• Polymer(Korea)
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• v.28 no.4
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• pp.344-351
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• 2004

Poly(ethylene glycol)-based diblock and triblock polyester copolymers stimulating to temperature were studied as injectable biomaterials in drug delivery system because of their nontoxicity, biocompatibility and biodegradability. We synthesized the diblock copolymers consisting of methoxy poly(ethylene glycol) (MPEG) (M$_{n}$=750 g/mole) and poly($\varepsilon$-caprolactone) (PCL) by ring opening polymerization of $\varepsilon$-CL with MPEG as an initiator in the presence of HCl . Et$_2$O. The aqueous solution of synthesized diblock copolymers represented sol phase at room temperature and a sol to gel phase transition as the temperature increased from room temperature to body temperature. To confirm the in vivo gel formation, we observed the formation of gel in the mice body after injection of 20 wt% aqueous solution of each block copolymer. After 2 months, we observed the maintenance of gel without dispersion in mice. In this study, we synthesized diblock copolymers exhibiting sol-gel phase transition and confirmed the feasibility as biomaterials of injectable implantation.n.

• Computers and Concrete
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• v.23 no.1
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• pp.61-68
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• 2019

This paper presents a computational rational model to predict the ultimate and optimized load capacity of reinforced concrete (RC) beams strengthened by a combination of longitudinal and transverse fiber reinforced polymer (FRP) composite plates/sheets (flexure and shear strengthening system). Several experimental and analytical studies on the confinement effect and failure mechanisms of fiber reinforced polymer (FRP) wrapped columns have been conducted over recent years. Although typical axial members are large-scale square/rectangular reinforced concrete (RC) columns in practice, the majority of such studies have concentrated on the behavior of small-scale circular concrete specimens. A high performance concrete, known as polymer concrete, made up of natural aggregates and an orthophthalic polyester binder, reinforced with non-metallic bars (glass reinforced polymer) has been studied. The material is described at micro and macro level, presenting the key physical and mechanical properties using different experimental techniques. Furthermore, a full description of non-metallic bars is presented to evaluate its structural expectancies, embedded in the polymer concrete matrix. In this paper, the mechanism of mechanical interaction of smooth and lugged FRP rods with concrete is presented. A general modeling and application of various elements are demonstrated. The contact parameters are defined and the procedures of calculation and evaluation of contact parameters are introduced. The method of calibration of the calculated parameters is presented. Finally, the numerical results are obtained for different bond parameters which show a good agreement with experimental results reported in literature.

• Textile Coloration and Finishing
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• v.34 no.2
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• pp.109-116
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• 2022

Tire codes are made of materials such as hemp, cotton, rayon, nylon, steel, polyester, glass, and aramid are fiber reinforcement materials that go inside rubber to increase durability, driveability, and stability of vehicle tires. The reinforcement of the tire cord may construct a composite material using tires such as automobiles, trucks, aircraft, bicycles, and fibrous materials such as electric belts and hoses as reinforcement materials. Therefore, it is essential to ensure that the adhesive force between the rubber and the reinforced fiber exhibits the desired physical properties in the rubber composite material made of a rubber matrix with reinforced fibers. This study is a study on the heat treatment conditions for improving the adhesion strength of the tire cord and the reinforced fiber for tires. The core technology of the drying process is a uniform drying technology, which has a great influence on the quality of the reinforcement. Therefore, the uniform airflow distribution is determined by the geometry and operating conditions of the dryer. Therefore, this study carried out a numerical analysis of the shape of a drying nozzle for improving the performance of hot air drying in a dryer used for drying the coated reinforced fibers. In addition, the flow characteristics were examined through numerical analysis of the study on the change in the shape of the chamber affecting drying.

• Korean Journal of Ecology and Environment
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• v.39 no.1 s.115
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• pp.85-92
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• 2006

To evaluate the primary production and nutrient uptake of macrophytes in Lake Paldang, this study investigate the vegetation areas of six dominant aquatic plants including Typha angustifolia, Zizania latifolia, Phragmites australis, Trapa japonica, Nelumbo nucifera and Savinia natans, and contents of carbon, nitrogen and phosphorus of each macrophyte. Total vegetation area of six dominant aquatic plants was 1.37 $km^2$. Among them, Typha angustifolia was the most wide-distributed species which occupied the 46.7% of total vegetation area. Littoral zone of South Han river had the largest vegetation area with 0.458 $km^2$, and North Han river, Kyungan river and confluence area in the order named. The results of the contents of carbon, nitrogen and phosphorus of macrophytes showed that the carbon contents of emergent macrophytes was higher than that of other life-forms. The nitrogen content of Salvinia natans, free-floating macrophyte was highest and that of Typha angustifolia, emergent macrophyte was lowest. The phosphorus content of Trapa japonica showed the highest content of phosphorus among six macrophytes and emergent macrophytes such as Zizania latifolia and Phragmites australis showed lower contents of phosphorus than other life-forms. The annual net primary production of macrophytes in Lake Paldang, 2004, was calculated as 758.4 ton C $yr^{-1}$ and the annual net nitrogen and phosphorus uptake of macrophyte was 16,921 kg $yr^{-1}$ and 1,841.0 kg P $yr^{-1}$ respectively. Comparing the total budget of organic carbon, nitrogen and phosphorus in Lake Paldang, the amount of primary production and nutrient uptake by macrophytes take a small portion in total budget implying macrophytes do not play an important role in budget of matters in river-type lake, Lake Paldang.

• Polymer(Korea)
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• v.38 no.6
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• pp.815-819
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• 2014

Scaffolds of tissue engineering should be biocompatible and biodegradable for cell attachment, proliferation and differentiation. In the various scaffold fabrication, 3D printing technique can make the three dimensional scaffold with interconnected pores for cell ingrowth. Polycaprolactone (PCL) is biodegradable polyester with a low melting temperature and has been approved by the Food and Drug Administration (FDA). In this study, PCL scaffold was fabricated by 3D bioprinting system and surface modification of PCL scaffold was controlled by NaOH treatment. Morphological change and wetability of NaOH-treated scaffold were observed by SEM and contact angle measurement system. The remnant of PCL treated with NaOH was measured by ATR-FTIR. In vitro study of scaffolds was evaluated with WST-1 and ALP activity assay. NaOH treatment of PCL scaffolds increased surface roughness, hydrophilicity, cell proliferation and osteogenic differentiation. These results indicate that NaOH-treated PCL scaffold made by 3D bioprinting has tissue engineered potential for the development of biocompatible material.

• Corrosion Science and Technology
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• v.12 no.1
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• pp.1-6
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• 2013

Recently Digital TV industry has drastically been moving the illuminating system, which causes an obvious product change from PDP and LCD to LED model to provide high-definition image. Due to strong competition in the digital industry, TV manufacturers make a great efforts to reduce production cost by using low-priced materials such as steels instead of aluminum and plastic etc. In this paper we have developed a new low-priced electrogalvanized steel sheet, which has a black resin composite layer, to substitute conventional high-priced PCM steel and plastic mold for rear cover panel in the digital TV. The black resin composite was prepared by mechanical dispersion of the mixture solution that consists of high solid polyester resin, melamine hardener, black pigment, micronized silica paste, polyacrylate texturing particle and miscellaneous additives. The composite solution was coated on the steel sheet using roll coater followed by induction furnace curing and cooling. Although the coated layer has a half thickness compared to the conventional PCM steels having $23{\mu}m$ thickness, it exhibits excellent quality for the usage of rear cover panel. The new steel sheet was applied to test products to get quality certification from worldwide electronic appliance customers. Detailed discussion provides in this paper including preparation of composite solution, roll coating technology, induction curing technology and quality evaluation from customers.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.31 no.4
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• pp.362-371
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• 1995

This study describes with the sinking behaviour for the purse seine. The experiment was carried out using three model purse seines of knotless netting. The nettings were woven in same leg length(10.5mm) of polypropylene 170 denier, polyamide 210 denier and polyester 250 denier two thread ply twine, each of the seines were named PP seine, PA seine and PES seine. Dimension of Purse seine models were 420cm for corkline and 85cm for seine depth, each models rigged 65.8g, 50.6g and 35.8g(weight in water) of lead for a leadline, seine models will have the same weight in water. Experiments carried out in the observation channel in a flume tank under still water conditions. Sinking motion was recorded by the one set of TV-camera for VTR, and reading coordinate carried out by the video digitization system. The results obtained were as follows: 1) Netting bundle for PP seine was existence on the surface of the water, spread out a netting by sinking force of sinkers. 2) Netting bundle for PES seine was existence in the middle of corkline and leadline. 3) Average sinking speed of seine margin was fastest for 10.7cm/s of PP seine, followed by 9.7cm/s of PA and 9.2cm/s of PES seines. 4) In all seines, the force of horizontal movement for the seine setting was values of ranged in disregard.

• Polymer(Korea)
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• v.30 no.3
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• pp.196-201
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• 2006

Poly (ethylene glycol)-based diblock and triblock thermo- sensitive polyester copolymers were investigated for application on tissue engineering and injectable biomaterials in drug delivery system due to their nontoxicity, biocompatibility and biodegradability. We synthesized the diblock copolymers consisting of methoxy poly (ethylene glycol) (MPEG) (Mn=750 g/mole) and poly $(\varepsilon-caprolactone)$ (PCL) by ring opening polymerization of $\varepsilon-CL$ with MPEG as an initiator in the presence of HCl $Et_2O$. The effect of diblock copolymers on in vivo osteogenic differentiation of rat bone marrow stromal cells (BMSCS) with and without the presence of osteogenic supplements (dexamethasone) was investigated. Thin sections were cut from paraffin embedded tissues and histological sections were stained by H&E, von Kossa, and immunohistochemical staining for osteocalcin. In conclusion, dexamethasone containing thermo- sensitive hydrogel might be improved osteogenic differentiation of BMSCs. We expect the osteoinduction effect to be excellent when it uses stem cell or other osteogenic materials.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.263-263
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• 2006

Poly (ethylene glycol)(PEG) - Poly (${\varepsilon}-caprolactone(CL)$) - Poly (D,L lactide(LA) (PCLA-PEG-PCLA) was synthesized by ring-opening polymerization to form temperature sensitive hydrogel triblock copolymer. The triblock copolymer was acrylated by acryloyl chloride. ${\beta}-amino$ ester was used as a pH sensitive moiety, in this study ${\beta}$- amino ester obtained from 1,4-butandiol diacrylate, and 4, 4' trimethylene dipiperidine, it have pKb around 6.6. pH/temperature sensitive penta-block copolymer (PAE-PCL-PEG-PCL-PAE) was synthesized by addition polymerization from acrylated triblock copolymer, 1,4-butandiol diacrylate, and 4, 4' trimethylene dipiperidine. Their physicochemical properties of triblock and penta-block copolymers were characterized by $^1H-NMR$ spectroscopy and gel permeation spectroscopy. Sol-gel phase transition behavior of PAE-PCL-PEG-PCL-PAE block copolymers were investigated by remains stable method. Aqueous media of the penta-block copolymer (at 20 wt%) changed from a sol phase at pH 6.4 and $10^{\circ}C$ to a gel phase at pH 7.4 and $37^{\circ}C$. The sol-gel transition properties of these block copolymers are influenced by the hydrophobic/hydrophilic balance of the copolymers, block length, hydrophobicity, stereo-regularity of the hydrophobic of the block copolymer, and the ionization of the pH function groups in the copolymer depended on the changing of environmental pH, respectively. The degradation and the stabilization at pH 7.4 and $37^{\circ}C$, and the stabilization at pH 6.4 and $10^{\circ}C,\;5^{\circ}C,\;0^{\circ}C$, of the gel were determined. The results of toxicity experiment show that the penta block copolymer can be used for injection drug delivery system. The sol?gel transition of this block copolymer also study by in vitro test ($200{\mu}l$ aqueous solution at 20wt% polymer was injected to mouse). Insulin loading and releasing by in vitro test was investigated, the results showed that insulin can loading easily into polymer matrix and release time is around 14-16days. The PAE-PCL-PEG-PCL-PAE can be used as biomaterial for drug, protein, gene loading and delivery.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.34 no.3
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• pp.274-282
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• 1998

This study deals with sinking resistance for purse seine, in the case of different d/l, ratio of twine diameter and leg length. Experiments carried out on the six types simplified reduced model seines which were made of knotless netting. The nettings were woven in different leg length 4.3, 5.0, 5.5, 6.0, 6.6 and 7.7mm of polyester 28 tex two threads two -ply twine, and each of the seines were named I, II, III, IV, V and Ⅵ seine. Dimension of seine models were 450cm for corkline and 85cm for seine depth, each seines rigged up 160g of float for a floatline and 50g (underwater weight) of lead for a leadline. Experiments were measured in the observation channel of a flume tank at the static conditions Sinking motion was recorded by the two sets TV-camera for VTR which were placed in top and side of the model seine, and reading coordinate carried out by the video digitization system. An analysis were calculated out by simultaneous differential equations for numerical method by Runge - Kutta - Gill sub - routine. The results obtained were as follows: 1. Average sinking speed of seine of seine margin was fastest for Ⅵ seine followed by V, IV, III, II and I seines. 2. The coefficient of resistance for a seine wall was depended upon the ratio of d/l : KD =0.081 (d/l )-0.5 3. The coefficient of resistance for netting bundle was not depended upon the ratio of d/l :CR = 0.91 (), d : Twine diameter, l : Leg length, : Density of netting materals, $\omega$ : Density of water