• Title/Summary/Keyword: plasmon resonance

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Fabrication of ZnO Nanorod based Robust Nanogenerator Metal Substrate (금속 기판적용을 통한 ZnO 나노로드기반 나노제너레이터 제조)

  • Baek, Seong-Ho;Park, Il-Kyu
    • Journal of Powder Materials
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    • v.22 no.5
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    • pp.331-336
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    • 2015
  • We report on the succesful fabrication of ZnO nanorod (NR)-based robust piezoelectric nanogenerators (PNGs) by using Cu foil substrate. The ZnO NRs are successfully grown on the Cu foil substrate by using all solution based method, a two step hydrothermal synthesis. The ZnO NRs are grown along c-axis well with an average diameter of 75~80 nm and length of $1{\sim}1.5{\mu}m$. The ZnO NRs showed abnormal photoluminescence specrta which is attributed from surface plasmon resonance assistant enhancement at specific wavelength. The PNGs on the SUS substrates show typical piezoelectric output performance which showing a frequency dependent voltage enhancement and polarity dependent charging and discharging characteristics. The output voltage range is 0.79~2.28 V with variation of input strain frequency of 1.8~3.9 Hz. The PNG on Cu foil shows reliable output performance even at the operation over 200 times without showing degradation of output voltage. The current output from the PNG is $0.7{\mu}A/cm^2$ which is a typical out-put range from the ZnO NR-based PNGs. These performance enhancement is attributed from the high flexibility, high electrical conductivity and excellent heat dissipation properties of the Cu foil as a substrate.

Optimization Method for Plasmonic Color Filters of High Optical Efficiency

  • Lee, Seonuk;Park, Junsu;Ju, Byeong-Kwon
    • International Journal of Internet, Broadcasting and Communication
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    • v.7 no.2
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    • pp.9-15
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    • 2015
  • Various studies with regard to increasing the optical efficiency of plasmonic color filters have previously been conducted, such as mixing materials or applying diverse pattern shapes. Fundamentally, it is important to maximize the photonic crystal effect by finding the optimum periods of lattice as well as calculating the most efficient transmission area. In this study, we propose a technical method for optimizing the plasmonic color filters that have a high color gamut and luminance by analyzing the light spectrums based on the 1931 color coordinate system. Moreover, we suggest a calculation method in order to define the individual color purity of red and green and blue filters. Consequently, efficiency values are obtained independently from each color filter by evaluating the color purity and the luminance. The final result obtained from simulation are 27.6% of relative luminance and 25.3% of color gamut. The proposed optimization method is applicable to all plasmonic color filters having photonic crystal arrays.

Theoretical Study on the Effects of Particle Size Distribution on the Optical Properties of Colloidal Gold (입자 크기 분포가 금 콜로이드의 광학성질에 미치는 영향에 대한 이론 연구)

  • Kim, Hyo-Jeong;Saha Leton Chandra;Jang, Joon-Kyung
    • Journal of the Korean Chemical Society
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    • v.51 no.5
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    • pp.407-411
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    • 2007
  • Mie theory has been used to calculate the extinction of a gold nanoparticle in water by varying its diameter from 1 to 1000 nm. Utilizing this size-dependent theoretical spectrum, we have calculated the extinction spectrum of a colloidal gold by taking into account the size distribution of particle. Such calculation is in better agreement with experiment than the calculation without considering the size distribution. A least-squares fitting is used to deduce the size distribution from an experimental extinction spectrum. For particles with their diameters ranging from 10 to 28 nanometers, the fitting gives reasonable agreement with the size distribution obtained from tunneling electron microscope images.

Electrical, optical, structural properties of GZO-Ag-GZO multilayer electrode (GZO-Ag-GZO 다층 투명 전극의 전기적, 광학적, 구조적 특성 연구)

  • Kim, Han-Ki;Park, Ho-Kyun;Choi, Kwang-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.443-443
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    • 2008
  • 본 연구에서는 Ga-doped ZnO(GZO)-Ag-GZO 다층 투명전극을 Dual DC magnetron sputtering system을 이용 하여 유리기판 위에 상온에서 제작하여 Ag 두께에 따른 전기적, 광학적, 구조적 특성변화를 조사하였다. Hall effect measurement와 UV/Vis spectrometer로 전기적, 광학적 특성을 분석하였으며, X-ray diffraction(XRD)와FE-SEM분석을 통해 결정성과 표면 특성을 조사하였다. FE-SEM 분석결과 island 형태에서 continuous layer로 박막의 형상이 바뀌면서 다층 투명전극의 전기적, 광학적 특성에 영향을 미치는 것을 알 수 있었다. 본 실험에서 Ag 두께 12 nm에서 가장 최적화되어 유리기판위에 상온에서 증착되었음에도 불구하고 $5.5{\times}{\times}10^{-5}\Omega$-cm, $6\Omega$/sq. 의 매우 낮은 면저항과 비저항을 각각 나타내었고 550 nm 파장에서 87 % 의 높은 광 투과도를 나타내었다. 또한 두께 12 nm의 Ag가 삽입된 다층 투명전극을 polyethylene terephthalate (PET) 기판위에 성막하여 Bending test를 실시하여 0.1% 이하의 매우 낮은 저항변화를 확인함으로써 플렉시블 기반의 디스플레이나 태양전지의 투명 전극으로서의 응용 가능성을 확인하였고 마지막으로 최적화된 다층 투명전극을 유기물태양전지의 애노드에 적용하여 기존 ITO 애노드를 대체할 수 있는 투명전극으로서의 가능성을 제시하였다.

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Characteristic Analysis of Nano-hole Array Optical Filter having Psychological Protection for Color Recognition (색 인지에 대한 심리보호효과를 가지는 나노홀어레이 광학필터 특성 분석)

  • Kang, Tae Young;Ahn, Heesang;Shin, Dong-Myeong;Hong, Suck Won;Kim, Kyujung;Lee, Donghoon
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.15 no.6
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    • pp.95-100
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    • 2016
  • We suggest and simulate an optical filter that a red wavelength range cannot transmit to protect the psychological stress that originates from the cognition of red color in emergency medical technicians. When a nanohole hexagonal array is fabricated on gold film using Anodic Aluminum Oxide (AAO), the blocked wavelength can be tuned by the hole diameter and film thickness. The characteristic of the transmittance for normal incident white light is simulated with Finite Element Method (FEM) in the MATLAB platform. Although the transmittance of the overall wavelength is reduced by 50% by the gold film, the transmittance of the red wavelength range is decreased by over 87%.

Investigation of Gold and Silver Nanoparticles as Acid-base pH Indicators and Their Transition pH Ranges

  • Jung, Byoung Gue;Jo, Jihee;Yu, Jin Won;Lim, Jong Kuk
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3595-3600
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    • 2014
  • Monitoring of pH, especially under highly alkaline conditions, is necessary in various processes in the industrial, biotechnological, agricultural, and environmental fields. However, few pH indicators that can function at highly alkaline levels are available, and most of which are organic-based pH indicators. Several years ago, it was reported that gold nanoparticles prepared using trisodium citrate dihydrate were rapidly aggregated at pH values higher than ~12.7. A shift of surface plasmon resonance for such aggregated gold nanoparticles can be applied to pH indicators, allowing for the substitution of traditional organic-based pH indicators. The most important characteristic of pH indicators is the transition pH range. Herein, gold and silver nanoparticles are prepared using different reducing agents, and their transition pH ranges are examined. The results showed that all nanoparticles prepared in this study exhibit similar transition pH ranges spanning 11.9-13.0, regardless of the nanoparticle material, reducing agents, and concentration.

Characteristics of Gold and Silver Based Bi- and Tri-metallic SPR Chip in the Intensity Measurement Mode (반사광 측정 모드에서 금과 은을 사용한 이층 금속 칩과 삼층 금속 칩의 특성 연구)

  • Kim, Hyungjin;Kim, Chang-duk;Sohn, Young-Soo
    • Journal of Sensor Science and Technology
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    • v.25 no.2
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    • pp.143-147
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    • 2016
  • Characteristics of the conventional gold (Au) surface plasmon resonance (SPR) chip, bi-metallic(Au/silver (Ag)) SPR chip, and tri-metallic(Au/Ag/Au) SPR chip were investigated and compared in the intensity measurement mode for the enhancement of SPR image sensor reactivity. Reflectance curves of the Au, bi- and tri-metallic SPR chips were acquired in phosphate-buffered saline (PBS) solution and were compared. The line width of the reflectance curve of the bi-metallic chip was the narrowest among the three different types of the chips. Also, the tangential slope of the bi-metallic chip was steeper than those of the other chips. Various concentrations of bovine serum albumin (BSA) were utilized in the SPR experiment. As a result, among the above three chips reflectance variation value of the bi-metallic chip was the largest.

Doxorubicin Binds to Un-phosphorylated Form of hNopp140 and Reduces Protein Kinase CK2-Dependent Phosphorylation of hNopp140

  • Kim, Yun-Kyoung;Lee, Won-Kyu;Jin, Young-nam;Lee, Kong-Joo;Jeon, Hye-sung;Yu, Yeon-Gyu
    • BMB Reports
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    • v.39 no.6
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    • pp.774-781
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    • 2006
  • Human nucleolar phosphoprotein p140 (hNopp140) is a nucleolar phosphoprotein that can bind to doxorubicin, an anti-cancer agent. We have examined the interaction between hNopp140 and doxorubicin as well as the folding property of hNopp140. Also, the effects of ATP and phosphorylation on the affinity of hNopp140 to doxorubicin are investigated by affinity dependent co-precipitation and surface plasmon resonance methods. Doxorubicin preferentially binds to un-phosphorylated form of hNopp140 with a $K_D$ value of $3.3\;{\times}\;10^{-7}$ M. Furthermore, doxorubicin reduces the protein kinase CK2-dependent phosphorylation of hNopp140, indicating that doxorubicin may perturb the cellular function of hNopp140 by reducing the protein kinase CK2-dependent phosphorylation of hNopp140. Low contents of the secondary structures of hNopp140 and the fast rate of proteolysis imply that hNopp140 has a high percentage of flexible regions or extended loop structures.

Review on Biosensors for Food Safety

  • Kim, Giyoung;Moon, Ji-Hea;Lim, Jongguk;Mo, Changyeun
    • Journal of Biosystems Engineering
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    • v.39 no.2
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    • pp.115-121
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    • 2014
  • Background: Frequent outbreaks of foodborne illness have been increased awareness of food safety. CDC estimates that each year roughly 48 million people gets sick, 128,000 are hospitalized and 3,000 die of foodborne diseases in US. In Korea, 6,058 were hospitalized and 266 incidents were reported in 2012. It is required to develop rapid methods to identify hazard substances in food products for protecting and maintaining safety of the public health. However, conventional methods for pathogens detection and identification involve prolonged multiple enrichment steps. Purpose: This review aims to provide information on biosensors to detect pathogens in food products to enhance food safety. Results: Foodborne outbreaks continue to occur and outbreaks from various food sources have increased the need for simple, rapid, and sensitive methods to detect foodborne pathogens. Conventional methods for foodborne pathogens detection require tremendous amount of labor and time. Biosensors have drawn attentions in recent years because of their ability to detect analytes sensitively and rapidly. Principles along with their advantages and disadvantages of a variety of food safety biosensors including fiber optic biosensor, impedimetric biosensor, surface Plasmon resonance biosensor, and nano biosensor were explained. Also, future trends for the food safety biosensors were discussed.

An Electrochemical Approach for Fabricating Organic Thin Film Photoelectrodes Consisting of Gold Nanoparticles and Polythiophene

  • Takahashi, Yukina;Umino, Hidehisa;Taura, Sakiko;Yamada, Sunao
    • Rapid Communication in Photoscience
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    • v.2 no.3
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    • pp.79-81
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    • 2013
  • A novel method of fabricating polythiophene-gold nanoparticle composite film electrodes for photoelectric conversion is demonstrated. The method includes electrodeposition of gold and electropolymerization of 2,2'-bithiophene onto an indium-tin-oxide (ITO) electrode. First, electrodeposition of gold onto the ITO electrode was carried out with various repetition times of pulsed applied potential (0.25 s at -2.0 V vs. Ag/AgCl) in an aqueous solution of $HAuCl_4$. Significant progress of the number density of deposited gold nanoparticles was confirmed from scanning electron micrographs, from 4 (1 time) to 25% (15 times). Next, electropolymerization of 2,2'-bithiophene onto the above ITO electrode was performed under controlled charge condition (+1.4 V vs. Ag wire, 15 $mC/cm^2$). Structural characterization of as-fabricated films were carried out by spectroscopic and electron micrographic methods. Photocurrent responses from the sample film electrodes were investigated in the presence of electron acceptors (methyl viologen and oxygen). Photocurrent intensities increased with increasing the density of deposited gold nanoparticles up to ~10%, and tended to decrease above it. It suggests that the surplus gold nanoparticles exhibit quenching effects rather than enhancement effects based on localized electric fields induced by surface plasmon resonance of the deposited gold nanoparticles.