• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.6
• /
• pp.481-485
• /
• 1998

We investigated the generation of high pretilt angle for nematic liquid crystal (NLC) in a cell with obilique non-polarized ultraviolet (UV) light irradiation on mixtured polyimide surface. It was found that the monodomain alignment of NLC is obtained with an angle of incidence of 75∼85 degrees on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect to photo-depolymerization of polymer. We successfully observed that the pretilt angle of NLC is generated above 5 degree with an angle of incidence of 75∼85 degrees. It is considered that the pretilt angle generation NLC is attributed to interaction between the LC molecules and the polymer surfaces.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.369-372
• /
• 2001

We studied the electro-optical (EO) performance in the vertical-alignment (VA) - l/4$\pi$ cell photoaligned with polarized UV exposure on a homeotropic photopolymer surfaces. Excellent voltage-transmittance curve in the VA - l/4$\pi$ cell photoaligned with polarized UV exposure for 3 min on the photopolymer containing cholesterol group of 8% can be achieved. The V-T characteristics in the VA-l/4$\pi$ cell photoaligned on the photopolymer surface can be improved by increasing cholesteryl group. For response time measurement, the transmittance characteristics of the VA-l/4$\pi$ cell photoaligned on the photopolymer surface was better than that of the VA-l/4$\pi$ cell rubbingaligned on a polyimide(Pl) surface.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.14 no.7
• /
• pp.600-605
• /
• 2001

The electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photo-aligned with polarized UV exposure on various blending photopolymer surfaces were investigated. Excellent LC alignment and voltage-transmittance (V-T) characteristics for TN-LCD photo-aligned with polarized UV exposure of normal incidence on the blending photopolymer (polyimide (PI) +PM4Ch(poly(4-methacryloyloxy chalcone))) surface containing chalcone group can be achieved. The EO performances for the TN-LCD photo-aligned on the blending photopolymer can be improved due to the photosensitivity by long side chain of the photopolymer.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11b
• /
• pp.350-353
• /
• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various photo-crosslinkable polyimide (PI) based polymer and blending photopolymer surfaces were stuided. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyirnide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively, However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.14 no.8
• /
• pp.670-674
• /
• 2001

The electro-optical (EO) performance in the vertical-alignment (VA) - 1/4$\pi$ cell photoaligned with polarized UV exposure on a homeotropic photopolymer surfaces was investigated. Excellent voltage-transmittance curve in the VA - 1/4$\pi$ cell photoaligned with polarized UV exposure for 3 min on the photopolymer containing cholesteryl group of 8% can be achieved. The V-T characteristics in the VA-1/4$\pi$ cell photoaligned on the photopolymer surface can be improved by increasing cholesteryl group. For response time measurement, the transmittance characteristics of the VA-1/4$\pi$ cell photopolymer surface was better than that of the VA-1/4$\pi$ cell rubbingaligned on a polyimide(PI) surface.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.14 no.4
• /
• pp.336-340
• /
• 2001

We have investigated the generation of pretilt angle and alignment stability for a nematic liquid crystal (NLC) with obliquely polarized UV exposure on the three kinds of photo-polymer. High pretilt angle of the NLC was obtained by polarized UV exposure on a PM4Ch surface for 1 min. But, the low pretilt angle of he NLC on a PVCi surface was observed. The pretilt angle generated is attributed ot the photosensitivity by the long side chaining of photo-polymer. Also, a good thermal stability of the three kinds of photo-polymer were obtained by thermogravimetric analysis (TGA) measurement until 300$^{\circ}C$. Finally, the good LC aligning capabilities using the photodimerization method were observed by annealing-treatment until 150$^{\circ}C$.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.10
• /
• pp.911-917
• /
• 1998

In this paper, we have investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet(UV) light irradiation polyimide (PI) surface. It was found that the monodomain alignment of the NLC is obtained with an angle of incidence of 70∼85。 on PI surface. It is considered that the monodomain alignment of NLC is attributed to anisotropic of NLC is about 3。 with and angle of incidence of 70∼75。. Finally, we observed that the voltage-transmittance, response time, and voltage-holding-ratio(VHR) characteristics of photo-aligned twisted nematic(TN)-LCD with and angle of incidence of 85。 on PI surface were almost same compared to rubbing -treated TN-LCD.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1998.06a
• /
• pp.109-112
• /
• 1998

In this paper, we studied on electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-LCD. We obtained that uniform LC alignment in TN-LCD with linearly polarized ultraviolet (LPUV) light irradiation on polyimide (PI) surface increases according to increasing irradiation time for 10 to 60 min. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with UV light irradiation time of 60 min were almost same in comparison with conventional TN-LCD were observed. From the results, we suggest that photo-aligned TN-LCD with LPUV light irradiation on PI surface is useful in applying LCD as for rubbing-free treatment method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11a
• /
• pp.350-353
• /
• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable polyimide (PI) based Polymer and blending photopolymer surfaces were studied. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decal (de), and cholesterol (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.14 no.11
• /
• pp.917-921
• /
• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable Polyimide (Pl) based polymer and blending photopolymer surfaces were investigated. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (Pl and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.