• Title/Summary/Keyword: pollution monitoring

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Preparation of Styrene-Ethyl acylate Core-shell Structured Detection Materials for aMeasurement of the Wall Contamination by Emulsion Polymerization

  • Hwang, Ho-Sang;Seo, Bum-Kyoung;Lee, Dong-Gyu;Lee, Kune-Woo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

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Temporal and Spatial Pattern of Ambient Nitrogen Dioxide Concentration in Forest and Urban Areas, Korea (우리나라 산림과 도시지역의 이산화질소 농도의 시·공간적 패턴)

  • Lee, Seung-Woo;Lee, Choong-Hwa
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.13 no.4
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    • pp.165-170
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    • 2011
  • The ambient concentrations of nitrogen dioxide ($NO_2$) at 65 forest areas were measured every month using passive diffusive samplers from 2002 to 2009 and were compared to those at urban areas in order to investigate the characteristics of temporal and spatial distributions of $NO_2$ from the forest and urban areas. The annually averaged concentrations of $NO_2$ gradually decreased for both areas. The average concentration of $NO_2$ in the forest areas was 8.0 ppb, which was lower than that in the urban areas (i.e., 19.4 ppb) and the ecological standard level of the European Union (i.e., 14.6 ppb). The monthly average of $NO_2$ concentration depicted seasonal variations particularly in the urban areas, showing higher concentration in winter and lower concentration in summer. Strong locality of $NO_2$ concentration distribution illustrates that the locations near the metropolitan areas (e.g., Gyeonggi and Chungnam provinces) had the highest concentration during the measurement period. A significant positive correlation between $NO_x$ emissions and $NO_2$ concentration was observed, suggesting that the magnitude and proximity to sources of atmospheric nitrogen oxides would be important controlling factors.

Availability Evaluation of TOC as the Environmental Standard - Survey of Lakes in Nakdong River Basin - (환경기준으로서의 TOC에 대한 활용성 평가 - 낙동강수계 호소를 대상으로 -)

  • Choi, Byoungwoo;Kang, Meea
    • Journal of Wetlands Research
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    • v.20 no.2
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    • pp.173-180
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    • 2018
  • The utilization of TOC(Total organic carbon), a new environmental standard, was evaluated for 30 lakes in the Nakdong River Basin, which is used for drinking and agricultural usage. The active use of water resources begins with securing satisfactory water quality. Since this allows people and nature to maintain stability of quality, water quality standards are being tightened to ensure good water quality. In order to improve the pollution level of organic matter in lakes in the living environment, it is important to use the appropriate organic substance index. The relationship between the newly introduced TOC and the existing COD(Chemical oxygen demand) in the targeted lake was positively correlated with the possibility of replacing the TOC with COD. However, the environmental grade standard using TOC is better than the environmental grade standard using COD, so it has the same effect as that of the grade of water quality using TOC as an organic substance factor. This indicates the limitation of TOC to directly replace existing COD when trying to determine or improve the quality level using organic indicators of lakes. Therefore, in order to secure the qualitative safety of the lake, it is required to strengthen environmental standards of TOC in terms of water quality grade. In addition, the correlation between TOC and COD shows a great difference depending on the utilization characteristics of the lake. This requires clear scientific identification, and it requires continuous monitoring of COD that has been used to accumulate indicators of lake organic matter.

On Characteristics of Surface Ozone Concentration and Temporal.Spatial Distribution in Kwangyang-Bay (광양만권의 오존농도 특성과 시.공간적 분포)

  • Ha, Hoon;Lee, Sang-Deug;Lee, Joong-Ki;Park, Chan-Oh;Mun, Tae-Ryong
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.642-652
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    • 2006
  • In order to understand the characteristics of surface ozone concentration and high $O_3$ concentration days, regional data from seven air quality monitoring stations which were operated by local governments were analyzed Regional characteristics of $O_3$ concentration were analyzed with the data of $O_3$ concentration and the characteristics of $O_3$ generation and weather conditions by the selection of the days in which the concentration was higher than 80 ppb. In the case of daily variation, the lowest $O_3$ concentration was shown in all regions from 7am to 8am and the highest around at 4 pm. The monthly variation of mean $O_3$ concentration and ${\Delta}O_3$ values revealed a reducing pattern in July and August following the peak in June, and again a gradual increasing trend in September and October. The result shows that the amount of ozone is dependent on photochemical reaction. The days of $O_3$ generated more than 80 ppb in the region of Gwangyang-bay were 544 days(1,760 hrs). The frequency of occurrence in the region revealed a strong pattern with the order of Samil-dong, Jinsang, and Gwangmu-dong stations in the Gwangyang region. However, Tein-dong, which is the nearest station to air pollution material generation source, showed the lowest frequency in the study area. Consequently, the meteorological parameters which can easily generate the high concentration of $O_3$ in the region of Gwangyang-bay are characterized as follows; atmospheric temperature which is higher than $19^{\circ}C$, relative humidity with the range of $60{\sim}85%$, the less average wind velocity than 5 m/s, cloud cover which is less than 5/10, and the more duration of sunshine than 8 hours.

Construction of High-Resolution Topographical Map of Macro-tidal Malipo beach through Integration of Terrestrial LiDAR Measurement and MBES Survey at inter-tidal zone (대조차 만리포 해안의 지상 LiDAR와 MBES를 이용한 정밀 지형/수심 측량 및 조간대 접합을 통한 정밀 지형도 작성)

  • Shim, Jae-Seol;Kim, Jin-Ah;Kim, Seon-Jeong;Kim, Sang-Ik
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.1
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    • pp.58-66
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    • 2010
  • In this paper, we have constructed high-resolution topographical map of macro-tidal Malipo beach through integration of terrestrial LiDAR measurement and MBES survey data at inter-tidal zone. To acquire the enough information of inter-tidal zone, we have done terrestrial LiDAR measurement mounted on the roof of vehicle with DGPS through go-stop-scan method at the ebb tide and MBES depth surveying with tide gauge and eye staff measurement for tide correction and MSL calculation at the high tide all together. To integrate two kinds of data, we have unified the vertical coordination standard to Incheon MSL. The mean error of overlapped inter-tidal zone is about 2~6 cm. To verify the accuracy of terrestrial LiDAR, RTK-DGPS measurement have done simultaneously and the difference of Z value RMSE is about 4~7 cm. The resolution of Malipo topographical map is 50 cm and it has constructed to DEM (Digital Elevation Model) based on GIS. Now it has used as an input topography information for the storm-surge inundation prediction models. Also it will be possible to use monitoring of beach process through the long-term periodic measurement and GIS-based 3D spatial analysis calculating the erosion and deposition considering with the artificial beach transition and coastal environmental parameters.

A Study on the Characteristics of Marine Debris in Coastline : Daekwang Beach In Imja Island, Jeollanam-Do, Korea (해안표착물의 특성에 관한 연구 : 전라남도 신안군 임자도 대광해수욕장)

  • Jang, Seong-Woong;Oh, Seung-Yeol;Kim, Dae-Hyun;Yoon, Hong-Joo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.17 no.2
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    • pp.123-129
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    • 2011
  • A study on the occurrence and movement of marine debris is required for protecting the marine environment and ecosystem from marine pollution. The aim of this study is to show annual production and movement characteristics through analysis for the flow path, composition and the sources of marine debris. This study analyzed the distribution and characteristics of marine debris collected in the region of $100\;m{\times}20\;m$($=2,000\;m^2$) at the Daekwang Beach in the Yellow Sea. During the collection period from 2008 to 2010, the total weight of the marine debris was 1,445 kg in this site. The most marine debris was plastic amounting to 46.5% of the whole collection; the rest were styrofoam(20%) and wooden material(12.6%). The amount of marine debris mused from foreign country observed 155.5 kg, more than 90% of them was plastic came from China such as buoys. Additionally, this study analyzed seasonal change if marine environment to understand occurrence amount change if marine debris. 2009 and 2010 was high occurrence ratio in season that the north wind is very strong and the occurrence rate appeared highest by 40% in the summer(July) of 2008 that appeared westbound tidal current. Overall, marine Debris mused from foreign country was high occurrence ratio in January, May and then November has a lot of quantity secondly. While, occurrence ratio was the highest by 46% summer(July) in 2008, but in 2009 and 2010 showed the lowest rate to 4%.

Conservation and Management of Lava Tubes in Jeju Island, Korea (제주도 용암동굴의 보존 및 관리 방안에 관한 연구)

  • Kim, Beom-Hoon;Kim, Tae-Ho
    • Journal of the Korean association of regional geographers
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    • v.13 no.6
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    • pp.609-622
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    • 2007
  • This paper examines the lava tubes designated as a natural monument in Jeju Island, and then makes the several suggestions for conserving and managing them. The cave entrances should be scientifically and strictly managed to prevent the deterioration, and to preserve the interior ecosystem, of the lava tubes. The land use and vegetation of the ground surface over the lava tubes should be also systematically managed; the destroyed sand dunes must be recovered for the development of speleothem in the lava tubes, and the plants with deep roots must be removed for the prevention of ceiling collapse. The provincial authorities should manage the ground surface over the lava tubes as a public land to remove the factors threatening the stability of the lava tubes. Since the roads crossing the ground surface are likely to cause the collapse of the lava tubes, new roads bypassing the caves need to be constructed, and warning signs should be also installed at the traverse points. A monitoring system on the cultural properties protection area over the lava tubes could be effectively established by encouraging residents to participate the conservation program of lava tubes. Since the falling blocks from ceilings have been usually observed in the lava tubes, it is urgent to examine their stability. In particular, the dangerous sections must be continuously monitored for taking a quick measure against the collapse. The air environments of lava tubes need to be scientifically analyzed based upon the long-term observations. The lighting equipments must be improved to minimize the green pollution in the lava tubes open to the public. The numbers of visitors should be also controlled to prevent the destruction and contamination of lava tubes caused by a large number of visitors.

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Water Quality Analysis of Hongcheon River Basin Under Climate Change (기후변화에 따른 홍천강 유역의 수질 변화 분석)

  • Kim, Duckhwan;Hong, Seung Jin;Kim, Jungwook;Han, Daegun;Hong, Ilpyo;Kim, Hung Soo
    • Journal of Wetlands Research
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    • v.17 no.4
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    • pp.348-358
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    • 2015
  • Impacts of climate change are being observed in the globe as well as the Korean peninsula. In the past 100 years, the average temperature of the earth rose about 0.75 degree in celsius, while that of Korean peninsula rose about 1.5 degree in celsius. The fifth Assessment Report of IPCC(Intergovermental Panel on Climate Change) predicts that the water pollution will be aggravated by change of hydrologic extremes such as floods and droughts and increase of water temperature (KMA and MOLIT, 2009). In this study, future runoff was calculated by applying climate change scenario to analyze the future water quality for each targe period (Obs : 2001 ~ 2010, Target I : 2011 ~ 2040, Target II : 2041 ~ 2070, Target III : 2071 ~ 2100) in Hongcheon river basin, Korea. In addition, The future water quality was analyzed by using multiple linear regression analysis and artificial neural networks after flow-duration curve analysis. As the results of future water quality prediction in Hongcheon river basin, we have known that BOD, COD and SS will be increased at the end of 21 century. Therefore, we need consider long-term water and water quality management planning and monitoring for the improvement of water quality in the future. For the prediction of more reliable future water quality, we may need consider various social factors with climate components.

Velocity-based decision of water quality measurement locations for the identification of water quality problems in water supply systems (상수도시스템 수질사고 인지를 위한 유속기반 수질계측기 위치 결정)

  • Hong, Sungjin;Lee, Chanwook;Park, Jiseung;Yoo, Do Guen
    • Journal of Korea Water Resources Association
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    • v.53 no.11
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    • pp.1015-1024
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    • 2020
  • Recently, water pollution accidents have continued to occur in pipelines such as red water Incheon and Seoul. In order to recognize this water quality problem, it is necessary to install a water quality sensor in an appropriate location and measure it in advance to detect or block the water supply to the water faucet of the shelter. However, there are limitations, such as maintenance costs, to installing multiple water meters in all pipelines. Therefore, this study proposed a methodology for determining and prioritizing the installation location of flow-based water quality sensor for the recognition of water quality problems in pipelines. We applied the proposed procedure to the pipe break scenario. The results of the determination of the location of the water quality sensor were presented by applying it to the pipe network that actually operates the emergency pipe in Korea. The result of the decision showed that in the event of abnormal situation caused by the destruction of individual pipes, the flow rate of the pipes around the aqueduct and the tank may change rapidly, resulting in water quality accidents caused by turbidity. In the future, it is expected that the water quality monitoring point selection method, such as establishing an external pipe operation plan for pipe cleaning, will utilize the procedure for determining the location of the water quality sensor according to the velocity.

Meteorological Characteristics of High-Ozone Episode Days in Daegu, Korea (대구시의 고농도 오존 발생 일에 나타나는 기상학적 특성)

  • Son, Im-Young;Kim, Hee-Jong;Yoon, Ill-Hee
    • Journal of the Korean earth science society
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    • v.23 no.5
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    • pp.424-435
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    • 2002
  • This study analyzes the surface ozone and meteorological data in Daegu for a period from 1997 to 1999. It also investigates the meteorological characteristics of high ozone episodes. For this study the high ozone episode has been defined as a daily maximum ozone concentration higher than 100ppb in at least one station among six air quality monitoring stations in Daegu, Korea. The frequency of episodes is 13 days. The frequency is the highest in May and September. The average value of daily maximum ozone concentration is 81.6ppb, and 8-hour average ozone concentration is 58.6ppb for the high episodes. This shows that ozone pollution is continuous and wide-ranging in Daegu. The daily maximum ozone concentration is positively correlated to solar radiation and daily maximum temperature, but negatively correlated to relative humidity, wind speed and cloud amount. The maximal correlation coefficient to solar radiation is 0.45. The differences between high ozone episode day's daily mean meteorological value and monthly mean value are +1.58hPa for sea level pressure, +3.45${\circ}$C for maximum temperature, -5.69% for relative humidity, -0.46ms$^{-1}$ for wind speed, -1.79 for cloud amount, and +3.97MJm$^{-2}$ for solar radiation, respectively. This shows that strong solar radiation, low wind speed and no precipitation between 0700${\sim}$1100LST are favorite conditions for high ozone episodes. It is related to the morning stagnant condition.