• Title/Summary/Keyword: poly(Ethylene terephthalate)

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Effects of PEO Additions on the Mechanical and Thermal Proprieties of PLA/PBAT Blends (폴리에틸렌옥사이드가 PLA/PBAT 블렌드 물성에 미치는 영향)

  • Jang, Hyunho;Kwon, Sangwoo;Eom, Yoojun;Yoo, Seungwoo;Park, Su-il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.2
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    • pp.93-98
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    • 2020
  • The blends of Poly(lactic acid) (PLA) and Poly(butylene adipate-co-terephthalate) (PBAT) have been recognized as a replacement for commodity plastic films and bags in biodegradable packaging industries. The purpose of this study is to identify changes in the thermal and mechanical properties of PLA/PBAT blends with the addition of poly(ethylene oxide)(PEO). PLA (80%) and PBAT (20%) were melt mixed with 0 to 10 phr of PEO and processed using a hot press. The addition of PEO into PLA/PBAT increased the elongation at break and improved thermal stability. With PEO addition, two melting temperature (Tm) peaks of PLA/PBAT merged into one peak showing improved miscibility. The result of this study showed that the addition of PEO increased the ductility and thermal stability of PLA/PBAT blends.

Study on the Market Conditions and Quality Evaluation Methods of post-consumer Recycled Polyethylene Terephthalate (PCR PET) Flake (재생 페트 플레이크의 시장 현황과 품질 평가 방안 연구)

  • Joo, Minjung;Suh, Sang Uk;Lee, Ka Eun;Oh, Jae Young
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.1
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    • pp.41-46
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    • 2020
  • PCR PET flake's market endeavors difficult situations of its oversupply and decreasing demands in South Korea. Since China banned the import of most recycled plastics, flake producers who mostly export the flakes lost their biggest market. The producers struggled to survive in the competitions with PCR PET flake from EU and 3rd countries but it was challenging due to substandard quality and increasing cost. Attempts to improve the quality of PCR PET flake have been made but they were only an individual company's efforts. The objective of this study was to understand the market status on PCR PET flake in South Korea and to present suggestions for improving its quality. The results of the questionnaires targeted to flake producers showed that no testing methods on PCR PET flake were standardized and there were critical factors to the quality such as moisture content, contaminants, and viscosity. Case studies of US, Japan and other countries had been done especially about testing methods and 76 samples from 21 companies were tested according to those methods. Based on the results, the final factors were decided as contaminants, moisture content, alkalinity index and intrinsic viscosity. There is a plan to standardize testing methods and they could be guidelines to improve the business competitiveness of PCR PET flake in South Korea.

Improvement of Electrical Conductivity of Transparent Conductive Single-Walled Carbon Nanotube Films Fabricated by Surfactant Dispersion

  • Lee, Seung-Ho;Kim, Myoung-Su;Goak, Jeung-Choon;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.17-17
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    • 2009
  • Single-walled carbon nanotubes (SWCNTs) have attracted much attention as promising materials for transparent conducting films (TCFs), thanks to their superior electrical conductivity, high mechanical strength, and complete flexibility. The CNT-based TCFs can be used in a variety of application fields as flexible, transparent electrodes, including touch panel screens, flexible electronics, transparent heaters, etc. First of all, this study investigated the effect of a variety of surfactants on the dispersion of SWCNTs in an aqueous solution. Following the optimization of the dispersion by surfactants, flexible TCFs were fabricated by spraying the CNT suspension onto poly(ethylene terephthalate) (PET) substrates. The sheet resistances of the TCFs having different surfactants were investigated with treatment in nitric acid ($HNO_3$) whose concentration and period of treatment time were varied. It seems that the $HNO_3$ removes the surfactants from and is simultaneously doped into the SWCNT network, reducing the contact resistance between CNTs. TCFs were characterized by UV-VIS spectroscopy, thermogravimetric analyzer (TGA), scanning electron microscopy (SEM), and four-point probe.

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A Study on the Bathochromic of Poly(Ethylene Terephthalate) Fabrics by Plasma Polymerization (Plasma polymerization에 의한 PET 직물의 심색화에 관한 연구)

  • Cho, Hwan;Kim, Han-Ki;Jang, Byung-Yul;Lee, Kwang-Woo;Cho, In-Sool;Heo, Man-Woo
    • Textile Coloration and Finishing
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    • v.5 no.3
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    • pp.194-205
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    • 1993
  • Plasma polymerization in prepared glow discharge was carried out to improve the bathochromic of dyed PET fabrics by using silicon containing vinyl monomer in plasma polymerization equipment which consists of a pair of electrodes was connected to the 13.56MHz RF generator. The optimum condition for the bathochromic effect was investigated on various plasma polymeriztion parameters. By plasma polymerization used silicon containing vinyl monomer, the bathochromic of dyed PET fabrics was very enhanced. The optimum conditions on this equipment were as follows ; electrode distance : 3cm, discharge output : 60W, gas pressure : 0.3 Torr, monomer flow rate : 30㎤/min. plasma polymerization time : 60sec. The apparent strength of plasma polymerized PET fabrics was increased about 40∼47% with decreasing about 3 of L value.

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Improvement of Electrical Conductivity of Transparent Conductive Single-Walled Carbon Nanotube Films Fabricated by Surfactant Dispersion

  • Lee, Seung-Ho;Kim, Myoung-Su;Goak, Jeung-Choon;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.254-254
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    • 2009
  • Single-walled carbon nanotubes (SWCNTs) have attracted much attention as promising materials for transparent conducting films (TCFs), thanks to their superior electrical conductivity, high mechanical strength, and complete flexibility. The CNT-based TCFs can be used in a variety of application fields as flexible, transparent electrodes, including touch panel screens, flexible electronics, transparent heaters, etc. First of all, this study investigated the effect of a variety of surfactants on the dispersion of SWCNTs in an aqueous solution. Following the optimization of the dispersion by surfactants, flexible TCFs were fabricated by spraying the CNT suspension onto poly(ethylene terephthalate) (PET) substrates. The sheet resistances of the TCFs having different surfactants were investigated with treatment in nitric acid ($HNO_3$) whose concentration and period of treatment time were varied. It seems that the $HNO_3$ removes the surfactants from and is simultaneously doped into the SWCNT network, reducing the contact resistance between CNTs. TCFs were characterized by UV-VIS spectroscopy, thermogravimetric analyzer (TGA), scanning electron microscopy (SEM), and four-point probe.

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A study on the effect of twice foaming process on microcellular foamed plastics (재발포가 MCPs에 미치는 영향)

  • Park J.Y.;Cha S.W.;Seo J.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.421-422
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    • 2006
  • According to the industrialization the using of polymers is increased by their mechanical or commercial demands. At now, the using of polymers is become bigger and bigger than yet. On the other words, our whole life is covered by the polymers. Due to the extended polymer using, the material cost is higher and higher. Therefore, the people used the polymer foaming process using the gas. The polymer foaming using the pentane or butane gas is prohibited by the government cause of the explosiveness and non-environmental friendly. Therefore, the members of MIT invented the Micro-cellular Polymer Foaming in 1980. The Micro-cellular Polymers has many cells in the polymer matrix. By compare between non-foamed polymers, the Micro-cellular Polymers have low material cost, soundproof and shock less. The purpose of this study is to study the twice foamed polymer by batch process. To know the reaction by step of microcellular foaming process, we measure the density of polymer. And to viewing the cell morphology, we used the scanning electron microscopy(SEM).

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Preparation and Properties of Functional PET Textured Yarn Coated with Aromatic Polymer (아로마틱 고분자를 적용한 기능성 PET 가공사 제조 및 특성)

  • Ahn, Dajeong;Choi, Chulhoon;Lee, Jaewoong;Lee, Sang Oh
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.148-154
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    • 2017
  • Many researches have been made on the processing technology of Poly(ethylene terephthalate) (PET), which is widely used for clothing and non-clothing applications. In this study, we coated PET filaments with m-aramid resin to improve heat resistance and antimicrobial properties. In order to enhance adhesion between PET and m-aramid polymer, the adhesive polymer was coated on the PET filaments using a winding speed of 100m/min and then treated with m-aramid. Scanning electron microscopy was used to analyze the surface of the adhesive polymer and m-aramid treated PET filament. The change of initial degradation temperature according to treatment was confirmed by thermogravimetric analysis. Antimicrobial activity analysis using bacterial reduction method showed that PET filament treated with adhesive polymer and m-aramid had an increased antibacterial effect compared to untreated PET filament.

Study on the Improvement of Light Transmittance of Polyester Film (폴리에스터 필름의 광투과도 향상에 대한 연구)

  • Kim, Si-Min;Park, Soo-Young
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.662-667
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    • 2012
  • Poly(ethylene terephthalate) (PET) base films with high light transmittance have been used for the substrate of various functional films in the flat panel display. The effects of the reflective index of coated films, the roughness of the film surface and the content of inorganic silica particles on the light transmittance were studied in this article. Light transmittance was increased by coating a water soluble resin with a low reflective index at an optimum thickness. The roughness of the film did not affect light transmittance when the Ra of the film surface was less than a quarter of the wavelength of incident light. Inorganic silica particles decreased light transmittance due to their absorbance and scattering of the incident light.

A Study on Polypropylene and Surface Modified PET Fiber Composites (표면처리된 PET 섬유와 PP 복합재료에 관한 연구)

  • Hahm, Moon-Seok;Kim, Chang-Hyeon;Ryu, Ju-Whan
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.7-12
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    • 2008
  • We confirmed that poly (ethylene terephthalate) (PET) fiber had the possibility to improve the mechanical properties of polypropylene (PP) by fabricating PP/PET fiber composites because PET enhanced mechanical properties and higher melting temperature than PP. But lower compatibility of between PP and PET fibers induced poor mechanical properties of PP/PET fiber composites in spite of incorporating PP-g-MAH as compatibilizer. To solve these problems of PP/PET fiber composites, we carried out a surface treatment on PET fiber using NaOH solution and Prepared PP/PET fiber composites with good mechanical properties by adding PP-g-MAH as a compatibilizer Then the behavior of the mechanical properties was correlated with the results obtained from SEM and IR spectroscopy.

Detergency of Particulate Soil of PET Fabric Finished with Hydrophilic and Hydrophobic Chemicals (친수 및 소수처리 PET직물의 고형오구의 세척성)

  • Kang, In-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.11
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    • pp.1237-1245
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    • 2012
  • The effect of hydrophilicity and hydrophobicity of PET fabric on the detergency of particulate soil were investigated as functions of the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. The detergency of the particulate soil was determined by the adhesion of particles to and their removal from fabric, the PET fabric and ${\alpha}-Fe_2O_3$ were used as textile materials and for the model of particulate soil, respectively. The hydrophilic and hydrophobic finish for PET fabric was treated with a polyester, silicone and fluorine organic compound of resin respectively. The adhesion of particulate soil to fabric treated with hydrophobic chemicals were slightly higher but its removal from fabric treated with hydrophobic chemicals was largely higher than fabric treated with a hydrophilic chemical regardless of solution conditions such as the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. Therefore, hydrophobic treatment for fabric had a more positive effect than the hydrophilic treatment on the detergency of particulate soil.