• Title/Summary/Keyword: polymer additives

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The Characteristics of Convective Heat Transfer in Non Boiling Vertical Downard Flow (비비등 수직 하향 유동의 대류 열전달 특성)

  • Lee, D.S.;Kim, J.G.;Yang, H.J.;Oh, Y.K.;Cha, K.O.
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.118-123
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    • 2000
  • This experimental study was conducted to figure out the characteristics of convective heat transfer in non boiling vertical downward flow with polymer additives. This experiment was studied in 26mm diameter, 800mm heating length and $1{\times}10^5W/m^2$ heat flux. The polymer concentration ranged from 0PPM to 500PPM with corresponding from Reynolds number $3.3{\times}10^4$ to $6.8{\times}10^4$ in non boiling vertical downward flow. Experimental results show that the characteristics of convective heat transfer was a strong function of polymer concentration and it has decreased with increasing the polymer concentration in non boiling vertical downward flow.

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Evolution of phase morphology and in-situ compatibilization of polymer blends during ultrasound-assisted melt mixing

  • Kim, Hyungsu;Ryu, Joung-Gul;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.14 no.3
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    • pp.121-128
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    • 2002
  • A series of thermoplastic polymers and their blends were melt-processed with high intensity ultrasonic wave in an intensive mixer. For the effective transfer of ultrasonic energy, an experimental apparatus was specially designed so that polymer melt can directly contact with ultrasonic horn. It was observed that significant variations in the rheological properties of polymers occur due to the unique action of ultrasonic wave without any aid of chemical additives. It was also found that the direct sonication on immiscible polymer blends in melt state reduces the domain sizes considerably and stabilizes the phase morphology of the blends. The degree of compatibilization was strongly affected by viscosity ratio of the components and the morphology was stable after annealing in properly compatibilized blends. It is suggested that ultrasound assisted melt mixing can lead to in-situ copolymer formation between the components and consequently provide an effective route to compatibilize immiscible polymer blends.

Study on Properties with Different Plasticizers in the Preparation of Polymer Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.35-39
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    • 2019
  • Four different polymer compounds were prepared from four kinds of plasticizers, viz. di-2-ethylhexyl azelate (DOZ), di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl sebacate (DOS), and di-2-butyl sebacate (DBS), for making cable sheaths for ships. Ethylene-vinyl acetate and ethylene-propylene-diene-copolymer as matrix polymers and ethylene-vinyl acetate grafted maleic anhydride as a coupling agent were compounded with a flame retardant, crosslinking agent, filler, and other additives, besides the plasticizer to obtain the polymer compounds. The polymer containing DOZ showed the highest MH and ${\Delta}T$ in the rheology test, while that containing DBS was found to have the lowest tensile strength and highest elongation because of low ${\Delta}T$. The four polymers showed similar values (31.7-31.9) for flame resistance, while the polymer containing DOZ showed the highest value for cold resistance.

The Effect of ZnCl$_2$ on Polysulfone Membrane

  • Kim, Sue-Ryeon;Lee, Kew-Ho;Jhon, Mu-Shik
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.34-35
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    • 1993
  • The study was undertaken to investigate the effects of ZnCl$_2$ in polysulfone(PSf)/N-methylpyrrolidone(NMP) on the structure and performance of its membrane. The effects of additives on the performances of membranes have been studied. It has been shown that some low molecular weight additives in polysulfone(PSf) casting solutions have effects on the performances of membranes cast from these solutions. It had been reported that ZnCl$_2$, as the additives-in PSf casting solution, decreases water permeability and increases the rejection rate of its membrane.

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A Study on the Drag Reduction with Polymer Additives (고분자물질(高分子物質) 첨가(添加)에 따른 마찰저항감소(摩擦抵抗減少)에 관한 연구(硏究))

  • Kim, J.G.;Cha, K.O.;Choi, H.J.;Kim, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.2
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    • pp.198-207
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    • 1996
  • It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity, and turbulent intensity whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with the inner diameter of 24mm and the length of 1,500mm. The polymer materials used are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results showed that the drag reduction of co-polymer is higher than that of polyacrylamide. Mean liquid velocities increased as polymer was added, and turbulent intensity decreased inversely near the pipe wall.

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Polymer surfaces studied by sum-frequency vibrational spectroscopy

  • Kim, D.;J. Sung;H. M. Cheong;C. N. Whang;Y. Ouchi;T. limori;N. Matsuie;K. Seki
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.70-73
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    • 2003
  • Sum-frequency vibrational spectroscopy has recently been used to investigate the surface of the various polymers and was able to find the chemical compositions and structures specific to the surface. Here we report our studies on two specific polymer samples to demonstrate its capability. Polyimide thin films were made by spin coating on fused quartz and $CaF_2$ substrates. The sum-frequency signal originating mainly from the air/polymer interface showed markedly different spectra, indicating the structural change of the polymer surface depending on the underlying substrate. Various polyethylene surfaces were also investigated by sum-frequency vibrational spectroscopy. The surface of polyethylene samples in the CH-region showed different sum-frequency spectra, presumably due to the trace amount of additives having much higher concentration at the air/polymer interface. These examples demonstrate the surface and interface of the polymer could have different structure and chemical composition from those of a bulk, which can be studied effectively by surface nonlinear optical spectroscopy.

Development of New Polymer Powders for the Industrial SFF system by using SLS Process (SLS 공정을 이용한 산업용 SFF 시스템용 신소재 고분자분말 개발)

  • Bang, Young-Kil;Choi, Ki-Seop;Park, Chang-Hyun;Kim, Hyung-Il;Lim, Byung-Seok;Kim, Dong-Soo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1404-1409
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    • 2007
  • Polymers for laser sintering were needed in order to fabricate the articles with the three-dimensional duplication equipment of SLS (selective laser sintering) process. The thermal properties, particle size, distribution, and shape of polymer powder had a close relation with the processibility of laser sintering. In this study, we prepared new polymer powders with uniform size and higher bulk density by wet process. Wet process consists of several finely-controlled steps such as dissolution, nucleation, propagation and crystallization. Several additives were added to improve the thermal, rheological, and flow properties.

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The Control of Electrostatic Characteristics in Toner Type Paper-like Display

  • Lee, Sung-Guk;Kwon, Soon-Hyung;Cho, Won-Ki;Song, Moon-Bong;Kim, Young-Woon
    • Journal of Information Display
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    • v.8 no.1
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    • pp.14-17
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    • 2007
  • The toner type paper-like display (PLD) has been developed with two polymer particles having opposite polarity composed of polymer, colorant and external additives (nano-sized silica). Nano-sized silica with triboelectric charge was used for the charge control agent (CCA) and influenced on the electrostatic properties of the silica-coated polymer particles. The surface morphology and the cohesiveness of silica-coated polymer particles were changed with the silica coating time. From these results, it was verified that the PLD cell using silica-coated particles (200 seconds) shows a good white appearance and low driving voltage.

Design of Oral Patches for the Treatment of Aphthous Stomatitis : Drug Layer (아프타성 구내염 치료용 구강 패취의 설계 : 약물층)

  • Lee, Kyu-Hyun;Park, Eun-Seok;Chi, Sang-Cheol
    • Journal of Pharmaceutical Investigation
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    • v.25 no.4
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    • pp.339-345
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    • 1995
  • For the effective treatment of aphthous stomatitis, the matrix type mucoadhesive patches containing triamcinolone acetonide have been formulated. The drug layer was obtained by drying the polymer gel which was prepared with carbomer 934P, ammoniomethacrylate copolymer, titanium dioxide and polyethylene glycol 400. The effects of the content of additives on physical characteristics of the polymer gel and the drug layer were evaluated. The addition of carbomer increased the yield point and the zero-shear viscosity of polymer gel as well as the thickness, the water absorption ratio, the adhesive time and $T_{50%}$ of drug layer. The adhesive time and the water absorption ratio of drug layer were also improved by the addition of ammoniomethacrylate copolymer, but the addition of titanium dioxide had decreased the zero-shear viscosity of polymer gel and the adhesive time of drug layer.

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Electrochemistry of Conductive Polymers 46. Polymer Films as Overcharge Inhibitors for Lithium-Ion Rechargeable Batteries

  • Choi, Shin-Jung;Park, Su-Moon
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.1-9
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    • 2010
  • Conducting polymer films grown from various aromatic compounds have been evaluated as overcharge protecting additives for lithium ion rechargeable batteries. The polymer films were grown electrochemically under the conditions similar to those encountered during the overcharging processes of lithium batteries and subsequently characterized by potentiodynamic, electrochemical quartz crystal microbalance, electrochemical impedance spectroscopic, and scanning electron microscopic experiments. Results indicate that bicyclic and polycyclic aromatic hydrocarbons would be poor candidates for inhibitors, while biphenyl, terphenyl, and benzene derivatives displayed excellent performances. Mixed polymer films grown from o-terphenyl and p-xylene show the best performance among the candidates.