• Title/Summary/Keyword: plastic energy

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Energetic Thermoplastic Elastomers from Azidated Polyepichlorohydrin Rubber (Az-PECH)/ Styrene Acrylonitrile Copolymer (SAN) Blends (아지드화 폴리에피클로로히드린 고무/스티렌-아크릴로니트릴 공중합체 블렌드로부터 에너지함유열가소성탄성체 제조)

  • Choi, Myung-Chan;Chang, Young-Wook;Noh, Si-Tae;Kwon, Jung-Ok;Kim, Dong-Kook;Kwon, Soon-Kil
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.375-380
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    • 2009
  • Polyepichlorohydrin rubber was treated with sodium azide (Na$N_3$) to replace its chlorine by azide ($N_3$). Then, the azidated polyepichlorohydrin rubber (Az-PECH) was blended with thermoplastic styrene-acrylonitrile copolymer with the rubber/plastic ratio of 80/20, 70/30 and 60/40 (wt/wt). The miscibility, mechanical and dynamic mechanical properties as well as elastic recovery properties of the blends were evaluated by DMA (Dynamic Mechanical Analyzer) and tensile tests. When azidation level in azidated PECH was upto 50%, the blends exhibited excellent miscibility, manifested by a single $T_g$, and fairly good elastic recovery. When azidation level was 75%, the blends showed phase separation. The miscible Az-PECH/SAN blends exhibited typical thermoplastic elastomer like properties, ie. melt processibility and high extensibility as well as good elastic recovery rate. It was also observed from combustion test that higher energy is released with the increase in the azidation level of the Az-PECH in the blends.

Particle Size-Dependent Failure Analysis of Particle-Reinforced Metal Matrix Composites using Dislocation Punched Zone Modeling (전위 펀치 영역 모델링에 의한 입자 강화 금속지지 복합재의 입자 크기 의존 파손 해석)

  • Suh, Yeong Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.3
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    • pp.275-282
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    • 2014
  • Particle-reinforced metal matrix composites exhibit a strengthening effect due to the particle size-dependent length scale that arises from the strain gradient, and thus from the geometrically necessary dislocations between the particles and matrix that result from their CTE(Coefficient of Thermal Expansion) and elastic-plastic mismatches. In this study, the influence of the size-dependent length scale on the particle-matrix interface failure and ductile failure in the matrix was examined using finite-element punch zone modeling whereby an augmented strength was assigned around the particle. The failure behavior was observed by a parametric study, while varying the interface failure properties such as the interface strength and debonding energy with different particle sizes and volume fractions. It is shown that the two failure modes (interface failure and ductile failure in the matrix) interact with each other and are closely related to the particle size-dependent length scale; in other words, the composite with the smaller particles, which is surrounded by a denser dislocation than that with the larger particles, retards the initiation and growth of the interface and matrix failures, and also leads to a smaller amount of decrease in the flow stress during failure.

Fabrication of a-Si:H/a-Si:H Tandem Solar Cells on Plastic Substrates (플라스틱 기판 위에 a-Si:H/a-SiGe:H 이중 접합 구조를 갖는 박막 태양전지 제작)

  • Kim, Y.H.;Kim, I.K.;Pyun, S.C.;Ham, C.W.;Kim, S.B.;Park, W.S.;Park, C.K.;Kang, H.D.;You, C.;Kang, S.H.;Kim, S.W.;Won, D.Y.;Choi, Y.;Nam, J.H.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.104.1-104.1
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    • 2011
  • 가볍고, 유연성(flexibility)을 갖는 박막(thin film)형 플랙서블 태양전지(flexible solar cell)는 상황에 따른 형태의 변형이 가능하여, 휴대가 간편하고, 기존 혹은 신규 구조물의 지붕(rooftop)등에 설치가 용이하여, 차세대 성장 동력 분야에서 각광받고 있다. 그러나 아직까지 플랙서블 태양전지는 제작시 열에 의한 기판의 변형, 기판 이송시 너울 현상, 대면적 패터닝(patterning) 기술 등 많은 어려움 등으로 웨이퍼나 글라스 기판에 제조된 태양전지 대비 낮은 광전환 효율을 갖는다. 따라서 본 연구에서는 플랙서플 태양전지 성능개선을 위해 3.5세대급 ($450{\times}450cm^2$) 스퍼터(sputter), 금속유기 화학기상장치 (MOCVD), 플라즈마 화학기상장치 (PECVD), 레이저 가공장치 (Laser scriber)를 이용하여 a-Si:H/a-SiGe:H 이중접합(tandem)을 갖는 태양전지를 제작하였고, 광 변환효율 특성을 평가하였다. 전도도(conductivity), 라만(Raman)분광 및 UV/Visible 분광 분석을 통하여 박막의 전기적, 구조적, 광학적 물성을 평가하여 단위박막의 물성을 최적화 했다. 또한 제작된 태양전지는 쏠라 시뮬레이터 (Solar Simulator)를 이용하여 성능 평가를 수행하였고, 상/하부층의 전류 정합 (current matching)을 위해 외부양자효율 (external quantum efficiency) 분석을 수행하였다. 제작된 이중접합 접이식 태양전지로 소면적($0.25cm^2$)에서 8.7%, 대면적($360cm^2$ 이상) 8.0% 이상의 효율을 확보하였으며, 성능 개선을 위해 대면적 패턴 기술 향상 및 공정 기술 개선을 수행 중이다.

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Self-Diagnosis of Damage in Carbon Fiber Reinforced Composites Using Electrical Residual Resistance Measurement (잉여 전기 저항 측정을 이용한 탄소 섬유 강화 복합재의 파손 측정)

  • Kang, Ji-Ho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.29 no.4
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    • pp.323-330
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    • 2009
  • The objective of this research was to develop a practical integrated approach using extracted features from electrical resistance measurements and coupled electromechanical models of damage, for in-situ damage detection and sensing in carbon fiber reinforced plastic(CFRP) composites. To achieve this objective, we introduced specific known damage (in terms of type, size, and location) into CFRP laminates and established quantitative relationships with the electrical resistance measurements. For processing of numerous measurement data, an autonomous data acquisition system was devised. We also established a specimen preparation procedure and a method for electrode setup. Coupon and panel CFRP laminate specimens with several known damage were tested. Coupon specimens with various sizes of artificial delaminations obtained by inserting Teflon film were manufactured and the resistance was measured. The measurement results showed that increase of delamination size led to increase of resistance implying that it is possible to sense the existence and size of delamination. A quasi-isotropic panel was manufactured and electrical resistance was measured. Then three different sizes of holes were drilled at a chosen location. The panel was prepared using the established procedures with six electrode connections on each side making a total of twenty-four electrodes. Vertical, horizontal, and diagonal pairs of electrodes were chosen and the resistance was measured. The measurement results showed the possibility of the established measurement system for an in-situ damage detection method for CFRP composite structures.

Bore-induced Dynamic Responses of Revetment and Soil Foundation (단파작용에 따른 호안과 지반의 동적응답 해석)

  • Lee, Kwang-Ho;Yuk, Seung-Min;Kim, Do-Sam;Kim, Tae-Hyeong;Lee, Yoon-Doo
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.27 no.1
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    • pp.63-77
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    • 2015
  • Tsunami take away life, wash houses away and bring devastation to social infrastructures such as breakwaters, bridges and ports. The coastal structure targeted object in this study can be damaged mainly by the wave pressure together with foundation ground failure due to scouring and liquefaction. The increase of excess pore water pressure composed of oscillatory and residual components may reduce effective stress and, consequently, the seabed may liquefy. If liquefaction occurs in the seabed, the structure may sink, overturn, and eventually increase the failure potential. In this study, the bore was generated using the water level difference, its propagation and interaction with a vertical revetment analyzed by applying 2D-NIT(Two-Dimensional Numerical Irregular wave Tank) model, and the dynamic wave pressure acting on the seabed and the surface boundary of the vertical revetment estimated by this model. Simulation results were used as input data in a finite element computer program(FLIP) for elasto-plastic seabed response. The time and spatial variations in excess pore water pressure ratio, effective stress path, seabed deformation, structure displacement and liquefaction potential in the seabed were estimated. From the results of the analysis, the stability of the vertical revetment was evaluated.

Comparison of the Solar Collection Efficiencies of Various Vinyl House (비닐하우스를 활용한 구조별 태양열 집열효율 비교연구)

  • Park, Know-Hyun;Shin, Hyu-Nyun;Lee, Dong-Sun;Shin, Dong-Hwa;Suh, Kee-Bong
    • Korean Journal of Food Science and Technology
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    • v.14 no.2
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    • pp.156-161
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    • 1982
  • Three plastic film solar dryers covered with different film layer were constructed by modifying farm vinyl house and studied their performance. The collection efficiency and temperature raising of type C which was covered with double layers of transparent PE and black PVC film was most efficient, followed after B covered with double layer of transparent PE film and type A covered with single layer transparent PE film. The inside temperature of type C was average $18^{\circ}C$ higher than ambient temperature and its collection efficiency showed 31.5% with air flow rate of $3.8m^3/min$. The solar energy collection efficiency of type C was increased in proportion to air flow rate up to 60.2% at $11.3m^3/min$. In demonstration drying test of red pepper in type C, drying capacity per unit area was 2.5 times higher than that of conventional solar drying on straw mat and drying time shortened to about half.

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Strategy and Development of Recycling Technology for End-of-Life Vehicles(ELVs) in Germany

  • Kim, Jae-Ceung
    • Resources Recycling
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    • v.14 no.3
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    • pp.16-36
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    • 2005
  • The quantity of passenger cars in industrial countries has been significantly increased in recent years. According to prognoses, this tendency is likely to continue in the forthcoming future. As a direct consequence, an increase of End-of Life-Vehicles (ELV) will confront us with the problem of "ELV-Recycling". In order to cope with this situation, the European regulation for the treatment of End-of-Life-Vehicles (09/2000) has been transferred to national law in Germany (ELV-Regulation from 1 July 2002). The long term aim is to reduce residues from the ELV-treatment to less than 5 wt% from 30 wt% within the next 10 years (2015). For that reason, there is a need for innovative and more efficient recycling techniques tailored to future materials in automobiles. The design process at automotive industry is continuously changing due to the strong demand on optional equipment and new technical solutions for fuel saving. Light materials, such as aluminum and plastics, consequently become more important and cause a decrease of ferrous metals. Since plastic materials are often used as compounds, a separation into initial material types by means of mechanical recycling methods is not possible. For that reason, efficient recycling can only be realized by introducing recycling-friendly car designs. In the end an integrated approach of auto makers and recycling industry is of decisive significance for the fulfillment of future regulations.

Cyclic Local Buckling Behavior of Steel Members with Web Opening (유공 강구조 부재의 반복 국부좌굴거동)

  • Lee, EunTaik;Ko, KaYeon;Kang, JaeHoon;Chang, KyoungHo
    • Journal of Korean Society of Steel Construction
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    • v.15 no.4 s.65
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    • pp.423-433
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    • 2003
  • Many study have been performed to describe the elastic and inelastic behavior of H-shaped beams with web openings that generally concentrated on the monotonic loading condition and concentric web opening. The findings of the studies led Darwin to propose formulas for the design of beams with web openings considering local buckling. While the formulas are simple and useful in real situation, more studies arc needed on their cyclic loading condition. In this experimental study, 12 H-shaped beams with web openings under cyclic loading condition were investigated. The dimension criteria based on the formulas proposed by Darwin were examined. The suitability of existing design formulas and the effects of plastic hinges on beams with web openings and of local buckling around web openings on the beam strength under cyclic loading were also studied. This was done by observing their behavior with various dimensional openings, eccentric per cent, and stiffeners.

Seismic Evaluation of Exposed Column-base Plate Weak-axis Connections Using L-shaped Hooked Anchor Bolts (L형 갈고리 앵커볼트를 사용한 약축방향 노출형 주각부의 내진성능 평가)

  • Lim, Woo-Young;You, Young-Chan
    • Journal of Korean Society of Steel Construction
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    • v.29 no.4
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    • pp.269-280
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    • 2017
  • In this study, seismic performance was evaluated for the exposed column-base plate weak-axis connections of small size steel structures through cyclic loading tests. The primary test parameters are the thickness of base plate, the presence of rib plates, the number of anchor bolts and embedment length of anchor bolts. To investigate the effect of bond performance of anchor bolts on the seismic performance of column-base plate connections, L-shaped round bars and thread bars were used as the hooked anchor bolts in the test specimens. Test results showed that bond performance of anchor bolts and the thickness of base plate significantly affect the structural performance and energy dissipation capacity. In particular, it was found that even if the requirements for minimum thickness of the base plate that is satisfied, the base plate can yield before the capacity of steel column reaches the plastic moment resulting in decreasing the structural performance of the connections. However, the proposed details of the connections might be considered as the partially restrained, that is semi-rigid connections. Consequently, the L-shaped thread anchor bolts is applicable in the exposed column-base plate weak-axis connections of small-size steel structures.

Cyclic Seismic Testing of Concrete-filled U-shaped Steel Beam-to-Steel Column Connections (콘크리트채움 U형 강재보-강재기둥 합성 내진접합부에 대한 주기하중 실험)

  • Park, Hong-Gun;Lee, Cheol-Ho;Park, Chang-Hee;Hwang, Hyeon-Jong;Lee, Chang-Nam;Kim, Hyoung-Seop;Kim, Sung-Bae
    • Journal of Korean Society of Steel Construction
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    • v.23 no.3
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    • pp.337-347
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    • 2011
  • In this study, seismic resistance of concrete encased U-shaped steel beam-to-steel H-shaped column connections was evaluated. Three specimens of the beam-to-column connection were tested under cyclic loading. The composite beam was integrated with concrete slab using studs. Re-bars for negative moment were placed in the slab. The primary test parameter was the details of the connections, which are strengthening and weakening strategies for the beam end and the degree of composite action. The depth of the composite beams was 600mm including the slab thickness. The steel beam and the re-bars in the slab were weld-connected to the steel column. For the strengthening strategy, cover plates were weld-connected to the bottom and top flanges of the steel beam. For the weakening strategy, a void using styrofoam box was located inside the core concrete at the potential plastic hinge zone. The test results showed that the fully composite specimens exhibited good strength, deformation, and energy dissipation capacities. The deformation capacity of the beam exceeded 4% rotation angle, which is the requirement for the Special Moment Frame.