• Proceedings of the Korean Society of Precision Engineering Conference
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• 2010.05a
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• pp.1315-1316
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• 2010

• Macromolecular Research
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• v.17 no.12
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• pp.963-968
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• 2009

Liquid crystal (LC; E7 and/or ML-0249)-embedded, poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP)-based, polymer electrolytes were prepared for use in dye-sensitized solar cells (DSSCs). The electrolytes contained 1-methyl-3-propylimidazolium iodide (PMII), tetrabutylammonium iodide (TBAI), and iodine ($I_2$), which participate in the $I_3^-/I^-$ redox couple. The incorporation of photochemically stable PVdF-co-HFP in the DSSCs created a stable polymer electrolyte that resisted leakage and volatilization. DSSCs, with liquid crystal(LC)-embedded PVdF-co-HFP-based polymer electrolytes between the amphiphilic ruthenium dye N719 absorbed to the nanocrystalline $TiO_2$ photoanode and the Pt counter electrode, were fabricated. These DSSCs displayed enhanced redox couple reduction and reduced charge recombination in comparison to that fabricated from the conventional PVdF-co-HFP-based polymer electrolyte. The behavior of the polymer electrolyte was improved by the addition of optimized amounts of plasticizers, such as ethylene carbonate (EC) and propylene carbonate (PC). The significantly increased short-circuit current density ($J_{sc}$, $14.60\;mA/cm^2$) and open-circuit voltage ($V_{oc}$, 0.68 V) of these DSSCs led to a high power conversion efficiency (PCE) of 6.42% and a fill factor of 0.65 under a standard light intensity of $100\;mW/cm^2$ irradiation of AM 1.5 sunlight. A DSSC fabricated by using E7-embedded PVdF-co-HFP-based polymer electrolyte exhibited a maximum incident photon-to-current conversion efficiency (IPCE) of 50%.

• Journal of Ocean Engineering and Technology
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• v.25 no.3
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• pp.53-65
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• 2011

This is the third of several companion papers dealing with the derivation of material constants for ductile failure criteria under hydrostatic stress. It was observed that the ultimate engineering stresses and elongations at fracture from tensile tests for round specimens with various notch radii tended to increase and decrease, respectively, because of the stress triaxiality. The engineering stress curves from tests are compared with numerical simulation results, and it is proved that the curves from the two approaches very closely coincide. Failure strains are obtained from the equivalent plastic strain histories from numerical simulations at the time when the experimental engineering stress drops suddenly. After introducing the new concept of average stress triaxiality and accumulated average strain energy, the material constants of the Johnson-Cook failure criterion for critical energies of 100%, 50%, and 15% are presented. The experimental results obtained for EH-36 steel were in relatively good agreement with the 100% critical energy, whereas the literature states that aluminum fits with a 15% critical energy. Therefore, it is expected that a unified failure criterion for critical energy, which is available for most kinds of ductile materials, can be provided according to the used materials.

• Geophysics and Geophysical Exploration
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• v.14 no.4
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• pp.282-288
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• 2011

One of the most challenging issues facing shallow seismic survey is how to generate large amplitude of high frequency signal with small seismic sources. We tested the performance of the most commonly used shallow seismic source, hammer, with four plates: PE, nylon, aluminum, and steel plates. We compared their signal powers in terms of impulsive forces, accelerations, and ground vibration velocities caused by hammer impacts. According to a previous work, hammer blowing to an aluminum plate would generate the largest amplitude among four combinations. However, it was found in this experimental research that aluminum plate delivers seismic wave energy to the ground less than that generated with steel or PE plate. Even though the amplitude is relatively small, plastic plates could provide seismic pulses of 180 ~ 200 Hz in the bandwidth, and it seems to be very hard to generate seismic energy over the frequency of 250 Hz.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.10
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• pp.1249-1255
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• 2011

A PHE (Process Heat Exchanger) is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR (Very High Temperature Reactor) to a chemical reaction that yields a large quantity of hydrogen. A small-scale PHE prototype made of Hastelloy-X was scheduled for testing in a small-scale gas loop at the Korea Atomic Energy Research Institute. In this study, as a part of the evaluation of the high-temperature structural integrity of the PHE prototype, high-temperature structural analysis modeling, and macroscopic thermal and elastic-plastic structural analysis of the PHE prototype were carried out under the gas-loop test conditions as a preliminary qwer123$study before carrying out the performance test in the gas loop. The results obtained in this study will be used to design the performance test setup for the modified PHE prototype.

• Environmental Engineering Research
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• v.23 no.3
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• pp.250-257
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• 2018

We developed new composites by combining the solid waste from Low-Density Polyethylene in the form of plastic bag (PB) and biomass from rice husk (RH),in the form of $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)), as alternative fuels for electrical energy sources, and for providing the best solution to reduce environmental pollution. Elemental compositions were obtained by using proximate analysis, ultimate analysis, and X-ray fluorescence spectroscopy, and the thermal characteristics were obtained from thermogravimetric analysis. The compositions of carbon and hydrogen from the ultimate analysis show significant increases of 20-30% with increasing PB in the composite. The activation energy for RH is 101.22 kJ/mol; for x = 0.9 and 0.7, this increases by 4 and 6 magnitude, respectively, and for x = 0.5, shows remarkable increase to 165.30 kJ/mol. The range of temperature of about $480-660^{\circ}C$ is required for combustion of the composites $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)) to perform the complete combustion process and produce high energy. In addition, the calorific value was determined by using bomb calorimetry, and shows value for RH of 13.44 MJ/kg, which increases about 30-40% with increasing PB content, indicating that PB has a strong effect of increasing the energy realized to generate electricity.

• Clean Technology
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• v.15 no.3
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• pp.186-193
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• 2009

The characteristics of product materials obtained from thermal degradation of low-qualify pyrolytic oil were investigated in this study. The reactants were produced by pyrolysis of mixed plastic waste with film type in a commercial rotary kiln reaction system. The properties of reactants were measured by elemental analysis, calorimetry analysis and SIMDIST analyst. The result of degradation experiments with different reaction temperature programs was discussed through product yields, cumulative yields and production rates of oil products. The multi-step reaction temperature program resulted in higher yields of product oils and lower yields of residues than one-step reaction temperature program. The product characteristics such as production yield and the rate of oil products etc. were influenced by reaction temperature program in the continuous thermal degradation.

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.23-28
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• 2017

Pyrolysis characteristics of waste plastic films were investigated by using a thermogravimetric analysis and pyrolyzer-gas chromatography/mass spectrometry. Thermogravimetric analysis results revealed that the pyrolysis of waste plastic films can be divided into two distinct reactions; (1) the decomposition reaction of starch at between 200 and $370^{\circ}C$ and (2) that of other plastic polymers such as PS, PP, PE at between 370 and $510^{\circ}C$. The kinetic analysis results obtained by using the revised Ozawa method indicated that the apparent activation energy of the pyrolysis reaction of waste plastic films was also changed dramatically according to the different decomposition reactions of two major waste plastic film components. Py-GC/MS results also revealed that the typical pyrolyzates of each polymer in waste plastic films were levoglucosan (starch), terephthalic acid (PET), styrene monomer, dimer, and trimer (PS), methylated alkenes (PP), and triplet peaks (PE) composed of alkadiene/alkene/alkane. The phthalate, used as a polymer additive, was also detected on the pyrogram of waste plastic films mixture.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.210-210
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• 2012

Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

• Steel and Composite Structures
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• v.37 no.3
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• pp.259-272
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• 2020

In this study a new hysteretic damper for seismic retrofit of soft-first story structures is proposed and its seismic retrofit effect is evaluated. The damper consists of one steel column member and two flexural fuses at both ends made of steel plates with reduced section, which can be placed right beside existing columns in order to minimize interference with passengers and automobiles in the installed bays. The relative displacement between the stories forms flexural plastic hinges at the fuses and dissipate seismic energy. The theoretical formulation and the design procedure based on plastic analysis is provided for the proposed damper, and the results are compared with a detailed finite-element (FE) model. In order to apply the damper in structural analysis, a macromodel of the damper is also developed and calibrated by the derived theoretical formulas. The results are compared with the detailed FE analysis, and the efficiency of the damper is further validated by the seismic retrofit of a case study structure and assessing its seismic performance before and after the retrofit. The results show that the proposed hysteretic damper can be used effectively in reducing damage to soft-first story structures.