• Title/Summary/Keyword: poly(propylene) (PP)

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Effect of Poly(propylene-co-octene) as a Compatibilizer on Mechanical Properties and Weldline Characteristics of Polypropylene/Poly(ethylene-co-octene) Blends (폴리프로필렌/에틸렌-옥텐 공중합체 블렌드의 기계적 성질 및 웰드라인 물성에 미치는 폴리프로필렌-옥텐 공중합체의 영향에 관한 연구)

  • Koo, Hyo-Seon;Son, Young-Gon
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.251-256
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    • 2011
  • Effect of poly(propylene-co-octene) as a compatibilizer in toughened polypropylene/ poly(ethylene-co-octene) (EOC) was investigated. The EOCs used were metallocene catalyzed commercial linear low density polyethylene and they are elastomeric materials. The poly(propylene-co-octene) was synthesized by metallocene catalyst in our laboratory to be used as a compatibilizer in PP/EOC blends. PP/EOC blends without compatibilizer shows very low mechanical properties in specimens with weldlines while incorporation of a compatibilizer significantly increases the mechanical properties of specimens with weldlines. However, compatibilized PP/EOC blends does not show increased impact property in a weldline free specimen and it is attributed to low molecular weight of the poly(propylene-co-octene) synthesized in present study. It is expected that the poly(propylene-co-octene) having increased molecular weight provides very good performance as an effective compatibilizer in toughened polypropylene/EOC blends.

Effect of the density of PolyPropylene foams on the absorption of the impact energy (충격에너지 흡수에 미치는 폴리프로필렌 폼 밀도의 영향)

  • 박남훈;고영호;문기석;윤희석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1398-1401
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    • 2003
  • Recently, The PolyPropylene(PP) Foam used as Bumper and Helmet is well known as a protective material for products. In this paper, the effect of the density of PP foams on the absorption of the impact energy is implemented. The result of the experiment has revealed that the effect of the high-density PP foams is remarkably increased compared with that of the low-density PP foams. And it also shows that the absorption of the impact energy of PP foams are greatly influenced by the density in impact velocity(220cm/s). These results are expected to be utilized for the technique of manufacturing a optimum impact structure.

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Morphological Properties of Binary Blends of Polyolefins Synthesized by Metallocene and Ziegler-Natta Catalysts (Ziegler-Natta와 메탈로센 촉매로 합성된 폴리올레핀 2원 블렌드의 상 형태학)

  • Kwag, Hanjin;Kim, Hak Lim;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.944-948
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    • 1999
  • The morphological properties of four binary blends of polyethylene synthesized by metallocene catalyst(MCPE) and four polyolefins prepared by Ziegler-Natta catalyst have been investigated to interpret the effect of micro-molecular structure on the phase morphology and interfacial behavior; four binary blend systems studied are high density polyethylene(HDPE)-metallocene polyethylene (MCPE), polypropylene(PP)-MCPE, poly(propylene-co-ethylene) (CoPP)-MCPE, and poly(propylene-co-ethylene-co-1-butylene) (TerPP)-MCPE, and they are all phase separated. The HDPE-MCPE blend shows evenly growing homogeneous HDPE domain on the continuous MCPE phase, on the other hand, the rest of three blends show complex heterogeneous phase behavior. The PP-MCPE blend shows that PP and MCPE and completely phase separated and phase inversion takes place at 50% MCPE. The CoPP-MCPE and TerPP-MCPE show enhanced interface due to the same micro-molecular structure of ethylene, and phase inversion takes place at 40% MCPE. In particular, TerPP-MCPE blend shows improved phase morphology between interfaces, and this may be arisen from the comonomer contents in TerPP, which are 1-butene and ethylene having the same chemical structure as that of MCPE. The enhancement of the phase morphology in the TerPP-MCPE blend is correlated with the mechanical and morphological properties. Thus, although the four blend systems are phase separated, the phase morphology suggests that the order of interfacial adhesion strength be HDPE-MCPE > TerPP-MCPE > CoPP-MCPE > PP-MCPE and that micro-molecular structure between constituents be one of major factors giving enhanced interfacial adhesion.

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Crack Resistance Properties of Fiber Reinforced Concrete with Recycled PET Fiber (재생 PET 섬유가 혼입된 섬유 보강 콘크리트의 균열저항특성)

  • Kim, Sung-Bae;Kim, Hyun-Young;Yi, Na-Hyun;Kim, Jang-Jay-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.545-546
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    • 2009
  • This study was performed to prove the possibility of utilizing short plastic fibers made for recycled polyethylene terephthalate (RPET) as a structural material. To measure of crack control capacity, restrained drying shrinkage cracking test was performed. In order to verify the capacity of RPET fiber, it was compared with poly propylene (PP) fiber, most widely used short synthetic fiber, for fiber volume fraction of 0%, 0.5%, 0.75%, and 1.0%.

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Roller compacted concrete pavements reinforced with steel and polypropylene fibers

  • Madhkhan, Morteza;Azizkhani, Rasool;Torki, Mohammad E.
    • Structural Engineering and Mechanics
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    • v.40 no.2
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    • pp.149-165
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    • 2011
  • In this paper, the effects of both pozzolans and (steel and poly-propylene) fibers on the mechanical properties of roller compacted concrete are studied. Specimens for the experiments were made using a soil-based approach; thus, the Kango's vibration hammer was used for compaction. The tests in the first stage were carried out to determine the optimal moisture requirements for mix designs using cubic $150{\times}150{\times}150$ mm specimens. In the tests of the second stage, the mechanical behaviors of the main specimens made using the optimal moisture obtained in the previous stage were evaluated using 28, 90, and 210 day cubic specimens. The mechanical properties of RCC pavements were evaluated using a soil-based compaction method and the optimum moisture content obtained from the pertaining experiments, and by adding different percentages of Iranian pozzolans as well as different amounts of steel fibers, each one accompanied by 0.1% of poly-propylene fibers. Using pozzolans, maximum increase in compressive strength was observed to occur between 28 and 90 days of age, rupture modulus was found to decrease, but toughness indices did not change considerably. The influence of steel fibers on compressive strength was often more significant than that of PP fibers, but neither steel nor PP fibers did contribute to increase in the rupture modulus independently. Also, the toughness indices increased when steel fibers were used.

A Study on PolyPropylene-base Functionalized Polyolefin for Secondary Battery Lead Tab Tape (이차전지 리드 탭 테이프용 폴리프로필렌 기반 기능성 폴리올레핀에 관한 연구)

  • Deok-Ho Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.3
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    • pp.619-627
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    • 2024
  • By analyzing the structure of the currently used Lead Tab tape structure, the outermost layer, low-temperature fusion functionalized olefin, was composed of pp base. To determine whether this could be used as the outermost layer of tab tape, the adhesive strength to metal foils such as copper and aluminum was measured and the adhesive strength was compared with commercially available functionalized olefin. When chlorine was grafted onto PP among the PP used in the composition, the average adhesive strength was similar to that of commercially available LT200T and superior to RE140R and LE320V. The maximum adhesive strength exceeded that of LE200T. When it comes to solvents, xylene has been shown to be better than any other. Physical methods such as substitution of other monomers, switching of additives or let-down hardly changed the adhesion of grafted PP, and the selection of PP is an important factor in preparing functional polymers.

Reliability Estimation and Dynamic Deformation of Polymeric Material Using SHPB Technique and Probability Theory (SHPB 기법과 확률이론을 이용한 고분자재료의 동적거동특성 및 건전성 평가)

  • Lee, Ouk-Sub;Kim, Dong-Hyeok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.9
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    • pp.740-753
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    • 2008
  • The conventional Split Hopkinson Pressure Bar (C-SHPB) technique with aluminum pressure bars to achieve a closer impedance match between the pressure bars and the specimen materials such as hot temperature degraded POM (Poly Oxy Methylene) and PP (Poly Propylene) to obtain more distinguishable experimental signals is used to obtain a dynamic behavior of material deformation under a high strain rate loading condition. An experimental modification with Pulse shaper is introduced to reduce the nonequilibrium on the dynamic material response during a short test period to increase the rise time of the incident pulse for two polymeric materials. For the dynamic stress strain curve obtained from SHPB experiment under high strain rate, the Johnson-Cook model is applied as a constitutive equation, and we verify the applicability of this constitutive equation to the probabilistic reliability estimation method. The methodology to estimate the reliability using the probabilistic method such as the FORM and the SORM has been proposed, after compose the limit state function using Johnson-Cook model. It is found that the failure probability estimated by using the SORM is more reliable than those of the FORM, and the failure probability increases with the increase of applied stress. Moreover, it is noted that the parameters of Johnson-Cook model such as A and n, and applied stress affect the failure probability more than the other random variables according to the sensitivity analysis.