• Title/Summary/Keyword: po

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Improvement of Electrochemical Performance of LiFePO4 by Carbon Coating and Morphology Control into Porous Structure (LiFePO4/C의 carbon coating 방법 및 다공성 구조 형성에 의한 전기화학적 특성 개선)

  • Kong, Ki Chun;Ju, Jeh Beck
    • Journal of the Korean Electrochemical Society
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    • v.17 no.4
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    • pp.229-236
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    • 2014
  • In this study, the method to improve the electrochemical performance of $LiFePO_4$ by carbon coating and morphology control into porous structure was studied. The synthesis of $LiFePO_4$ was done by coprecipitation method by two step procedure. In the first step $FePO_4$ precursor was synthesized by coprecipitation method, followed by impregnation of lithium into the precursor at $750^{\circ}C$. The carbon coating was done by both physical and chemical coating processes. Using the physical coating process, the amount of coating layer was 6% and the capacity achieved was 125 mAh/g. In case of chemical coating process, the active material delivered 130~140 mAh/g, which is about 40% improvement of delivered capacity compared to uncoated $LiFePO_4$. For the morphology control into porous structure, we added nano particles of $Al_2O_3$ or $SiO_2$ into the active materials and formed the nanocomposite of ($Al_2O_3$ or $SiO_2$)/$LiFePO_4$. Between them, $SiO_2/LiFePO_4$ porous nanocomposite showed larger capacity of 132 mAh/g.

Protective effects of perilla oil and alpha linolenic acid on SH-SY5Y neuronal cell death induced by hydrogen peroxide

  • Lee, Ah Young;Choi, Ji Myung;Lee, Myoung Hee;Lee, Jaemin;Lee, Sanghyun;Cho, Eun Ju
    • Nutrition Research and Practice
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    • v.12 no.2
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    • pp.93-100
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    • 2018
  • BACKGROUND/OBJECTIVE: Oxidative stress plays a key role in neuronal cell damage, which is associated with neurodegenerative disease. The aim of present study was to investigate the neuroprotective effects of perilla oil (PO) and its active component, alpha-linolenic acid (ALA), against hydrogen peroxide $(H_2O_2)$-induced oxidative stress in SH-SY5Y neuronal cells. MATERIALS/METHODS: The SH-SY5Y human neuroblastoma cells exposed to $250{\mu}M$ $H_2O_2$ for 24 h were treated with different concentrations of PO (25, 125, 250 and $500{\mu}g/mL$) and its major fatty acid, ALA (1, 2.5, 5 and $25{\mu}g/mL$). We examined the effects of PO and ALA on $H_2O_2$-induced cell viability, lactate dehydrogenase (LDH) release, and nuclear condensation. Moreover, we determined whether PO and ALA regulated the apoptosis-related protein expressions, such as cleaved-poly ADP ribose polymerase (PARP), cleaved caspase-9 and -3, BCL-2 and BAX. RESULTS: Treatment of $H_2O_2$ resulted in decreased cell viability, increased LDH release, and increase in the nuclei condensation as indicated by Hoechst 33342 staining. However, PO and ALA treatment significantly attenuated the neuronal cell death, indicating that PO and ALA potently blocked the $H_2O_2$-induced neuronal apoptosis. Furthermore, cleaved-PARP, cleaved caspase-9 and -3 activations were significantly decreased in the presence of PO and ALA, and the $H_2O_2$-induced up-regulated BAX/BCL-2 ratio was blocked after treatment with PO and ALA. CONCLUSIONS: PO and its main fatty acid, ALA, exerted the protective activity from neuronal oxidative stress induced by $H_2O_2$. They regulated apoptotic pathway in neuronal cell death by alleviation of BAX/BCL-2 ratio, and down-regulation of cleaved-PARP and cleaved caspase-9 and -3. Although further studies are required to verify the protective mechanisms of PO and ALA from neuronal damage, PO and ALA are the promising agent against oxidative stress-induced apoptotic neuronal cell death.

Luminescence Properties of Europium-doped NaSr(PO3)3 Phosphor (Europium이 첨가된 NaSr(PO3)3형광체의 형광특성)

  • Yoon, Changyong;Park, Cheolwoo
    • Journal of the Korean Society of Radiology
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    • v.13 no.4
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    • pp.645-652
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    • 2019
  • Phosphor with phosphorus doped with rare earth ions was investigated by searching Sr and Eu phosphors suitable for substitution of Eu ions with similar ionic radius to polyphosphate host. The $NaSr(PO_3)_3$ phosphor was synthesized by the solid state method and the $NaSr(PO_3)_3:Eu^{2+}$ phosphor was prepared by the carbon thermal reduction method. Both of the phosphors were identified by X - ray diffraction. The excitation and emission spectra of $NaSr(PO_3)_3:Eu^{3+}$ increased fluorescence intensity and intensity quenching with increasing $Eu^{3+}$ concentration. The higher the $Eu^{3+}$ concentration in the emission spectrum, the higher the local symmetry of $Eu^{3+}$ environment. The mechanism of concentration quenching, in which fluorescence decreases due to the energy transfer between $Eu^{2+}$ ions with the closest critical distance between $Eu^{2+}$ ions with increasing $Eu^{2+}$ ion concentration, was confirmed in the emission spectrum of $NaSr(PO_3)_3:Eu^{2+}$ concentration. It is possible to change the fluorescent region through the post-processing of single rare earth ion added phosphors, and it is possible to change the fluorescence by applying the energy transfer and concentration quenching mechanism according to the local symmetry of $Eu^{3+}$ will be used for high phosphor development.

Effect of insect protein and protease on growth performance, blood profiles, fecal microflora and gas emission in growing pig

  • Young Bin, Go;Ji Hwan, Lee;Byong Kon, Lee;Han Jin, Oh;Yong Ju, Kim;Jae Woo, An;Se Yeon, Chang;Dong Cheol, Song;Hyun Ah, Cho;Hae Ryoung, Park;Jin Ho, Cho;Ji Yeon, Chun
    • Journal of Animal Science and Technology
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    • v.64 no.6
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    • pp.1063-1076
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    • 2022
  • Two experiments were conducted to determine the effect of Hermetia illucens larvae (HIL) as protein and protease on growth performance, blood profiles, fecal microflora, and gas emission in growing pig. In experiment 1, the seventy-two crossbred growing pigs ([Landrace × Yorkshire] × Duroc) with an initial body weight (BW) of 27.98 ± 2.95 kg were randomly allotted to one of four dietary treatments (3 pigs per pen and 6 replicates pen per treatments). The experimental design was a 2 × 2 factorial arrangement of treatments evaluating two diets (Poultry offal diets and HIL diets) without or with supplementing protease. The poultry offal in basal diet has been replaced by HIL. In experiment 2, the four crossbred growing pigs ([Landrace × Yorkshire] × Duroc) with an initial BW of 28.2 ± 0.1 kg were individually accepted in stainless steel metabolism cages. The dietary treatments included: 1) PO- (PO-; poultry offal diet), 2) PO+ (PO- + 0.05% protease), 3) HIL- (3% PO of PO- diet was replacement 3% HIL), 4) HIL+ (HIL- + 0.05% protease). In experiment 1, From weeks 0 to 2, average daily gain (ADG) and feed efficiency (G:F) were significantly increased in the PO diet group compared with the HIL group. From weeks 2 to 4, ADG and G:F were higher for protease group than for non-protease group. At weeks 2 and 4, the PO diet group had lower blood urea nitrogen (BUN) levels than HIL diet group. In experiment 2, crude protein (CP) and nitrogen (N) retention were decreased by HIL diet at weeks 2 and 4. The fecal microflora and gas emission were not affected by HIL and protease. The HIL diet showed lower CP digestibility than PO diet and total essential amino acids digestibility tended to higher in PO diet than HIL diet. In summary, the present study revealed that replacement of the PO protein with the HIL protein and the additive of protease in growing pig diets during the overall experimental period had no negative effect.

A Study on Phosphate Removal Characteristic of EAF Slag for Submarine Cover Material (EAF Slag의 해양복토제 활용을 위한$PO_4{^-}-P$ 제거특성에 관한 연구)

  • Kim, Jae-Won;Seo, Jong-Beom;Kang, Min-Gyeong;Kim, In-Deuk;Oh, Kwang-Joong
    • Clean Technology
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    • v.16 no.4
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    • pp.258-264
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    • 2010
  • This study estimated the possibility of phosphate removal characteristics to utilize EAF(electric arc furnace) slag as submarine cover material. The major phosphate removal mechanism was a certain formation of HAP precipitation occurred by the ionization reaction between $Ca^{2+}$ and $OH^-$, which were leached from the EAF Slag. Another phosphate removal mechanism was the adsortion of EAF slag surface. As a result of $PO_4{^-}-P$ removal characteristics using continuous column reactor, $PO_4{^-}-P$ concentration decreased rapidly after 3 days and 10 days later, it show under 0.5 ppm. The result as applied in real sea water, shows that the phosphate removal effects were 93~98% by the subaqueous sediment removal using the EAF slag. In conclusion, EAF slag is useful in $PO_4{^-}-P$ removal and control and it is possible to use without additional process like crush and selection.

Synthesis of Amin-type Anion Exchanger from Acrylic Acid Grafted Polypropylene Nonwoven Fabric and Its Ion-exchange Property(II) (아크릴산 그라프트 폴리프로필렌 부직포로부터 아민형 음이온 교환체의 합성 및 이온교환특성(II))

  • Na, Choon-Ki;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.775-782
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    • 2009
  • PP-g-AA-Am nonwoven fabric, which possess anionic exchangeable function, was prepared by chemical modification of carboxyl (-COOH) group of PP-g-AA nonwoven fabric to amine ($-NH_2$) group using diethylene triamine (DETA). Its adsorption characteristics for anionic nutrients including isotherm, kinetics and co-anions were studied by batch adsorption experiments. Adsorption equilibriums of $PO_4$-P on PP-g-AA-Am fabric were well described by the Langmuir isotherm model, and their adsorption energies were ranged 10.3 kJ/mol indicating an ion-exchange process as primary adsorption mechanism. The adsorption selectivity of PP-g-AA-Am nonwoven fabric for anions under competition with each other was in following order: $SO_4\;^{2-}$>$PO_4\;^{3-}$>$NO_3\;^-$>$NO_2\;^-$. Also, all results obtained from this study indicate that the $PO_4$-P removal capacity of PP-g-AA-Am nonwoven fabric was extremely superior to that of PA308 anion-exchange resin.

A Study on the Modeling of PoF Estimation for Probabilistic Risk Assessment based on Bayesian Method (확률론적 위험도평가를 위한 베이지안 기반의 파손확률 추정 모델링 연구)

  • Kim, Keun Won;Shin, Dae Han;Choi, Joo-Ho;Shin, KiSu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.619-624
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    • 2013
  • To predict the probabilistic service life, statistical factors should be included to consider the uncertainty of parameters. Generally the probabilistic analysis is one of the common methods to account the uncertainty of parameters on the structural failure. In order to apply probabilistic analysis on the deterministic life analysis, it would be necessary to introduce Probability of Failure(PoF) and conduct risk assessment. In this work, we have studied probabilistic risk assessment of aircraft structures by using PoF approach. To achieve this goal, the Bayesian method was utilized to model PoF estimation since this method is known as the proper method to express the uncertainty of parameters. A series of proof tests were also conducted in order to verify the result of PoF estimation. The results from this efforts showed that the PoF estimation model can calculate quantitatively the value of PoF. Furthermore effectiveness of risk assessment approach for the aircraft structures was also demonstrated.

Expression of phospholipase C β1 in olive flounder (Paralichthys olivaceus) following external stress stimulation

  • Woo, Soo Ji;Jang, Hee Young;Lee, Hyung Ho;Chung, Joon Ki
    • Fisheries and Aquatic Sciences
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    • v.19 no.4
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    • pp.18.1-18.10
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    • 2016
  • In this study, to clarify the function of $PoPLC-{\beta}1$, in response to stress challenge, we examined the $PoPLC-{\beta}1$ expression pattern in response to external stress (pathogen-associated molecular pathogen challenge and environmental challenge including temperature and salinity). $PoPLC-{\beta}1$ expression analysis of tissue from olive flounder showed that the messenger RNA (mRNA) was predominantly expressed in the brain, heart, eye, liver, spleen, and stomach. We also tested the mRNA expression of the $PoPLC-{\beta}1$ in the spleen and kidney of olive flounder by RT-PCR and real-time PCR following stimulation with lipopolysaccharide (LPS), concanavalin A (ConA), or polyinosinic:polycytidylic acid (PolyI:C) and compared with the inflammatory cytokines IL-1b and IL-6 in the stimulated flounder tissues. Each of the spleen and kidney and mRNA transcripts of $PoPLC-{\beta}1$ were increased 30- and 10-fold than normal tissue at 1-6 h post injection (HPI) with PolyI:C when the expression of $PoPLC-{\beta}1$ transcript was similar to LPS and ConA. We also tested the expression of $PoPLC-{\beta}1$ in response to temperature and salinity stress. The expression of $PoPLC-{\beta}1$ also was affected by temperature and salinity stress. Our results provide clear evidence that the olive flounder $PLC-{\beta}1$ signal pathways may play a critical role in immune function at the cellular level and in inflammation reactions. In addition, $PLC-{\beta}1$ appears to act as an oxidative-stress suppressor to prevent cell damage in fish.

A Sensing Method of PoRAM with Multilevel Cell (멀티레벨 셀을 가지는 PoRAM의 센싱 기법)

  • Lee, Jong-Hoon;Kim, Jung-Ha;Lee, Sang-Sun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.12
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    • pp.1-7
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    • 2010
  • In this paper, we suggested a sensing method of PoRAM with the multilevel cell When a specific voltage is applied between top and bottom electrodes of PoRAM unit cell, we can distinguish cell states by changing resistance values of the cell. Especially, we can use the PoRAM as the multilevel cell due to have four stable resistance values per cell. Therefore, we proposed an address decoding method, sense amplifier and control signal for sensing of a multilevel cell. The sense amplifier is designed based on a current comparator that compared a cell current the cell with a reference current, and have a low input impedance for a amplification of the current. The proposed circuit was designed in a $0.13{\mu}m$ CMOS technology, we verified to sense each data "00", "01", "10", "10" by four states of a cell current.

A Study of Structure and Thermal Properties of K2O·CaO·P2O5 Glasses (K2O·CaO·P2O5계 유리의 열적특성과 구조분석)

  • Yoon, Young-Jin;Yoon, Tae-Min;Lee, Yong-Soo;Kang, Won-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.194-198
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    • 2002
  • Various composition of $K_2O{\cdot}CaO{\cdot}P_2O_5$ glasses were studied by melting process to identify glass forming region. Thermal properties were observed by DSC and TG-DTA, structural properties were investigated by FT-IR and Raman Spectroscopy. The glass transition temperature (Tg) and softening temperature (Ts) were decreased with increasing $K_2O\;and\;P_2O_5$ contents. The basic structural unit of phosphate glasses is the $PO_2\;and\;PO_4^{3-}$ groups to make a cross-link and P-O-P group to form skeleton structure. As CaO content was increased, the P-O-P field strength in these glass was increased and intensity of $PO_2\;and\;PO_4^{3-}$ stretch was decreased.