• 한국도로학회논문집
• /
• 제15권4호
• /
• pp.43-51
• /
• 2013

PURPOSES : The main purposes of this study are to examine the influences of polyethylene wax-based WMA additive on the optimum asphalt content of warm-recycled asphalt mixture based on the Marshall mix design and to evaluate performance of warm-recycled asphalt mixture containing 30% RAP with polyethylene wax-based WMA additive. METHODS: Physical and rheological properties of the residual asphalt were evaluated in terms of penetration, softening point, ductility and performance grade (PG) in order to examine the effects of polyethylene wax-based WMA additive on the residual asphalt. Also, To evaluate performance characteristics of the warm-recycled asphalt mixtures using polyethylene wax-based WMA additive along with a control hot-recycled asphalt mixture, indirect tensile strength test, modified Lottman test, dynamic immersion test, wheel tracking test and dynamic modulus test were conduced in the laboratory. RESULTS : Based on the limited laboratory test results, polyethylene wax-based WMA additive is effective to decrease mixing and compacting temperatures without compromising the volumetric characteristics of warm-recycled asphalt mixtures compared to hot-recycled asphalt mixture. Also, it doesn't affect the optimum asphalt content on recycled-asphalt mixture. All performance test results show that the performance of warm-recycled asphalt mixture using polyethylene wax-based WMA additive is similar to that of a control hot-recycled asphalt mixture. CONCLUSIONS: Overall, the performance of warm-recycled asphalt mixture using polyethylene wax-based WMA additive is comparable to hot-recycled asphalt mixture.

• Korean Chemical Engineering Research
• /
• 제50권2호
• /
• pp.223-228
• /
• 2012

ABS와 폴리에틸렌(Polyethylene, PE) 및 ABS-PE 혼합물의 저온열분해를 회분식 반응기를 이용하여 상압 및 $450^{\circ}C$에서 실행하였다. 열분해 시간은 20~80분까지 하였고 열분해로 생성된 성분은 지식경제부에서 고시한 증류성상온도에 따라 가스, 가솔린, 등유, 경유, 중유로 분류하였다. ABS와 PE의 혼합 폐플라스틱의 열분해 전환율은 PE의 함량이 증가할수록 증가하는 것으로 나타났다. 열분해생성물의 수율은 PE의 함량이 높을수록 중유 > 가스 > 가솔린 > 경유 > 등유 순으로 회수되었다.

• 한국응용과학기술학회지
• /
• 제25권4호
• /
• pp.495-502
• /
• 2008

To investigate the synergy effect on the pyrolysis of mixture of polyethylene(PE) and polystyrene(PS), the pyrolysis of PE, PS and the mixture of PE-PS was carried out in a batch reactor at the atmospheric pressure and $450^{\circ}C$. The pyrolysis time was from 20 to 80 mins. The liquid products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the distillation temperatures based on the petroleum product quality standard of Korea Institute of Petroleum Quality. The analysis of the product oils by GC/MS showed that the new components produced by mixing were not detected. The synergy effect according to mixing of PE and PS did not also appear. The conversion and yield of mixtures were in proportion to the mixing ratio of sample.

• Elastomers and Composites
• /
• 제36권4호
• /
• pp.246-254
• /
• 2001

본 연구에서는 CSM 고무를 유화하기 위하여 계면화학적 성질을 이용한 반전유화법과 계면활성제로서 비이온 및 음이온 계면활성제를 혼합 사용하였다. 단독계면활성제를 사용하였을 때에는 에멀젼의 분리가 발생하였고, 비이온 계면활성제 Span 60과 음이온 계면활성제 SLS를 혼합 사용하는 경우에는 상의 분리가 발생하지 않았다. 그러므로 혼합계면활성제를 사용하여 제조한 에멀젼의 droplet size, 전단속도에 따른 점도 및 전단응력과 같은 유변학적 거동을 통하여 에멀젼의 안정성을 규명하였다. 혼합계면활성제의 양에 따라 droplet size는 감소하였고, 이에 점도는 증가하였으며, 전단속도에 따른 점도 및 전단응력 측정결과 각각 non-Newtonian 흐름인 shear thinning 거동과 항복응력 값을 보였다. 이러한 실험결과인 유변학적 거동으로부터 CSM 고무를 유화하기 위해서는 반전유화법과 혼합계면활성제를 사용함으로써 에멀젼의 안정성을 향상시켰음을 확인할 수 있었다.

• 대한전자공학회논문지
• /
• 제13권4호
• /
• pp.6-11
• /
• 1976

beewax와 polyethylene을 혼합한 모체에 탄색 및 연분말을 징량첨가시켜서 정특성감온소자를 제조하였다. C.(beewax·Polyethylene)시편은 온도범위 20°∼90℃에서 104-1010Ωcm의 PTC특성을 나타내었으며 제조과정상에 분말혼합 및 가압냉각방법를 도입함으로써 그 재현성과 안정성을 현저히 개선시킬 수 있었다. 또한 Fe-(betwax· polyethylene)시편은 같은 온도범위에서 102-1010Ωcm의 PTC특성을 나타내었으며 저저항범위에서 PTC효과를 얻을 수 있었다. The carbon (the iron) -beewax·polyethylene thermistors have been prepared by heating the well ground mixture of carbon (iron), beewax and polyethylene at 160℃ for one hour and by cooling it under pressure of 12kgw/cm2. The resistivity for the former (the latter) increased from 102Ω·cm (104Ω·cw) to 1010Ω·cm(1010Ω·cm) as temperature changed from 20℃ to 90℃. The resistivity, 102Ω·cm at room temperature for the former, was lower by order Q( two than that for the papostor made by the earlier reporter. The reproducibility, which has been an important Problem for this type of thermistors to be industrialized, was improved by introducing pressure in cooling procedure for both carbon and iron thermistors.

• 청정기술
• /
• 제15권2호
• /
• pp.109-115
• /
• 2009

폴리에틸렌-폴리프로필렌 혼합물의 열분해에 대한 시너지효과를 조사하기 위하여 폴리에틸렌(PE)과 폴리프로필렌(PP) 및 PE-PP혼합물의 저온열분해를 회분식 반응기를 이용하여 상압 및 $450^{\circ}C$에서 실행하였다. 열분해 시간은 20${\sim}$80분이었으며, 열분해로 생성된 성분은 한국석유품질검사소에서 고시한 증류성상온도에 따라 가스, 가솔린, 등유, 경유, 중유로 분류하였다. GC/MS에 의한 생성오일의 성분분석 결과 PE-PP 혼합에 의해서 새로운 성분이 검출되지 않았고 혼합에 따른 시너지효과 또한 나타나지 않았다. PE-PP 혼합물의 전환율과 각 생성물의 수율은 시료의 혼합비율에 비례하였다.

• 한국도로학회논문집
• /
• 제4권1호
• /
• pp.161-170
• /
• 2002

본 연구는 폐폴리에틸렌필름(폐비닐)을 아스팔트 혼합물에 첨가하여 아스팔트 포장재료의 품질특성을 향상시키고 환경적으로 문제가 되고 있는 폐비닐을 재활용하기 위한 연구의 일환으로 수행되었다. 폐비닐 사용시 나타날 수 있는 포장체의 특성을 파악하기 위하여 국내에서 가장 많이 수거되는 LDPE 폐비닐을 사용하여 현장에서의 실용성을 고려한 건식혼합법으로 아스팔트 혼합물을 제조하였다. 제조한 혼합물에 대하여 마샬안정도 시험, 간접인장강도 시험, 반복주행시험 및 피로시험을 수행한 결과 폐비닐을 혼합한 혼합물이 일반혼합물에 비하여 인장강도가 향상되고 윤하중에 의한 소성변형 저항성 및 피로균열 저항에 크게 효과적인 것으로 나타났다.

• 한국안전학회지
• /
• 제14권2호
• /
• pp.83-89
• /
• 1999

The electrical properties due to mixture ratio of linear low density polyethylene(LLDPE) and ethylene vinyl acetate(EVA) films are studied. An experimental specimen is selected as LLDPE/EVA of thickness 200${\mu}{\textrm}{m}$ produced by mixture ratio of 50 : 50, 60 : 40, 70 : 30 and 80 : 2 wt%. In temperature range from $25^{\circ}C$ to 12$0^{\circ}C$, the measurement of volume resistivity using a highmegohm meter is performed within 10 minutes since each voltage of DC 100 V, 250 V, 500 V and 1000 V is applied, according to the step voltage method. From FT-IR spectrum for an analysis of physical properties, it can be confirmed that LLDPE blended with EVA shows an absence of carbonyl groups(1735 $cm^{-1}$, C=0) and ether groups(1242 $cm^{-1}$, C-O). The peak of LLDPE and EVA made of mixture ratio of 70 : 30 at 2$\theta$ =21.4$^{\circ}$ in the results of XRD is higher than the others. In the experiment for volume resistivity characteristics in order to investigate the electrical properties of specimen, it is confirmed that volume resistivity is decreased with the increase of the molecular motion and temperature.

• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.226-226
• /
• 2006

Ethylene was polymerized with a catalyst having sterically hindered pentamethylcyclopentadienyl ligand, $Cp^{\ast}_{2}ZrCl_{2}/MAO$, and the polymerization mixture were treated with dry oxygen (oxidative workup) to produce hydroxyl-terminated polyethylenes (PE-OH). Polyethylene-block-Poly (${\Box}-caprolactone$) was synthesized from PE-OH and ${\cdot}\^{A}-caprolactone$A by using stannous octoate as a catalyst for ring opening polymerization of ${\cdot}\^{A}-caprolactone$. Polyethylene-block-Poly(methyl methacrylate) was obtained by transforming the hydroxyl-terminated polyethylenes to macroinitiators for atom transfer radical polymerization (ATRP) and by reacting them with MMA.

• Journal of Nutrition and Health
• /
• 제29권2호
• /
• pp.153-158
• /
• 1996

Polyethylene glycols(PEGs)are hydrophilic molecules that have been used to characterize intestinal permeability via the paracellular pathway. Using a mixture of PEGs(400, 600 and 1000), containing oligomers in the molecular weight range 330 to 1122 D, the molecular weight permeability dependence in the jejunum of the rat small intestine was examined, employing an in situ recirculation perfusion technique. Individual oligomers were determined by HPLC with refractive detection. In the range studied, a distinct molecular weight cut-off was not apparent. Corrected for the length of jejunum used in the study, over the molecular weight range 330 to 1122D, the apparent permeability(Papp) of PEG ranged from 4.92$\pm$0.02$\times$10-5cm/sec(mean$\pm$SEM, n=5) to 0.28$\times$10-5cm/sec. Also, it was observed that the apparent permeability was inversely proportional to approximately MW2. The results in this study suggest that molecular weight is an important factor in determining the intestinal permeability.