• Title/Summary/Keyword: plasma activated

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Poly-$\alpha$-methylstyrene Films by Plasma Polymerization(I) (플라즈마 중합된 Poly-$\alpha$-methylstyrene 박막(I))

  • Park, Sang-Hyun;Lee, Chwi-Cwung;Han, Sang-Ok;Lim, Youg-Hoon;Lee, Deok-Chool
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.304-306
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    • 1991
  • A new gas-flow type reactor for plasma polymerization was developed to symthesize functional polymer, which enhances the reaction of radicals activated in discharge. $\alpha$-Methylstyrene was used for the polymerization, which are known as starting monomers for the polymer with degradating characteristics. The molecular structure and molecular weight distribution of the polymers were studied.

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Study on characterization of hydrogenated carbon nitride thin films prebared by Plasma-Assisted Chemical Vapor Deposition (RF-PACVD를 이용한 Hydrogenated Carbon Nitride박막의 합성 및 특성에 관한 연구)

  • Lee, Chul-Hwa;Kim, Byoung-Soo;Park, Gu-Bum;Lee, Sang-Hee;Jin, Yoon-Young;Lee, Duck-Chool
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.856-857
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    • 1998
  • Hydrogenated amorphous carbon nitride [a-C:H(N)] films were deposited on pretreated silicon(100) substrate in activated gas phase using. RF plasma-assisted CVD. We measured the FT-IR spectrum to investigate $C{\equiv}N$ stretching mode(nitrile), C-H stretching mode, C-H bending mode, C=C stretching mode C=N(imino) mode, and the EDX to investigate the ratio of N to C(0.25). By the results of FT-IR and EDX spectrum, We confirmed that hydrogenated amorphous carbon nitride films successfully were synthesized by RF-PACVD

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A case of intracranial hemorrhage in a neonate with congenital factor VII deficiency

  • Lee, Won-Seok;Park, Young-Sil
    • Clinical and Experimental Pediatrics
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    • v.53 no.10
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    • pp.913-916
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    • 2010
  • Congenital factor VII deficiency is a rare autosomal-recessive bleeding disorder. Bleeding manifestations and clinical findings vary widely, ranging from asymptomatic subjects to patients with hemorrhages that may cause significant handicaps. Treatment has traditionally involved factor VII(FVII) replacement therapy using fresh frozen plasma, prothrombin complex concentrates or plasma-derived FVII concentrates. Recombinant activated FVII ($NovoSeven^{(R)}$) is currently considered the first-line treatment for replacement therapy of FVII deficiency. Here we present a case of severe intracerebral and intraventricular hemorrhage in a neonate with congenital FVII deficiency.

Phospholipases Dl and D2 Regulate Different Phases of Exocytosis in Mast Cells

  • Lee, Jun-Ho;Chang, Sung-Ho;Kim, Young-Mi;Her, Her Erk;Choi, Wahn-Soo
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.135.1-135.1
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    • 2003
  • The rat mast cell line RBL-2H3 contains both phospholipase D (PLD)1 and PLD2. Previous studies with this cell line indicated that expressed PLD1 and PLD2 are both strongly activated by stimulants of secretion. We now show by use of PLDs tagged with enhanced green fluorescent protein that PLD1, which is largely associated with secretory granules, redistributes to the plasma membrane in stimulated cells by processes reminiscent of exocytosis and fusion of granules with the plasma membrane. (omitted)

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Phosphorylation, 14-3-3 protein and photoreceptor in blue light response of stomatal guard cells

  • Toshinori Kinoshita;Takashi Emi;Michio Doi;Shimazaki, Ken-ichiro
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.335-337
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    • 2002
  • Blue light (BL) induces stomatal opening through activation of H$^{+}$ pump, which creates electrical gradient across the plasma membrane for $K^{+}$ uptake into guard cells. The pump is the plasma membrane H$^{+}$ -ATPase and is activated via phosphorylation of the C-terminus with concomitant binding of the 14-3-3 protein. The opening is initiated by the perception of BL through phototropin (phot), which are recently identified as BL receptors in stomatal guard cells. In this study, we provide the biochemical evidence for phots as BL receptors in stomatal guard cells. vfphot was phosphorylated reversibly by BL, and phosphorylation levels of vfphot increased earlier than those of the plasma membrane W-ATPase. BL-dependent phosphorylations of vfphot and H$^{+}$-ATPase showed similar fluence dependency. Staurosporin, an inhibitor of serine/threonine protein kinase, and diphenyleneiodonium chloride (DPI), an inhibitor of flavoprotein, inhibited BL-dependent phosphorylations of vfphot and H$^{+}$ -ATPase. These results indicate that vfphot acts as a BL-receptor mediating stomatal opening.l opening.

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Effect of Hydrocarbons on the Promotion of NO-$NO_2$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.33-46
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of NO-$NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $NO_2$ etc.) successively produced by hydrocarbon decomposition form the primary path of NO-$NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient NO-$NO_2$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Effect of Hydrocarbons on the Promotion of $NO-NO_{2}$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.178-188
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_{2}$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_{2}$ etc.) successively produced by hydrocarbon decomposition form the primary path of $NO-NO_{2}$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_{2}$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Measurement of Ion Energy Distribution using QMS & Ionization Enhancement by usign Magnetic Field in Triod BARE (자장을 이용한 이온화율 증대형 삼극형 BARE에서 이온화율의 증대경향과 QMS를 이용한 이온의 에너지 분포 측정)

  • 김익현;주정훈;한봉희
    • Journal of the Korean institute of surface engineering
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    • v.24 no.3
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    • pp.119-124
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    • 1991
  • Recently, the trend of research in hard coating is concentrate on developing the process of ionization rate under low operating pressure, to get the thin film with high adhesion and dense microstructures. In this study ionization rate enhancement type PVD process using permanent magnet is developed, which enhances the ionization rate by confining the plasma suppressing the wall loss of electron. By the result to investigate the characteristic of glow discharge, the ionization rate of this process is enhanced about twice as high as that of triod BARE process (about 26%), and more dense TiN microstructures are obtained in this process. Cylindrical ion energy analyzer is made and attached in front of a quadrupole mass filter for the analysis of the energy distribution of reactive gas and activated gas ions from the plasma zone. To analyze the operation mechanism of ion energy analyzer, computer simulation is performed by calculation the electric field environment using finite element method. By these analyses of ion energy distribution of outcoming ions from the plasma zone, it is found that magnetic field enhances ion kinetic energy as well as ionization rate. The other results of this study is that the foundation of feed-back system is constructed, which automatically control the partial pressure of reactive gas. In can be possible by recording the data of mass spectrum and ion energy analysis using A-D converter.

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Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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Adhesion of Cu on Polycarbonate with the Condition of Surface Modification and DC-Bias Sputtering Deposition (폴리카보네이트에서의 표면개질 조건과 DC-Bias Sputtering 증착에 따른 Cu 밀착성)

  • 배길상;엄준선;이인선;김상호;고영배;김동원
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.5-12
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    • 2004
  • The enhancement of adhesion for Cu film on polycarbonate (PC) surface with the $Ar/O_2$ gas plasma treatment and dc-bias sputtering was studied. The plasma treatment with this reactive mixture changes the chemical property of PC surface into hydrophllic one, which is shown by the variation of contact angle with surface modification. The micro surface roughness that also gives the high adhesive environment is increased by the $Ar/O_2$ gas plasma treatment. These results were observed distinctly from the atomic force microscopy (AFM). The negative substrate dc-bias effect for the Cu adhesion on PC was also investifated. Accelerated $Ar^{+}$ lons in sheath area of anode bombard the bare surface of PC during initial stage of dc bias sputtering. PC substrate. therefore, has severe roughen and hydrophilic surface due to the physical etching process with more activated functional group. As dc-bias sputtering process proceeds, morphology of Cu film shows better step coverage and dense layer. The results of peel test show the evidence of superiority of bias sputtering for the adhesion between metal Cu and PC.C.