• Title/Summary/Keyword: plastics waste

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Review on PVA as a Water Soluble Packaging Material (수용성 폴리비닐알콜(PVA) 포장소재의 이용)

  • Lee, Ji-Youn;Jang, Si-Hun;Park, Su-Il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.15 no.1
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    • pp.25-32
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    • 2009
  • It is now widely recognized that the disposal of packaging waste is an increasing environmental concern. Recent interest in polymer waste management of packaging materials has added incentive to the research. Poly(vinyl alcohol) is a readily biodegradable water-soluble polymer. However, this polymer cannot be processed by conventional extrusion technologies because the melting point of PVA is close to its decomposition temperature. Therefore, PVA films have been mostly prepared by solvent casting from water. Applications of PVA include sizing, binders, fibers, and films for agricultural chemicals and hospital laundry bags. A better understanding of PVA films, which also play important roles in the degradation of plastics, will expand the usage of PVA. Composite films based on PVA generally exhibit better mechanical and thermal properties than pure PVA. The aim of this review article is to review types, formation, and properties of PVA films and PVA based composite films used in packaging related researches.

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Hydrothermal Pre-treatment and Gasification of Solid Wastes to Produce Electrical Power and Hydrogen

  • Yoshikawa, Kunio
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.09a
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    • pp.3-12
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    • 2006
  • The main feature of these total technologies is that we can constitute the optimum treatment scheme fitting to the property of wastes, amount of wastes and energy requirement. For high moisture content wastes or biomass resources, high pressure steam process (MMCS) for crush, dry and deodorize wastes to produce high quality fertilizer of fuel is most appropriate. For dry or semi-dry solid wastes, the STAR-MEET system can be applied to produce low-BTU gases for power generation using duel fueled diesel engines of Stirling engines, and the REPRES and HyPR-MEET systems can be applied to produce hydrogen rich medium-BTU gas. For waste plastics and oils, liquefaction technology is best fit to produce light oil or kerosene equivalent fuel oils. These total technologies are completely different from the existent waste treatment technologies based on land-filling or incineration, and are expected to disseminate all over the world in the near future.

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GASIFICATION OF CARBONEOUS WASTES USING THE HIGH TEMPERATURE REFORMER

  • Lee, Dong-Jin
    • Environmental Engineering Research
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    • v.10 no.3
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    • pp.122-130
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    • 2005
  • Gasification of carbonaceous wastes such as shredded tire, waste lubricating oil, plastics, and powdered coal initiates a single-stage reforming reactor(reformer) Without catalyst and a syngas burner. Syngas is combusted with $O_2$ gas in the syngas burner to produce $H_2O\;{and}\;CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevates the temperature of reactor above $1,200^{\circ}C$, and hydrogen gas fraction reaches 65% of the product gas output. Reactants and heat necessary for the reaction are provided through the syngas burner only. Neither $O_2$ gas nor steam is injected into the reforming reactor. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and the product syngas is recycled into syngas burner.

The Evaluation of a Plastic Material Classification System using Near Field IR (NIR) Spectrum and Decision Tree based Machine Learning (Near Field IR (NIR) 스펙트럼 및 결정 트리 기반 기계학습을 이용한 플라스틱 재질 분류 시스템)

  • Kook, Joongjin
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.92-97
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    • 2022
  • Plastics are classified into 7 types such as PET (PETE), HDPE, PVC, LDPE, PP, PS, and Other for separation and recycling. Recently, large corporations advocating ESG management are replacing them with bioplastics. Incineration and landfill of disposal of plastic waste are responsible for air pollution and destruction of the ecosystem. Because it is not easy to accurately classify plastic materials with the naked eye, automated system-based screening studies using various sensor technologies and AI-based software technologies have been conducted. In this paper, NIR scanning devices considering the NIR wavelength characteristics that appear differently for each plastic material and a system that can identify the type of plastic by learning the NIR spectrum data collected through it. The accuracy of plastic material identification was evaluated through a decision tree-based SVM model for multiclass classification on NIR spectral datasets for 8 types of plastic samples including biodegradable plastic.

A Study of School Waste Disposal Status and Its Reforms (Public Primary and Secondary Schools in Seoul) (학교 쓰레기 처리현황과 개선에 관한 연구 - 서울시 공립 초.중등학교를 대상으로 -)

  • 노성빈
    • Hwankyungkyoyuk
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    • v.3 no.1
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    • pp.130-140
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    • 1992
  • The purpose of this study was to survey the trends of waste products in schools, its gathering and disposal, identification of problems and to analyze its disposal. Moreover, this study was aimed at basic suggestions about the establishment and plans of waste environmental education. 98 public primary and secondary schools were surveyed in Seoul during the month of March and April, 1991. Information was collected from each educational association by random sampling. Questionaries were used for this survey. To understand the disposal status of school waste and its reforms, this study surveyed the amount of waste by products, their origin and analyzed the disposal by type, one number of schools and teachers involved. The dump sited and disposal methods of school waste, its problems, and the status of school waste educations were researched, and ideal disposal methods and plans for waste education were suggested. The results were as follows. 1. The School's trash was produced by followings: paper, vinyle plastics, food, woods, metals, ceramics, glass, bottles, and ash from the heating system. The biggest cause of the school's waste as shown by the survey was a lack of environmental awareness(39.8%). The second biggest was the use of a one time use of disposable paper products(27.6%). 2. Waste collection by different grade levels were proven to be important but as you move from elementary to high school, the waste collecting operation decreased, in this connection between the students and waste collection itself it was significant on the other hand the teachers were not working as significant variables. 3. Of the school that collected waste 69.5 percent of the schools separately grouped common waste and recyclable waste. 25 schools(42.4%) received improvement on their environmental awareness of trash collection through this method. 4. From the number of disposal sites in surveyed schools, it was determined that the education of the necessity for separation of waste was performed in vain and accordingly the should require a real education in the future. 5. Regarding the method of disposal of waste the survey indicated that the #1 method of disposal was partial burning and the remains carried to a dump site by others(35,7%). In elementary schools the entire waste was taken by individuals to a dump site (33.3%). In high schools partial burning and then transported by individuals #1 in our survey(50%). 6. Relative to the problem of the treatment to waste, the emission of smoke from the burning was considered to be the #1 priority in our survey (62.3%) the problem of trash collection being delayed was 52.1%(1in our survey). 7. The present situation of environmental education of waste us lacking. Under present circumstances, the practice of public announcements for improvement and waste-paper collection has been going on vigorously but lacking in education as to the preparation of compositions for students the themes of public exhibitions, the organizing of voluntary associations should be part of the education system to reinforce student's awareness of proper waste disposal. 8. The most economical alternative for disposal was recycling usable waste or combustible material through a variety of education we can therefore educate students bring this education to their homes public servants will also be able to benefit in the waste disposal process with proper education. In conclusion we should intensify the systemical organization and the education of our waste disposal for a better environment.

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A Study on the Enhancement of Inventories for Precursors (NOx, SOx) Released from Open Burning of Agricultural Waste Vinyl Causing the Secondary Generation of Particulate Matters

  • Kim, Tae-Han;Choi, Boo-Hun
    • Journal of People, Plants, and Environment
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    • v.24 no.2
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    • pp.195-207
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    • 2021
  • Background and objective: While response measures to particulate matters in rural areas are limited due to poor inventory record keeping in the agricultural sector, it is necessary to control agricultural waste vinyl and the emission of precursors released from open burning and the secondary generation of particulate matters. Currently, the open burning emission calculation method uses the definition prescribed in CAPSS by the National Institute of Environmental Research. Methods: This study presented an open burning emission calculation formula for agricultural waste vinyl, which is included as agricultural waste. As for activity data, the open burning ratio of agricultural waste vinyl, and the annual incineration volume provided in the Status Survey by the Ministry of Agriculture, Food, and Rural Affairs were applied. The emission factor was generated through incineration tests on three agricultural plastic film samples collected by the Korea Environment Corporation. Results: Among precursors, SOx and NOx were selected and their emission features were monitored with incineration experiment infrastructure based on the EPA 5G method. The highest emission concentration by agricultural waste type was concentrated in the first and second quarters. As for emission factor of SO2, it was calculated at 98.25 g/kg for mulching-use LDPE, 52.31 g/kg for greenhouse-use LDPE, and 14.40 g/kg for HDPE. As for NOx, it was calculated at 18.21 g/kg for mulching-use LDPE, 16.49 g/kg for greenhouse-use LDPE, and 10.67 g/kg for HDPE. Conclusion: This test confirmed the incineration features of PE-based plastics, ascertained the SOx emission factor that had not been included in open burning in the past, and established that low NOx emission concentration is interfered by soil mixed with livestock excretions. The findings from this study are expected to contribute to improving the system for controlling air pollutants in rural environments.

Development of moveable instrument for fuel of cement production and of clean process for cement production using waste plastics from agriculture (농업용 폐비닐을 이용한 이동식 시멘트 연료 제조 장치 및 이를 이용한 시멘트 제조 청정 공정 개발)

  • Seo, Hyung-Nam;Goo, Sang-Ser;Choi, Young-Ki;Min, Kyung-So;Kang, Seong-Gu;Oh, Hea-Kap
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.109-113
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    • 2004
  • In this study, we tried to develop the moveable instrument for fuel of cement production by using waste plastics from agriculture that was not recycled. First we investigated the burning character of recycled fuel and feasibility of second pollution. Then we made the instrument which can produce the solid fuel under 1cm size. In changing the inputting method from pre-heater to main burner, this reduces the NOx and O2 emission rate. and When we input it 0.5ton/hour, we obtain 0.2-0.3 ton/hour reduction of coal amount.

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Recycling of Red Mud as Plastic Fillers (플라스틱 Filler로서의 적니의 재활용)

  • Kim, Jeong Ho;Soh, Young Soo;Kim, Joon-Hyung
    • Clean Technology
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    • v.5 no.2
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    • pp.45-52
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    • 1999
  • Recycling of red mud from the aluminium manufacturing process was investigated to be utilized as plastic fillers. High density polyethylene(HDPE), low density polyethylene(LDPE) and polypropylene(PP) were found to be the suitable plastic material for which red mud can be used as fillers. With the addition of red mud the plastic showed red brown color. As the ratio of amount of red mud to plastic increased, the tensile strength increased while the Izod impact strength decreased. About five percent of ethylene vinyl alcohol(EVA) was needed as an additive to prevent the lowering of impact strength. Maleic anhydride modified polypropylene was effective for reduction of impact strength lowering of PP. Mixed waste plastics containing LDPE, HDPE, PP, polystyrene and ABS could also accommodate red mud as fillers. In this case, significant loss in mechanical properties were observed due to immiscibility between the components. Ethylene propylene rubber(EPR) and styrene butadiene styrene block copolymer (SBS) could be used to improve the impact properties of the commingled waste plastics.

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Design of Fuzzy Clustering-based Neural Networks Classifier for Sorting Black Plastics with the Aid of Raman Spectroscopy (라만분광법에 의한 흑색 플라스틱 선별을 위한 퍼지 클러스터링기반 신경회로망 분류기 설계)

  • Kim, Eun-Hu;Bae, Jong-Soo;Oh, Sung-Kwun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.7
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    • pp.1131-1140
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    • 2017
  • This study is concerned with a design methodology of optimized fuzzy clustering-based neural network classifier for classifying black plastic. Since the amount of waste plastic is increased every year, the technique for recycling waste plastic is getting more attention. The proposed classifier is on a basis of architecture of radial basis function neural network. The hidden layer of the proposed classifier is composed to FCM clustering instead of activation functions, while connection weights are formed as the linear functions and their coefficients are estimated by the local least squares estimator (LLSE)-based learning. Because the raw dataset collected from Raman spectroscopy include high-dimensional variables over about three thousands, principal component analysis(PCA) is applied for the dimensional reduction. In addition, artificial bee colony(ABC), which is one of the evolutionary algorithm, is used in order to identify the architecture and parameters of the proposed network. In experiment, the proposed classifier sorts the three kinds of plastics which is the most largely discharged in the real world. The effectiveness of the proposed classifier is proved through a comparison of performance between dataset obtained from chemical analysis and entire dataset extracted directly from Raman spectroscopy.

Distinct Bacterial and Fungal Communities Colonizing Waste Plastic Films Buried for More Than 20 Years in Four Landfill Sites in Korea

  • Joon-hui Chung;Jehyeong Yeon;Hoon Je Seong;Si-Hyun An;Da-Yeon Kim;Younggun Yoon;Hang-Yeon Weon;Jeong Jun Kim;Jae-Hyung Ahn
    • Journal of Microbiology and Biotechnology
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    • v.32 no.12
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    • pp.1561-1572
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    • 2022
  • Plastic pollution has been recognized as a serious environmental problem, and microbial degradation of plastics is a potential, environmentally friendly solution to this. Here, we analyzed and compared microbial communities on waste plastic films (WPFs) buried for long periods at four landfill sites with those in nearby soils to identify microbes with the potential to degrade plastics. Fourier-transform infrared spectroscopy spectra of these WPFs showed that most were polyethylene and had signs of oxidation, such as carbon-carbon double bonds, carbon-oxygen single bonds, or hydrogen-oxygen single bonds, but the presence of carbonyl groups was rare. The species richness and diversity of the bacterial and fungal communities on the films were generally lower than those in nearby soils. Principal coordinate analysis of the bacterial and fungal communities showed that their overall structures were determined by their geographical locations; however, the microbial communities on the films were generally different from those in the soils. For the pulled data from the four landfill sites, the relative abundances of Bradyrhizobiaceae, Pseudarthrobacter, Myxococcales, Sphingomonas, and Spartobacteria were higher on films than in soils at the bacterial genus level. At the species level, operational taxonomic units classified as Bradyrhizobiaceae and Pseudarthrobacter in bacteria and Mortierella in fungi were enriched on the films. PICRUSt analysis showed that the predicted functions related to amino acid and carbohydrate metabolism and xenobiotic degradation were more abundant on films than in soils. These results suggest that specific microbial groups were enriched on the WPFs and may be involved in plastic degradation.