• Title/Summary/Keyword: polyamide

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Effect of injection molding conditions on morphology of binary polymer blends (이성분계 고분자 블렌드의 형태학에 미치는 사출 조건의 영향)

  • Son, Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.165-169
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    • 2008
  • The effect of processing conditions on the morphology of polyphenyleneoxide (PPO)/polyamide 6 (PA 6) blends were investigated. Injection molded part with a $15cm{\times}15cm{\times}3.2mm$ sized plate was molded with various injection molding conditions, and the morphology of the injection molded blends was investigation by using SEM. As a result, we found that molded part shows very complicated morphology because it has experienced complex thermal, shear and elongation history during the processing.

A Study on the Post Deformation According to an Environmental Temperature of the Plastic Fuel Tube for Automobile (자동차용 플라스틱 연료튜브의 환경온도에 따른 후변형에 관한 연구)

  • Park, J.S.;Moon, C.Y.;Jeong, Y.D.
    • Journal of Power System Engineering
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    • v.7 no.2
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    • pp.56-60
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    • 2003
  • Recently the plastic fuel tube is usually used to reduce production cost and weight in automobiles. These days, material used to plastic fuel tube is the polyamide12. The fuel tube is made of the PA12. Post deformation of the tube has been changed by environmental temperature. So, it is important to prevent post deformation. The experiment is performed to investigate post deformation of the tube produced by each bending process. In this study, the results we obtained are used to bending process system for post deformation as the environmental temperature of the tube. It turned out that the method of steam heating and air cooling was shown less deformation than other methods.

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Electrical Properties by water immersion of Engineering Polymer (Engineering Polymer의 흡습에 따른 전기적 특성 변화)

  • Park, Jae-Yeol;Park, Sung-Hee;Kwon, Oh-Deok;Kang, Seong-Hwa;Lim, Kee-Joe
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.198-200
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    • 2003
  • In this paper, electrical characteristics of EP(engineering plastic) studies for the purpose of electrical insulation materials. A base resin of the EP are Polyamide and Polyphthalamide. And filler is Glass Fibre. Electrical characteristics of EP represents volume resistivity, arc resistance and breakdown voltage according to glass fiber contents. We compare before water immersion and after water immersion. As the results of experiments, Polyphthalamide has good characteristics of insulation material rather than Polyamide as an insulator for electrical power system.

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Synthesis of Thermotropic Liquid-Crystalline Polyamides and Copolyamides Containing a Different Spacer in the Main Chain and Their Structure Interpretation (Spacer 의 변화에 의한 Thermotropic Polyamide 및 Copolyamide 의 합성)

  • ;;Toshiyuki Uryu
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.109-116
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    • 1993
  • Synthesis and liquid-crystallinites of thermotropic polyamides and copolyamides were investigated. Thermotropic polyamides and copolyamides containing a flexible spacer in the backbone were obtained by the two or three components melt polycondensations of 4,4'-dicarboxy-${\alpha}$${\omega}$-diphenoxy alkane as an A components, 4,4'-diacetoamido-3,3' dimethoxybiphenyl as a B, 1,4-diacetoamido-benzene (diacetylated p-phenylenediamine) was used as another amide-group-forming minomer. The content of the amide groups in the thermotropic polyamide and Copolyamide widely varied depending on the structure of the amide-group forming diacetoamido monomers. A polymer (9CLDI) showed a typical nematic texture between 218$^{circle}C$ ($T_m$) and 345$^{circle}C$($T_i$) The melting points of the members of this series of polymers increased with decreasing methylene spacer. The polymer structure and mesmorphic nature were examined by solid and solution ${^13}C$-NMR spectroscopy, cross polarizing microscopy with a hot stage.

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Radiation-Induced Graft Copolymerization of Hydrophilic Monomer onto Nylon 6

  • Choi, Jae-Ho;Lee, Chong-Kwang;Lee, Kwang-Jin
    • Nuclear Engineering and Technology
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    • v.6 no.3
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    • pp.161-169
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    • 1974
  • Radiation grafting of acrylic acid onto nylon fabric has been studied by "simultaneous irradiation" method to render its surface more hydrophilic. Nylon fabric immersed in monomer solution was irradiated in air or under vacuum with gamma-rays from Co-60. Most parts of polyacrylic acid formed on the surface of the fabric were extracted off from the fabric with 0.1% solution of sodium hydroxide at 10$0^{\circ}C$. The chemical components of the grafted product have been determined. By comparing graft polymer with ungrafted polyamide, the rate of water absorption and antistatic behavior are improved. improved.

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Development of membrane blend using casting technique for water desalination

  • El-Gendi, A.;Ali, S.S.;Ahmed, S.A.;Talaat, H.A.
    • Membrane and Water Treatment
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    • v.3 no.3
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    • pp.201-209
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    • 2012
  • Membrane separation technologies have some of advantages are considered a better alternative to traditional methods. Research of novel membranes is very vital for covering the higher required of membrane in several purposes like water desalting technology. In this work polyamide-6/cellulose acetate (PA-6/CA) blend membrane was developed according to the wet phase inversion system. The structures of the prepared membranes were examined by scanning electron microscopy (SEM). SEM images showed uniform particles distribution in the prepared membranes. Moreover, SEM images revealed that the membranes have relatively uniform surface (PA-6/CA). PA-6/CA blend membranes systems are evaluated by using synthetic NaCl solution. The separation performance showed that salt rejection increased with increasing of heat treatment of the casted films and it was improved with increasing of operating pressure.

Hydrolysis Resistance and Mechanical Property Changes of Glass Fiber Filled Polyketone Composites Upon Glass Fiber Concentration

  • Kim, Sung Min;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.1-8
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    • 2017
  • Hydrolysis resistance and mechanical property changes of polyketone (POK)/glass fiber (GF) composites were investigated for GF concentrations varying between 30 and 50%. The hydrolysis resistance of GF filled POK and polyamide66 (PA66, hydrolysis resistant grade) composites were compared. As shown by the experimental results, increasing the immersion time of the composites in a monoethylene glycol (MEG)/water solution at $120^{\circ}C$ had no impact or resulted in slightly decreased mechanical properties such as the tensile strength, tensile modulus, and strain at break in case of POK composites, whereas the mechanical properties of PA66 composites showed a significant drop. Increasing GF concentrations increased the tensile strength, tensile modulus, flexural strength, and flexural modulus of POK composites; however, impact strength did not show significant changes. Hydrolysis mechanisms of POK and PA66 are discussed.

Preparation and Characterization of Durable Softener for Cotton Fiber (면섬유용 내구성유연제의 제조 및 유연특성)

  • Lee, Ae-Ri;Kim, Sung-Rae;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.341-345
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    • 2003
  • Organic acid salt of fatty polyamide (DDDT) and acrylate of fatty carbamide (DDTCA) were synthesized as a main component for the softener. O/W type non-ionic softener (NSC) was prepared by blending DDDT and DDTCA with beef tallow, lanolin anhydride. polyoxyethylene(7) stearyl ether, and polyoxyethylene(50) oleyl ether. After treatment of NSC to all cotton fabrics, the physical properties such as tear strength, crease recovery, and flexing abrasion resistance were measured. As a result of the measurement, NSC was proved to be durable non-ionic softener with good softness.

Synthesis of the photochromic and electrochromic dyes and their sensible properties (I) - Dyeing application with photochromic moiety to the fiber substrate- (광변색성 및 전기변색성 색소의 합성 및 특성(I) -광변색성 특성의 섬유소재에의 응용-)

  • Son Young-A;Park Young-Min;Kim Byung-Soon;Kim Sung-Hoon
    • Textile Coloration and Finishing
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    • v.18 no.2 s.87
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    • pp.24-30
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    • 2006
  • The photosensitive spiroxazine compound and the electrosensitive viologen compound were prepared to examine their practical application feasibilities and behaviors. These dyes represent corresponding chromism effects related to their own characteristics of the dye molecules. Thus, the prepared dyes were characterized and their absorption spectra were also investigated. Besides, an interest on direct spiroxazine exhaustion to the polyamide substrates and its photochromic effects within the fiber molecules were determined. The photochromic reaction on the substrates was clearly observed and its reversible decoloration behaviors responded.