• 한국환경과학회지
• /
• 제23권11호
• /
• pp.1909-1918
• /
• 2014

In this experiment no solvent based polyurethane(PU) adhesives were prepared with the polyol, isocyanate, dioctyl phthalate(DOP), 2-hydroxyethylacrylate(2-HEA) and other acrylate monomers. The softenening point of the PU adhesives measured by Ring & Ball method were examined in the present study. And adhesion strength and mechanical properties such as tensile strength and 100% modulus of the PU adhesives were evaluated by Universal Test Machine. The experimental results showed that increase of both DPE-41, benzoylperoxide(BPO) and toluene diisocyanate(TDI) increased softenening point, adhesion strength, tensile strength and 100% modulus. However as DOP content increased sofenening point, adhesion strength decreased and tensile strength, 100% modulus also decreased.

• 전기화학회지
• /
• 제6권2호
• /
• pp.141-144
• /
• 2003

Proton conducting polymeric gels as the electrolytes of electrochemical capacitors have been prepared by two different methods: 1) swelling a polymethacrylate-based polymer matrix in aqueous solutions of inorganic and organic acids, and 2) polymerizing complexes of anhydrous acids and prepolymers with organic plasticizer. The FT-IR spectra strongly suggest that the carbonyl groups in the polymer matrix interact with protons from the doped acids. High ionic (proton) conductivity in the range of $6\times10^{-4}-4\times10^{-2}\;S\;cm^{-1}$ was obtained at room temperature for the aqueous gels. The non-aqueous polymer complexes showed rather low ionic conductivity, but it was about $10^{-3}\;S\;cm^{-1}\;at\;70^{\circ}C$ for the $H_3PO_4$ doped polymer electrolyte. The mechanisms of ion (proton) conduction in the polymeric systems are discussed.

• Bulletin of the Korean Chemical Society
• /
• 제23권5호
• /
• pp.683-687
• /
• 2002

We have investigated the effect of the number of ethylene oxide (EO) units inside poly(ethylene glycol)dimethacrylate (PEGDMA) on the ionic conductivity of its gelled polymer electrolyte, whose content ranges from 50 to 80 wt%. PEGDMA gelled polym er electrolytes, a crosslinked structure, were prepared using simple photo-induced radical polymerization by ultraviolet light. The effect of the number of EO on the ionic conductivity was clearly shown in samples of lower liquid electrolyte content. We have concluded that the ionic conductivity increased in proportion to both the number of EO units and the plasticizer content. We have also studied the electrochemical properties of 13PEGDMA (number of EO units is 13) gelled polymer electrolyte.

• 공업화학
• /
• 제20권4호
• /
• pp.363-369
• /
• 2009

오일 가격의 폭등에 따른 바이오디젤 사용량의 증가로 인해 글리세롤 부산물의 공급과잉이 유발되었다. 원래 글리세롤은 석유화학,페인트,담배, 생활용품 및 화장품 분야에 원료자체로써 사용되어 왔다. 최근에는 글리세롤을 값싼 원료로 사용하여 고부가가치의 기능성 물질을 개발하는 응용 연구를 통해 고부가가치의 유도체 물질로 상용화되는 사례가 많이 보고되고 있다. 본 총설에서는 글리세롤을 원료로 사용하여 새로운 고부가 글리세롤 유도체로 개발한 연구동향을 검토해 보았다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
• /
• pp.1059-1064
• /
• 2001

This study is about accurate steel column position method in the Top down method's delicate part. When the concrete is placing, it is required that complementary measures to the transformation due to concrete pressure, column buckling, the trouble due to bar net inserting and so on. To solve the problem of exist method, the concrete is placed at the bottom of excavated hole in advance. then, the steel column is inserted into the excavated hole. With a new method try, the problem due to placing pressure and others is could be prevented. In this study, the concrete is examined with test-slump, slump flow, and compressive strength to do quantitative analysis of concrete. The factors of the experiment is plasticizer, retarder addition rate, fly ash substitution rate to cement. Considering of the new method try, the retarder added concrete properties-fluidity, viscosity, strength-is investigated as time lapsing.

• 한국안전학회지
• /
• 제9권1호
• /
• pp.68-75
• /
• 1994

The cetylpyridium ion-selective electrode were developed by dibenzo-18-crown-6 for auto control of the chemical plants. The effect of content of active material and the membrane thickness on the response characteristics of electrode such as the linear reponse range, the detection limit, and Nemstian slope of the electrod, were studied. The electrode characteristics was better with decreasing the content of active material above the optimum content, but became worse below these. DBP was best as a plasticizer, The effect of the membrane thickness on the electrode characteristics was improved with decreasing the membrane thickness, but below the optimum membrane thickness the electrode exhibited an inverse trend.

• Journal of Biosystems Engineering
• /
• 제28권2호
• /
• pp.143-150
• /
• 2003

전분 완충재의 물리적, 기계적 특성을 개선하기 위한 노력들이 많이 이루어지고 있지만 기존의 플라스틱 완충재와 비교하면 더 많은 노력이 요구되어진다. 그래서 본 연구에서는 전분 완충재의 물리적 기계적 특성에 대한 유연제(plasticizers)와 첨가제(additives)의 영향을 규명하였다. 전분과 합성수지 그리고 여러 유연제 또는 첨가제를 혼합한 뒤 Brabender사의 일축 압출기를 이용하여 여러 축속도(60~120 rpm)에서 압출 가공한 후 물리적, 기계적 특성을 조사하였다. 전분 완충재의 밀도(bulk density)와 압축성(bulk compressibility)은 혼합물에서 물의 비율이 증가함에 따라 증가하였지만, 복원성(bulk resiliency)은 조금 감소하였다. 측정되어진 전분 완충재의 특성은 변형전분(hydroxypropylated starch)의 사용으로 향상되었다. 또한, glycerol, glycerol monostearate 그리고 alkylglucosides의 첨가도 전분 완충재의 밀도와 압축성을 증가시켰다. 염화철(II) 0.5%을 포함한 전분 완충재는 첨가제를 포함하지 않은 전분 완충재에 비하여 밀도 42%와 압축성 58%가 각각 감소한 반면, 복원성은 13%포인트 증가하였다. 변형전분과 염화철(II)이 첨가된 전분 완충재는 기존의 플라스틱 완충재에 비하여 밀도와 압축성은 떨어지지만, 대체 사용되어질 수 있는 것으로 판단되었다.

• Journal of Biosystems Engineering
• /
• 제37권3호
• /
• pp.209-213
• /
• 2012

Purpose: This study was performed to develop a simple, disposable thin-film optical nitrate sensor. Methods: The sensor was fabricated by applying a nitrate-selective polymer membrane on the surface of a thin polyester film. The membrane was composed of polyvinylchloride (PVC), plasticizer, fluorescent dye, and nitrate-selective ionophore. Fluorescence intensity of the sensor increased on contact with a nitrate solution. The fluorescence response of the optical nitrate sensor was measured with a commercial fluorospectrometer. Results: The optical sensor exhibited linear response over four concentration decades. Conclusions: Nitrate ion concentrations in plant nutrient solutions can be determined by direct optical measurements without any conditioning before measurements.

• 한국자동차공학회논문집
• /
• 제21권3호
• /
• pp.126-133
• /
• 2013

Recently, it was reported that complaints about problems being experienced with the performance of vehicles operating on autogas in Korea. The problem was being assumed due to contaminants in LPG and an oily material which was being deposited in vaporizer, injector in LPG fuel system. This study is focused on the analysis of contaminant of automobile parts on LPG fuel system. The sampling points of contaminants are injectors, fuel filters, vaporizer in automobile equipment and it was also investigated by GC-MS, ICP-AES, SIMDIS and EDS. According to results, it was presumed that this contaminants had been analyzed plasticizers with hydrocarbons with high boiling point, Fe from steel corrosion, greases from gas station.

• 한국안전학회지
• /
• 제5권2호
• /
• pp.40-49
• /
• 1990

For the determination of polluant NOx in ambient air, nitrate ion-selective electrode(ISE) was made. To comparison of NOx in each method, the nitrate-ISE, NEBA, Orion electrode were used to determinee NOx in ambient air. In this work, the concentration of NOx in ambient air was average 0.06ppm. The results were good agreement with those obtained by each method within a relative error of 3％, Absorbing efficiency of nitrogen oxides in ambient air was good for Alkali solution. The determination of nitrogen oxides in ambient air using the Aliquat 336N-PVC membrane electrode was one of the useful method. The best characteristics of the Aliquat 336N-PVC me,mbrane electrode were obtained with the ion-exchanger concentration level of 6.5-9.1 percent by weight. The optimal membrane composition, was 9.09wt.％ of ion-exchanger, 30.95wt.％ of PVC, 60.6wt.％ of plasticizer (DBP), and 0.5mm of thickness. Under the above condition, the electrode approached the Nernstian slope most closely, and the linear response ranges produced the best results.