• Title/Summary/Keyword: polyester system

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Improvement of Tensile Strength of Polyester Resin Using Silica/Chopped Glass Fiber Modified by Coupling Agent (실란 처리된 실리카 및 절단 유리섬유에 의한 폴리에스테르 수지의 인장강도 향상)

  • Lee, Jeon-Kyu;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.30-34
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    • 2012
  • For the purpose of development of polymeric material for marine applications, the effects of silica and chopped glass fiber on tensile strength of polyester resin were studied. A series of experiments were performed with different contents of silica and chopped glass fiber. Tensile strength of polyester resin was increased with the contents of unmodified glass fiber, and decreased with that of silica. The surfaces of silica and chopped glass fiber were modified with coupling agent at different concentrations, and the modification showed positive effect on the increase of tensile strength of polyester resin. Synergistic effect on the tensile strength of polyester resin was observed by modified silica and chopped glass fiber.

Castor oil based hyperbranched polyester/bitumen modified fly ash nanocomposite

  • Bhagawati, Deepshikha;Thakur, Suman;Karak, Niranjan
    • Advances in nano research
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    • v.4 no.1
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    • pp.15-29
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    • 2016
  • A low cost environmentally benign surface coating binder is highly desirable in the field of material science. In this report, castor oil based hyperbranched polyester/bitumen modified fly ash nanocomposites were fabricated to achieve the desired performance. The hyperbranched polyester resin was synthesized by a three-step one pot condensation reaction using monoglyceride of castor oil based carboxyl terminated pre-polymer and 2,2-bis (hydroxymethyl) propionic acid. Also, the bulk fly ash of paper industry waste was converted to hydrophilic nano fly ash by ultrasonication followed by transforming it to an organonano fly ash by the modification with bitumen. The synthesized polyester resin and its nanocomposites were characterized by different analytical and spectroscopic tools. The nanocomposite obtained in presence of 20 wt% styrene (with respect to polyester) was found to be more homogeneous and stable compared to nanocomposite without styrene. The performance in terms of tensile strength, impact resistance, scratch hardness, chemical resistance and thermal stability was found to be improved significantly after formation of nanocomposite compared to the pristine system after curing with bisphenol-A based epoxy and poly(amido amine). The overall results of transmission electron microscopic (TEM) analysis and performance showed good exfoliation of the nano fly ash in the polyester matrix. Thus the studied nanocomposites would open up a new avenue on development of low cost high performing surface coating materials.

Effect of Air-jet Texturing Conditions on the Physical Properties of Low Melting Polyester/Tencel Composite Yarn (에어제트 텍스처링 조건이 저융점 폴리에스터/텐셀 복합사의 물리적 특성에 미치는 영향)

  • Lee, Sun Young;Yoo, Jae Jung;Choi, Oh Gon;Lee, Si Woo;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.25 no.1
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    • pp.47-55
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    • 2013
  • Physical properties of the composite yarn using low-melting(LM) polyester/Tencel were investigated with air-jet texturing conditions such as temperature, take-up overfeed, yarn speed and air pressure. Surface morphology, microstructure, tensile property, glossiness were evaluated. Surface morphology of a composite yarn had more damaged and loosened structure according to increase of take-up overfeed, yarn speed and air pressure. Crystallinity was affected by parameters such as temperature, yarn speed, take-up overfeed and air pressure and especially, yarn speed was most effective for increase of crystallinity. Also, it was found that temperature and air pressure had significantly affected tensile properties of a composite yarn. The glossiness of yarn increased with increase of temperature, yarn speed and air pressure.

An Evaluation of Factors Influencing the Thermal Insulation and Evaporative Resistance of a Waterproof and Breathable Garment System (투습방수의류의 보온력 및 증발저항 평가와 관련 변인)

  • Shim, Huen sup
    • The Korean Journal of Community Living Science
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    • v.25 no.4
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    • pp.549-556
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    • 2014
  • This study evaluates the thermal insulation and evaporative resistance of a waterproof and breathable garment system and determines the factors influencing its thermal performance. The experimental garments were composed of underwear (shirts with 100% wool and 100% polyester) and outerwear (jackets and pants with a vapor-permeable membrane and a vapor-impermeable membrane). Data on clothing insulation in a dry condition ($10^{\circ}C$) and a wet condition ($10^{\circ}C$, 40% R.H.), evaporative resistance ($34^{\circ}C$, 40% R.H., and $10^{\circ}C$, 40% R.H.), and microclimate vapor pressure were collected and analyzed. According to the results, the thermal insulation of the experimental garment system ranged 1.27~1.40 in the dry condition and 0.40~0.89 in the wet condition at $10^{\circ}C$. Evaporative resistance ranged $41{\sim}525m^2Pa/W$. A decrease in thermal insulation by wetting underwear ranged 31~67% in the cold condition ($10^{\circ}C$). The breathability of the outer garment influenced the decrease in thermal insulation by wetting. The type of underwear fiber influenced the decrease in thermal insulation only when it was used with breathable outerwear. The vapor-permeable outerwear sample with polyester underwear (P_Perm) showed a larger decrease in insulation than that with wool (W_Perm). The evaporative resistance of the vapor-permeable ensemble showed no effect of underwear in the warm condition ($34^{\circ}C$), but polyester underwear showed lower evaporative resistance than wool in the cold condition ($10^{\circ}C$). The vapor-impermeable ensemble showed no difference in evaporative resistance between polyester underwear and wool underwear in both conditions. Future research should consider various clothing ensemble combinations and environmental conditions and evaluate wear comfort by using human subjects.

Fitness and Physical Properties in Current Stretch Fabrics for Bottoms -Focused on the Tight Skirt- (하의용 시판 신축성 소재의 물리적 특성과 맞음새에 과한 연구 -스커트를 중심으로-)

  • 이진희;최혜선;도월희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.10
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    • pp.1467-1477
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    • 2002
  • This study was investigated physical properties of stretch fabrics by KES-FB system to show suitable basic data to making skirts of excellent capacity and develop more organized basic skirt pattern by fitness evaluation. 1. The results of T. H. V.(Total Hand Value) were as followa: In the kind of blending fiber, cotton/spandex was more excellent than nylon/spandex and polyester/spandex, in the direction of stretch, one-way(weft inserted polyurethan yarn) polyester/spandex and cotton/spandex were higher than two-way(warp and wet inserted polyurethan yarn) polyester/spandes and cotton/spandex, two-way nylon/spandex was higher than one-way nylon/spandex. 2. The results of calculating the variance between sample stretch fabrics and Japanese s/s women's suit fabrics after standardizing were as follows: Stretch fabrics has 2 range of tensile, bending, shearing, compression, surface, thickness and weight as compared with Jpanese s/s women's suit fabrics. In the tensile property, one-way stretch fabrics were almost the same with Japanese s/s women's suit fabrics, only two-way polyester/spandex had+1~+2 range. In the bending, shear property, there was no difference between sample fabrics and Japanese s/s women's suit fabrics 3. In the total fitness of the skirt, nylon/spandex is the best in the fabrics and one-way stretch fabric is better than two-way strethch fabric.

A Study on the Bending Properties of Fabrics for Korean Women's Clothes (부인용 한복지의 굽힘특성에 관한 연구)

  • 성수광
    • Journal of the Korean Home Economics Association
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    • v.26 no.1
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    • pp.11-19
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    • 1988
  • Bending properties of 168 commercial silk fabrics and polyester fabrics for korean women's clothes were tested by KES-F system. Samples were classified into for summer, fall & winter fabrics. In this study, bending regidity(B) and bending hysteresis(2HB) were measured, then 2HB/W, {{{{ SQRT { 2HB/W} }}}}, 2HB/B which are concerning to formation of weared clothes and transformation behavior were investigated. fabrics for korean women's silk clothes for fall & winter were compared with fabrics for japanese kimono clothes on the bending properties. The results were as follows : 1. The bending regidity of silk fabrics were higher than polyester fabrics and bending hysteresis of fall & winter fabrics were higher than summer fabrics. 2. The 2HB/W and {{{{ SQRT { 2HB/W} }}}} of polyester fabrics were lower than silk fabrics. 3. the silk fabrics for summer clothes were the least in 2HB/B. 4. Silk fabrics for korean women's clothes were almost the same in bending rigidity, bending hysteresis and thickness of fabrics for japanese kimono clothes, but weight of the silk fabrics were lower to fabrics for jpanese kimono clothes.

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Dielectric Characterization of Unsaturated Polyester Curing (불포화 폴리에스터의 경화에 따른 유전특성 연구)

  • 오경성;김홍경;김명덕;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.728-736
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    • 2002
  • The thermal and dielectric properties of unsaturated polyester resin system during cure were analyzed under Isothermal conditions. Both $varepsilon$′ and $varepsilon$" decreased and dipole relaxation was observed under isothermal conditions during cure. The ionic conductivity decreased linearly with the conversion according to the Kienle-Rate equation (ln($varepsilon$"$_{ionic}$we$_{0}$)=C$_{r}$$alpha$+C$_{0}$) up to $alpha$=0.15, after which it aparted from the relationship due to the entanglement of polymer chains. The effect of ionic conductivity was revealed to be larger than that of dipole motion during the whole cure through the electrical modulus analysis. Although dielectric motion was analyzed with Debye model, it was observed only at a narrow time region of middle stage of cure. In order to estimate the dielectric properties during the whole cure, the Havriliak-Negami model was considered and modified with the strong effect of ionic conductivity. The changes of $varepsilon$′ and $varepsilon$" were well estimated with this modified Havriliak-Negami model.

Dyeing Properties of Polyester Ultrarmicrofiber (초극세 폴리에스테르 섬유의 염색성)

  • 정동석;김호정;이문철
    • Textile Coloration and Finishing
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    • v.11 no.3
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    • pp.1-8
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    • 1999
  • Polyester ultrarmcrofiber(UMF, fiber fineness : 0.05d) and the other three kinds of polyester fibers(0.52, 1.04 and 2.08d) were dyed with two disperse dyes, C.1. Disperse Red 60 and Blue 56. Dyeing rates and absorption isotherms of these dyes have been measured at 100, 115 and $130^\circ{C}$ in water system. The dye bath was maintained at pH 5.0 with acetic acid(0.1mo1/1) /sodium acetate(0.1mo1/1) buffers and a liquor ratio of 1000:1. The absorption isotherms from two disperse dyes are nearly linear up to the saturation values, which increase with the temperature of dyeing. Dye uptake decreased with the fiber fineness in lower temperature $100^\circ{C})$, whereas increased in higher temperature$(130^\circ{C})$. A comparatively greater quantity of dye is necessary to dye ultrarmcrofiber fabrics than conventional fabrics. Disperse Blue 56 having a good build-up property is agreed to Fothergill's equation, which is inversely varied with the fiber fineness by the quantity of dye necessary to obtain a given shade.

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Miscibility and Thermal Behavior of Biodegradable Synthetic Aliphatic Polyester (Bionolle) and Poly(epichlorohydrin) Blends (생분해성 지방족 폴리에스테르(Bionolle)와 폴리에피클로로하이드린 블렌드의 상용성 및 열적 거동에 관한 연구)

  • 김진호;최형진;이동주;윤진산;진인주
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.358-365
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    • 2000
  • Miscibility itnd thermal behavior of blends of synthetic biodegradable aliphatic polyester (Bionolle) with poly(epichlorohydrin) (PECH) were investigated by a differential scanning calorimetry (DSC), a dynamic mechanical thermal analyzer (DMTA) and a rotational rheometer. Observed both single glass transition temperatures from the DSC in agreement with the Fox equation and single T$_{g}$ changes as a function of composition from the DMTA indicate that these blend mixtures are miscible. In addition, the miscibility of this blend system was also observed from the single curve of the Cole-Cole Plot of log G′($\omega$) vs. log C"($\omega$) from the dynamic test using a rotational rheometer. This was further verified from the cryogenically fractured surface of BDP/PECH blends by scanning electron microscopy.

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Consumer Needs and Sensory Evaluation of Jacquard Fabrics for Blind Using Low Melting Polyester (저융점 폴리에스터를 이용한 블라인드용 자카드 직물의 소비자 요구도 및 감성구조)

  • Kim, Jeong Hwa;Lee, Jung Soon;Lee, Sung Young;Lee, Seung Gu
    • Korean Journal of Human Ecology
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    • v.22 no.6
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    • pp.673-686
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    • 2013
  • The purpose of this study is to identify consumer needs and sensory evaluation of jacquard fabrics for blind using low melting polyester. Ten kinds of jacquard fabric used for this study were developed. Developed jacquard fabrics were assessed subjectively by 164 consumers using 7-point scale of 22 consumer needs and 43 sensory descriptors. The results were briefly summarized as follows: the most important parameter to choose fabric for blind was 'Easy-use' and the other parameters are 'Lightproof', 'UV-protect', 'Design', 'Price', 'Color', 'Insulation', 'Easy-care'. The image sensibility of jacquard fabrics was explained by six factors: feminine, active, modern, traditional, pure, cozy. Higher preference was found in jacquard fabrics of clear, natural, luxurious, simple, feminine, young, cozy, graceful image. The preference was predicted 38.2% with feminine, modern, pure, cozy, traditional factors. Correlation coefficient between image sensibility factor 1 and preference was 0.437. The 3 factors (feminine, modern, pure)were selected as significant image sensibility affecting preference.