화는 없었다. 수분 친화도는 고분자비율과 비례하였으며, 분무건조로 제조된 고체분산체의 경우가 조금 높은 수분 친화도를 가졌다. 용출실험 결과 인공위액에서는 고분자의 비율이 높아질수록 용출률이 증가하였으며, 인공장액에서의 용출속도는 고분자의 비율과 반비례하는 것을 볼 수 있었다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
• /
• pp.337-340
• /
• 2008

As the Ready-mixed Shotcrete using Powdered Polymer Dispersion, Shotcrete Matrix as totally shotcrete gel that a part of second binder in Shotcrete materials is dense. Also, Ready-mixed Shotcrete is showed the decreasing Rebound and rising Durability. Therefore, it is possible that Ready-mixed Shotcrete for High-Strength and High-Waterproof can apply to the Powdered Polymer Dispersion.

• 한국세라믹학회지
• /
• 제51권4호
• /
• pp.324-331
• /
• 2014

The dispersion characteristics of AlN-4.5 wt% $Y_2O_3$ powder mixture by various dispersants were investigated in ethanol and methyethly-ketone (MEK) solvents. In general, the cationic polymer dispersants demonstrated superior dispersion of the powder as compared to the non-ionic ester-type dispersants or anionic phosphate-ester-based ones. The dispersion performance of the cationic polymer dispersants was sensitive to the type of solvent. An anhydric maleic-acid-based graft copolymer dispersant, AFB-1521, demonstrated a very good dispersion capability in ethanol but exhibited a much inferior dispersion in MEK. On the other hand, the dispersion of the powder mixture was very good with a phosphate-ester-based block polymer dispersant, BYK-111, in MEK solvent, while dispersionwas much degraded in ethanol.

• 한국고분자학회지:고분자과학과기술
• /
• 제16권1호
• /
• pp.38-47
• /
• 2005

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
• /
• pp.1005-1010
• /
• 2001

Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top layers with thin thicknesses, typically 5~ 15mm. The purpose of this study is to evaluate basic properties of self leveling materials using polymer modifier as kinds of SBR, PAE, SUBA. Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as in order to facilitate the workability required. The self leveling materials using four types of polymer dispersion are prepared with polymer-cement ratios which respectively range from 50%, 75%, and were tested for basic characteristics such as adhesion in tension, crack resistance test, rebound test after the preparative tests for unit weight, air content, consistency ratio etc. The results show almost as equal quality as existing commercial industrial flooring when mortar is modified by polymer dispersion. Adhesion in tension of polymer modified mortars using each SBR and PAE emulsion was over 10 kgf/$cm^{2}$. Crack or flaw derived from shrinkage is strongly dependent on the type of polymer dispersion because of each different total solid of polymer. It is judged that polymer modified mortar with self-leveling can be very well suited for Floor-finished.

• 폴리머
• /
• 제33권6호
• /
• pp.596-601
• /
• 2009

아세클로페낙은 높은 결정성을 갖는 난용성 약물이다. 이러한 난용성 약물의 용해도를 증진시키기 위해서 고체분산법을 바탕으로 한 분무건조기를 이용하여 미립구를 제조하였다. PVP-K30을 수용성 담체로 사용하였고 폴록사머는 계면활성화제로 사용하였다. 제조된 아세클로페낙 고체분산체의 특성을 SEM, DSC, XRD 그리고 FT-IR을 이용하여 확인하였다. SEM, DSC, XRD을 통하여 아세클로페낙 고체분산체가 무정형임을 알 수 있었고 FT-IR을 통하여 아세클로페낙과 PVP-K30간에 수소결합을 통해 염을 형성하고 있다는 것을 확인할 수 있었다. 제조된 미립구는 pH 6.8에서 방출을 실시하였으며 시판제인 $Airtal^{(R)}$과 용출률을 비교하였으며 분무건조를 통해 제조한 미립구가 시판제인 $Airtal^{(R)}$ 보다 용출률이 크다는 것을 확인하였다.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2001년도 학술논문발표회
• /
• pp.88-92
• /
• 2001

This paper discusses the strength properties of the polymer-modified mortars using redispersible polymer powders, which is widely used for the manufacture of prepackaged-type polymer-modified mortar products at present. The polymer-modified mortars using redispersible polymer powders are prepared with various polymer-cement ratios, and tested for air content, flexural and compressive strengths, and tensile strength. The strength properties are almost the same as those of polymer dispersion-modified mortars, depending on the polymer-cement ratios, and are improved over unmodified mortar. In particular, between tensile strength and glass transition point of polymer powder have a high correlation. It is concluded from the test results that polymer-modified mortars using redispersible polymer powders can be used in the same manner as ordinary polymer dispersion-modified mortars.

• Journal of Pharmaceutical Investigation
• /
• 제38권2호
• /
• pp.111-117
• /
• 2008

To overcome the solubility of poorly water-soluble drug, the formation of solid dispersion using a spray-dryer with polymeric material, that can potentially enhance the dissolution rate extend of drug absorption was considered in this study. $Eudragit^{(R)}$ E100 as carrier for solid dispersion is acrylate copolymer that soluble in acidic buffer solutions (below pH 5.0). It was used to increase dissolution of atorvastatin calcium as a water-insoluble drug in acidic environments. In this study, a spray-dryer was used to prepare solid dispersion of atorvastatin calcium and $Eudragit^{(R)}$ E100 for purpose of improving the solubility of drug. Atorvastatin calcium and $Eudragit^{(R)}$ E100 were dissolved in ethanol and spray-dryed. DSC and XRD were used to analyze the crystallinity of the sample. It was found that atorvastatin calcium is amorphous in the $Eudragit^{(R)}$ E100 solid dispersion. FT-IR was used to analyze the salt formation by interaction between atorvastatin calcium and $Eudragit^{(R)}$ E100. Comparative dissolution study exhibited better dissolution characteristics than the commercial drug ($Lipitor^{(R)}$) as control. The dissolution rate of atorvastatin calcium was markedly increased in solid dispersion system in simulated gastric juice (pH 1.2). This study proposed that this solid dispersion system improved the bioavailability of poorly water-soluble atorvastatin calcium.