• Title/Summary/Keyword: polyethylene terephthalate(PET)

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Improvement of Out-coupling Efficiency of Organic Light Emitting Device by Ion-beam Plasma-treated Plastic Substrate (이온빔 플라즈마 처리된 플라스틱 기판에 의한 OLED의 광추출 효율 향상)

  • Kim, Hyeun Woo;Song, Tae Min;Lee, Hyeong Jun;Jeon, Yongmin;Kwon, Jeong Hyun
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.7-10
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    • 2022
  • A functional polyethylene terephthalate substrate to increase light extraction efficiency of organic light-emitting diodes is studied. We formed nano-structured PET surfaces by controlling the power, gas, and exposure time of the linear ion-beam. The haze of the polyethylene terephthalate can be controlled from 0.2% to 76.0% by changing the peak-to-valley roughness of nano structure by adjusting the exposure cycle. The treated polyethylene terephthalate shows average haze of 76.0%, average total transmittance of 86.6%. The functional PET increases the current efficiency of organic light-emitting diodes by 47% compared to that of organic light-emitting diode on bare polyethylene terephthalate. In addition to polyethylene terephthalate with light extraction performance, by conducting additional research on the development of functional PET with anti-reflection and barrier performance, it will be possible to develop flexible substrates suitable for organic light-emitting diodes lighting and transparent flexible displays.

Study on the Hydrophilicity of Modified Polyester (개질시킨 폴리에스테르 중합체의 친수성 연구)

  • Jung, Byung-Ok
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.930-934
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    • 1998
  • The modified poly(ethylene terephthalate) (PET) was synthesized by copolymerizing dimethyl terephthalate with ethylene glycol, polyethyleneglycol, and dodecylbenzene sulfonate as a surfactant. After characterization of viscosity, color, and contant angle, hydrophilic characteristics of the modified PET depending on additives was discussed.

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Experimental analysis of damage in short-fiber-reinforced composite waste polyethylene terephthalate as a pile foundation material

  • Jang, Hongseok;Seo, Segwan;Cho, Daesung
    • Steel and Composite Structures
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    • v.45 no.1
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    • pp.147-157
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    • 2022
  • This study assessed the compressive and tensile strengths and modulus of elasticity of waste polyethylene terephthalate (PET) using the ASTM standard tests. In addition, short carbon and glass fibers were mixed with waste PET to examine the improvements in ductility and strength during compression. The bonding was examined via field-emission scanning electron microscopy. The strength degradation of the waste PET tested under UV was 40-50%. However, it had a compressive strength of 32.37 MPa (equivalent to that of concrete), tensile strength of 31.83 MPa (approximately ten times that of concrete), and a unit weight of 12-13 kN/m3 (approximately half that of concrete). A finite element analysis showed that, compared with concrete, a waste PET pile foundation can support approximately 1.3 times greater loads. Mixing reinforcing fibers with waste PET further mitigated this, thereby extending ductility. Waste PET holds excellent potential for use in foundation piles, especially while mitigating brittleness using short reinforcing fibers and avoiding UV degradation.

Recovery of Polyethylene Telephthalate Monomer over Cu or Mn/γ-Al2O3 Catalysts (Cu, Mn/γ-Al2O3 촉매상에서 polyethylene telephthalate 단량체의 회수 연구)

  • Sim, Jae-Wook;Kim, Seung-Soo
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.485-489
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    • 2017
  • Polyethylene terephthalate (PET) has been widely applied in polymers and packaging industries to produce synthetic fibers, films, drink bottles or food containers. Therefore, it has become one of the major plastic wastes. In this article, glycolysis known as one of the main methods in PET chemical recycling was investigated using a glycol to break down the polymer into a monomer. Glycolysis of PET and ethylene glycol was performed in a micro-tubing reactor under various conditions. The effect of glycolysis conditions on the product distribution was investigated at experimental conditions of the EG/PET ratio of 1~4, the reaction time of 15~90 min and the reaction temperature of $250{\sim}325^{\circ}C$ with Mn and Cu catalysts. The highest yield of bis (2-hydroxyethyl) terephthalate monomer (BHET) was obtained as 89.46 wt% under the condition of the reaction temperature of $300^{\circ}C$ and the time of 30 min using 10 wt% $Cu/{\gamma}-Al_2O_3$ catalyst, with the PET and ethylene glycol ratio of 1 : 2.

Reduction of reflection from PET (polyethylene terephthalate) film surface by natural plasma etching

  • Oh, Hoon;Song, Yu-Jin;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1419-1424
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    • 2006
  • We could reduce the reflection from PET(polyethylene terephthalate) film surface by natural plasma etching which does not use etch masks. The plasma etched PET film showed lower reflectance and higher transmittance which is resulted by making subwavelength structure(SWS) on the film surface by the plasma etch rate difference between the amorphous and crystalline region in the surface of PET film.

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Preparation of PET non-woven by Electro-spinning (전기 방사를 이용한 PET(Polyethylene terephthalate) 부직포 제조)

  • 김관우;이근형;김학용;이덕래
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.177-178
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    • 2002
  • 일반적으로 폴리에틸렌테레프탈레이트(polyethylene terephthalate)는 에틸렌글리콜(ethylene glycol)과 테레프탈산(terephthalic acid) 또는 디메틸렌 테레프탈레이트(dimethylene terephthalate)를 중합시켜 만든다[1]. 폴리에스테르는 전도성 필름, 전기전자분야, 청량음료의 병 등으로 널리 사용되고 있다. 또한 뛰어난 강도, 내열성을 이용하여 자동차분야, 전기분야에서 금속, 페놀수지를 대체하는 용도로 사용되고 있다. (중략)

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Kinetic Analysis for the Catalytic Pyrolysis of Polyethylene Terephthalate Over Cost Effective Natural Catalysts

  • Pyo, Sumin;Hakimian, Hanie;Kim, Young-Min;Yoo, Kyung-Seun;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.706-710
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    • 2021
  • In the current research, thermal and catalytic thermogravimetric (TG) analysis of polyethylene terephthalate (PET) over natural zeolite (NZ), olivine, bentonite, HZSM-5, and HAl-MCM-41 were investigated using a TG analyzer and model-free kinetic analysis. Catalytic TG analysis of PET was carried out at multi-heating rates, 10, 20, 30, and 40 ℃/min, under nitrogen atmosphere. Apparent activation energy (Ea) values for the thermal and catalytic pyrolysis of PET were calculated using Flynn-Wall-Ozawa method. Although natural catalysts, NZ, olivine, and bentonite, could not lead the higher PET decomposition efficiency than synthetic zeolites, HZSM-5 and HAl-MCM-41, maximum decomposition temperatures on the differential TG (DTG) curves for the catalytic pyrolysis of PET, 436 ℃ over olivine, 435 ℃ over bentonite, and 434 ℃ over NZ, at 10 ℃/min, were definitely lower than non-catalytic pyrolysis. Calculated Ea values for the catalytic pyrolysis of PET over natural catalysts, 177 kJ/mol over olivine, 168 kJ/mol over bentonite, and 171 kJ/mol over NZ, were also not lower than those over synthetic zeolites, however, those were also much lower than the thermal decomposition, suggesting their feasibility as the proper and cost-effective catalysts on the pyrolysis of PET.

Catalytic Pyrolysis of Waste Polyethylene Terephthalate over Waste Concrete

  • Lim, Sejeong;Kim, Young-Min
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.707-711
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    • 2019
  • The feasibility of waste concrete as a catalyst for the effective pyrolysis of polyethylene terephthalate (PET) was examined using thermogravimetric (TG) and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) analyses. TG analysis results indicated that the maximum decomposition temperature of PET is not altered by the use of waste concrete, showing similar values (407 ℃ and 408 ℃ at 5 ℃/min). Meanwhile, the volatile product distribution data obtained from the Py-GC/MS analysis revealed that the use of waste concrete promoted the deoxygenation reaction via converting the oxygen containing products such as benzoic acids, benzoates, and terephthalates to valuable deoxygenated aromatic hydrocarbons including benzene, toluene, ethylbenzene, and styrene. This suggests that the waste concrete can be used as a potential catalyst for the production of valuable aromatic hydrocarbons from PET pyrolysis.

Surface Cleaning of Polyethylene Terephthalate Film with Non-equilibrium Atmospheric Discharge Plasma

  • Sung, Youl-Moon
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.2
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    • pp.79-83
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    • 2008
  • The dampness by treating the surface with polyethylene terephthalate (PET) film was measured to grasp the plasma parameters and was observed the surface condition with an atomic force microscope (AFM) to find the causes of the dampness. Also, the vibrational and rotational temperatures in the plasma were calculated after identifying the radicals within the plasma by analyzing the emission spectral with an emission spectrum. The hydrophilic properties were enhanced, by treating the surface of the PET film with non-equilibrium atmospheric discharge plasma. When the rotational temperature was 0.22 to 0.31 eV within the plasma, surface modification control could be easily carried out to surface treatment of PET film on non-equilibrium atmospheric pressure plasma.