• 제목/요약/키워드: polyamide

검색결과 409건 처리시간 0.027초

이성분계 고분자 블렌드의 형태학에 미치는 사출 조건의 영향 (Effect of injection molding conditions on morphology of binary polymer blends)

  • 손영곤
    • 한국산학기술학회논문지
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    • 제9권1호
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    • pp.165-169
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    • 2008
  • 사출 조건이 이성분계 고분자 블렌드의 형태학에 미치는 영향을 관찰하기 위해 폴리페닐렌옥사이드 (PPO)/폴리아마이드 6 (PA 6) 블렌드를 선정하였다. 두께가 3.2 mm이고 한 변의 길이가 15 cm인 정사각형의 평판 형태의 사출물을 여러 사출 조건에서 제조하고 각 위치별로 파단시편을 제조하여 형태학을 관찰하였다. 그 결과 수지가 스크류, 노즐 스프루 게이트를 지나 최종위치에 자리 잡을 때까지 복잡한 온도, 전단력과 신장력의 영향으로 복잡한 형태학을 가짐을 알 수 있었다.

자동차용 플라스틱 연료튜브의 환경온도에 따른 후변형에 관한 연구 (A Study on the Post Deformation According to an Environmental Temperature of the Plastic Fuel Tube for Automobile)

  • 박정식;문찬용;정영득
    • 동력기계공학회지
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    • 제7권2호
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    • pp.56-60
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    • 2003
  • Recently the plastic fuel tube is usually used to reduce production cost and weight in automobiles. These days, material used to plastic fuel tube is the polyamide12. The fuel tube is made of the PA12. Post deformation of the tube has been changed by environmental temperature. So, it is important to prevent post deformation. The experiment is performed to investigate post deformation of the tube produced by each bending process. In this study, the results we obtained are used to bending process system for post deformation as the environmental temperature of the tube. It turned out that the method of steam heating and air cooling was shown less deformation than other methods.

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Engineering Polymer의 흡습에 따른 전기적 특성 변화 (Electrical Properties by water immersion of Engineering Polymer)

  • 박재열;박성희;권오덕;강성화;임기조
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.198-200
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    • 2003
  • In this paper, electrical characteristics of EP(engineering plastic) studies for the purpose of electrical insulation materials. A base resin of the EP are Polyamide and Polyphthalamide. And filler is Glass Fibre. Electrical characteristics of EP represents volume resistivity, arc resistance and breakdown voltage according to glass fiber contents. We compare before water immersion and after water immersion. As the results of experiments, Polyphthalamide has good characteristics of insulation material rather than Polyamide as an insulator for electrical power system.

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Spacer 의 변화에 의한 Thermotropic Polyamide 및 Copolyamide 의 합성 (Synthesis of Thermotropic Liquid-Crystalline Polyamides and Copolyamides Containing a Different Spacer in the Main Chain and Their Structure Interpretation)

  • 송진철;김경환
    • 한국염색가공학회지
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    • 제5권2호
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    • pp.109-116
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    • 1993
  • Synthesis and liquid-crystallinites of thermotropic polyamides and copolyamides were investigated. Thermotropic polyamides and copolyamides containing a flexible spacer in the backbone were obtained by the two or three components melt polycondensations of 4,4'-dicarboxy-${\alpha}$${\omega}$-diphenoxy alkane as an A components, 4,4'-diacetoamido-3,3' dimethoxybiphenyl as a B, 1,4-diacetoamido-benzene (diacetylated p-phenylenediamine) was used as another amide-group-forming minomer. The content of the amide groups in the thermotropic polyamide and Copolyamide widely varied depending on the structure of the amide-group forming diacetoamido monomers. A polymer (9CLDI) showed a typical nematic texture between 218$^{circle}C$ ($T_m$) and 345$^{circle}C$($T_i$) The melting points of the members of this series of polymers increased with decreasing methylene spacer. The polymer structure and mesmorphic nature were examined by solid and solution ${^13}C$-NMR spectroscopy, cross polarizing microscopy with a hot stage.

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Radiation-Induced Graft Copolymerization of Hydrophilic Monomer onto Nylon 6

  • Choi, Jae-Ho;Lee, Chong-Kwang;Lee, Kwang-Jin
    • Nuclear Engineering and Technology
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    • 제6권3호
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    • pp.161-169
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    • 1974
  • Nylon직포의 표면을 친수화 하기 위하여 동시조사법으로 Acrylic acid를 방사선 graft중합시켰다. Monomer용액속서 침지된 Nylon직포를 공기중 또는 진공하에서 ${\gamma}$-선으로 조사시켰다. 직포 표면에 형성된 Polyacrylic acid는 10$0^{\circ}C$의 sodium hydroxide용액(0.1%)으로 대부분 추출되었다. 접목 반응된 생성물의 화학적 조성을 측정하였다. 접목반응된 Polymer와 방사선 처리를 하지 않은 polyamide를 비교하여 볼 때 흡수성이라든가 대전성은 증진되었다.

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Development of membrane blend using casting technique for water desalination

  • El-Gendi, A.;Ali, S.S.;Ahmed, S.A.;Talaat, H.A.
    • Membrane and Water Treatment
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    • 제3권3호
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    • pp.201-209
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    • 2012
  • Membrane separation technologies have some of advantages are considered a better alternative to traditional methods. Research of novel membranes is very vital for covering the higher required of membrane in several purposes like water desalting technology. In this work polyamide-6/cellulose acetate (PA-6/CA) blend membrane was developed according to the wet phase inversion system. The structures of the prepared membranes were examined by scanning electron microscopy (SEM). SEM images showed uniform particles distribution in the prepared membranes. Moreover, SEM images revealed that the membranes have relatively uniform surface (PA-6/CA). PA-6/CA blend membranes systems are evaluated by using synthetic NaCl solution. The separation performance showed that salt rejection increased with increasing of heat treatment of the casted films and it was improved with increasing of operating pressure.

Hydrolysis Resistance and Mechanical Property Changes of Glass Fiber Filled Polyketone Composites Upon Glass Fiber Concentration

  • Kim, Sung Min;Kim, Kwang-Jea
    • Elastomers and Composites
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    • 제52권1호
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    • pp.1-8
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    • 2017
  • Hydrolysis resistance and mechanical property changes of polyketone (POK)/glass fiber (GF) composites were investigated for GF concentrations varying between 30 and 50%. The hydrolysis resistance of GF filled POK and polyamide66 (PA66, hydrolysis resistant grade) composites were compared. As shown by the experimental results, increasing the immersion time of the composites in a monoethylene glycol (MEG)/water solution at $120^{\circ}C$ had no impact or resulted in slightly decreased mechanical properties such as the tensile strength, tensile modulus, and strain at break in case of POK composites, whereas the mechanical properties of PA66 composites showed a significant drop. Increasing GF concentrations increased the tensile strength, tensile modulus, flexural strength, and flexural modulus of POK composites; however, impact strength did not show significant changes. Hydrolysis mechanisms of POK and PA66 are discussed.

면섬유용 내구성유연제의 제조 및 유연특성 (Preparation and Characterization of Durable Softener for Cotton Fiber)

  • 이애리;김성래;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제20권4호
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    • pp.341-345
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    • 2003
  • Organic acid salt of fatty polyamide (DDDT) and acrylate of fatty carbamide (DDTCA) were synthesized as a main component for the softener. O/W type non-ionic softener (NSC) was prepared by blending DDDT and DDTCA with beef tallow, lanolin anhydride. polyoxyethylene(7) stearyl ether, and polyoxyethylene(50) oleyl ether. After treatment of NSC to all cotton fabrics, the physical properties such as tear strength, crease recovery, and flexing abrasion resistance were measured. As a result of the measurement, NSC was proved to be durable non-ionic softener with good softness.

광변색성 및 전기변색성 색소의 합성 및 특성(I) -광변색성 특성의 섬유소재에의 응용- (Synthesis of the photochromic and electrochromic dyes and their sensible properties (I) - Dyeing application with photochromic moiety to the fiber substrate-)

  • 손영아;박영민;김병순;김성훈
    • 한국염색가공학회지
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    • 제18권2호
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    • pp.24-30
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    • 2006
  • The photosensitive spiroxazine compound and the electrosensitive viologen compound were prepared to examine their practical application feasibilities and behaviors. These dyes represent corresponding chromism effects related to their own characteristics of the dye molecules. Thus, the prepared dyes were characterized and their absorption spectra were also investigated. Besides, an interest on direct spiroxazine exhaustion to the polyamide substrates and its photochromic effects within the fiber molecules were determined. The photochromic reaction on the substrates was clearly observed and its reversible decoloration behaviors responded.