• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.205.1-205.1
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• 2016

핵융합로에서 고온, 고에너지 플라즈마에 장기간 노출되는 플라즈마 대면재는 고속 입자와 중성자에 의한 열화 및 침식과 높은 열부하를 견뎌야 하므로 높은 수준의 재료기술과 표면 코팅기술의 개발이 필요하다. 텅스텐은 용융점이 높고, 스퍼터링(Sputtering) 현상이 적으며, Tritium 재침적 현상이 제한되는 우수한 특성 때문에 핵융합로 대면제에 적용하기 위한 다양한 연구가 진행되고 있다. 본 연구에서는 VPS(vacuum plasma spray) 장비를 이용하여 5, 10, $25{\mu}m$ 크기의 텅스텐 분말을FM(ferritic-martenitic) steel 기판에 용사 코팅하였다. 입자 크기를 달리하여 제작한 3종의 시편은 시편 전후 두께 및 무게 변화, 현미경이미지, 비커스 경도, 3D 표면 형상, XRD를 이용하여 코팅층의 특성을 평가하였으며, $10{\mu}m$ 크기의 텅스텐 분말 시편이 가장 우수한 특성을 나타내는 것을 확인하였다.

• Journal of the Korean institute of surface engineering
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• v.29 no.6
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• pp.745-752
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• 1996

Wear property of plasma spray coating in $Cr_2O_3$ powder manufatured of spray dry method on the aluminum substrate was inspected for the application of piston-ring of automotive enginel. The plama spray coatings were varied with feed rate and particle size. Used the ball-on disc type tribometer, wear volume, friction, surface rougness were investigated. The delamination of the coating layer were observed with SEM. Also the cross-section of wear track were investigated, using optical microscopy. As a result of experiment, wear mechanism was addressed in the various coating process.

• Journal of the Korean institute of surface engineering
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• v.27 no.3
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• pp.134-142
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• 1994

$Al_2O_3$coatings on mild steel substrate by plasma spray process were produced to evaluate microstructural characterization and mechanical properties. As-coated $Al_2O_3$coating samplessd were subjected to two heat treat-ment conditions : ⅰ) annealing under vacuum circumstance, ⅱ) hot press treated condition. The two heat treat-ed coatings were investigated in terms of microhardness, adhesion strength, wear resistance, porosity forma-tion, and microstructures. In the case of the coatings which were subject to preparation step ⅰ, the porosity in the coating was decreased with the increase of temperature ($700^{\circ}C$-$1100^{\circ}C$), and the wear resistance, microhardnesss and adhesion strength were increased with the increase of temperature. On the other hand, in the case of the coatings which were subject to preparation step ⅱ, wear resistance and adhesion strength were improved with the increase of temperature and pressure. Experimental measurements of coatings which were produced by both preparation conditions were enhanced compare to those of as-coated coatings.

• Structural Engineering and Mechanics
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• v.4 no.6
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• pp.679-702
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• 1996

The finite element method is employed in conjunction with micromechanical modelling in order to assess the performance of ceramic thermal barrier coatings applied to structural components. The study comprises the conditions of the deposition of the coating by plasma spraying as well as the thermal cycling of the coated component, and it addresses particularly turbine blades. They are exposed to high temperature changes strongly influencing the behaviour of the core material and inducing damage in the ceramic material by intense straining. A concept of failure analysis is discussed starting from distributed microcracking in the ceramic material, progressing to the formation of macroscopic crack patterns and examining their potential for propagation across the coating. The theory is in good agreement with experimental observations, and may therefore be utilized in proposing improvements for a delayed initiation of failure, thus increasing the lifetime of components with ceramic thermal barrier coatings.

• Journal of the Korean institute of surface engineering
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• v.27 no.1
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• pp.12-18
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• 1994

The plasma spray process was used to deposit coatings of $ZrO_2$-8wt%Y2O3 powders on mild steel sub-strate, and the characteristics of as-deposited and heat treated coatings have been investigated. Particulary, the variations of porosity, wear resistance, thermal barrier and thermal shock resistance in $ZrO_2$-8wt% $Y_2O_3$coatings after heat treatment under vacuum circumstance have been investigated. The porosity of the coating layer was increased with increased spray distance. In the case of the arc current of 450A and at the spray distance of 50mm, it was obtained the lowest amount of porosity. After heat treatment, the amount of porosity was found to be decreased, and the wear resistance, microhardness and thermal shock resistance were im-proved. However, the thermal barrier was decreased.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.298-303
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• 2000

The 3 mol% yttria stabilized zirconia (3-Y PSZ) powder was heat treated at 50 0$^{\circ}C$ to evaporate the polymer binder and stabilize the tetragonal phase. The wear experiments were carried out on a ring-on-plate type reciprocating wear tester at selected temperatures with in the range room temperature to 600$^{\circ}C$ The results show that the heat treatment of powder decreases the wear rate due to the reduction of microcracks and pores in coatings and the stabilization of the tetragonal phase. Powder heat treatment enhanced the quality of the coating layer by removing remnant gases during coating process and the powder heat treatment at which tetragonal phase is stable diminished phase ratio of monoclinic. These two effects improved wear resistance characters.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2001.06a
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• pp.42-48
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• 2001

Chromium carbides have the excellent wear properties as transition metal carbides. Their tribological applications were studied recently. The nano-sized ceramic could enhance the mechanical and electronical properties of materials. In this study, it was observed to test the wear of the coated surface of nano-sized chromium carbides. The nano-sized chromium carbides were produced by sol-gel processing. Coating surface of produced powders was obtained front plasma spraying. Wear test of coating surface was held increasing temperature. The friction coefficient and the wear loss were testified in dry environment. And the worn surfaces were analyzed by XRD and SEM.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.6
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• pp.359-364
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• 2019

The suspension plasma spraying is a modification of conventional plasma spray techniques that has been developed to overcome the challenge of using fine particles in plasma spray processes. In this study, microstructure developments and mechanical property of yttrium oxide (Y₂O₃) coatings prepared by the suspension plasma spray coating technique have been investigated to determine the effect of processing parameters including plasma gun current and total gas flow. The results showed that a highly dense Y₂O₃ coating having low porosity of 0.2 vol% without any lamellar structures can be achieved at the optimum condition of gun current 200 A and total gas flow 220 L/min.

• Journal of the Korean institute of surface engineering
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• v.34 no.5
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• pp.486-493
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• 2001

Partially stabilized zirconia (PSZ) is an attractive material for thermal barrier coating. Zirconia exists in three crystallographic phases: cubic, tetragonal and monoclinic. Especially, the phase transformation of tetragonal phase to monoclinic phase accompanies significant volume expansion, so this transition generally results in cracking and contributes to the failure of the TBC system. Both the plasma sprayed ZrO$_2$-8Y$_2$O$_3$ (YSZ) coat and the ZrO$_2$,-25CeO$_2$,-2.5Y$_2$O$_3$ (CYSZ) coat are isothermally heat -treated at 130$0^{\circ}C$ and 150$0^{\circ}C$ for 100hr and cooled at different cooling rates. The monoclinic phase is not discovered in all the CYSZ annealed at 130$0^{\circ}C$ and 150$0^{\circ}C$. In the 150$0^{\circ}C$ heat-treated specimens, the YSZ contains some monoclinic phase while none exists in the 130$0^{\circ}C$ heat-treated YSZ coat. For the YSZ, the different phase transformation behaviors at the two temperatures are due to the stabilizer concentration of high temperature phases and grain growth. For the YSZ with 150$0^{\circ}C$-100hr annealing, the amount of monoclinic phase increased with the slower cooling rate. The extra oxygen vacancy, thermal stress, and c to t'phase transformation might suppress the t to m martensitic phase transformation.

• Maxillofacial Plastic and Reconstructive Surgery
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• v.23 no.5
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• pp.396-405
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• 2001

Osseointegrated implants are used for the fixation of dental prosthesis with good long-term clinical results. In an attempt to improve the quantity and quality of the bone-implant interface, numerous implant modification have been used. Implants surface modifications have been used such as titanium-plasma sprayed, hydroxyapatite-coating, sandblasted, sandblasted and acid-etched, acid-etched. Rough surface implants have greater implant surface area and enhance the bone-implant interface and improve stabilization. The purpose of present study was to evaluate light microscopic and scanning microscopic examinations and removal torque value of newly developed calcium phosphate blast and acid-etched implant in the femur of rabbits. Titanium plasma sprayed(TPS) implant served as controls. After 12 weeks of healing of the femurs of 12 rabitts, the implant-containing segments of femur were removed on bloc and bone block including sections. Histologic examination and histomorphometric and removal torque values comparision were made for two implants. Obtained results are follows: 1. Newly developed calcium phosphate blasted and acid-etched implants were in close contact with bone under light microscopic examinations. 2. New implants showed mean bone-to implant contact 59.8%, whereas TPS implants showed mean bone-to implant contact 54.5% (statistically no difference p<0.05). 3. New implants showed mean bone density 56.7%, whereas TPS implants showed mean bone density 49.2% (statistically difference p<0.05). 4. New implants demonstrated mean removal torque values 40.5Ncm, whereas the mean removal torque values of TPS implants ranged 39.3Ncm. No statistical differences(p<0.05) were observed between two groups of implants nor was there any difference between the two implants at the clinical level.