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[ $CO_2$ ] Recovery from LNG-fired Flue Gas Using a Multi-staged Pilot-scale Membrane Plant (파일럿규모의 다단계 막분리 공정을 통한 LNG 연소 배가스로부터 이산화탄소의 회수연구)

  • Kim, Jeong-Hoon;Choi, Seung-Hak;Kim, Beom-Sik;Lee, Soo-Bok;Lee, Yong-Taek
    • Membrane Journal
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    • v.17 no.3
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    • pp.197-209
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    • 2007
  • In this study, a multi-staged pilot-scale membrane plant was constructed and operated for the separation of $CO_2$ from LNG-fired boiler flue gas of 1,000 $Nm^3/day$. The target purity and recovery ratio of $CO_2$ required for the pilot plant were 99% and 90%, respectively. For this purpose, we previously developed the asymmetric polyethersulfone hollow fibers and evaluated the effects of operating pressure and feed concentration of $CO_2$ on separation performance[1,2]. The permeation data obtained were also analyzed in relation with the numerical simulation data using counter-current flow model[3,4]. Based on these results, we designed and prepared the demonstration plant consisting of dehumidification process and four-staged membrane process. The operation results using this plant were compared with the numerical simulation results on multi-staged membrane process. The experimental results matched well with the numerical simulation data. The concentration and the recovery ratio of $CO_2$ in the final stage permeate stream were ranged from $95{\sim}99%$ and $70{\sim}95%$, respectively, depending on the operating conditions. This study demonstrated the applicability of the membrane-based pilot plant for $CO_2$ recovery from flue gas.

The Impact of Side Reactions in Sulfur Recovery Unit Design (황 회수 공정 설계에서 부 반응의 영향)

  • Kim, Sung Ho;Jung, Won Seok;Lee, Hee Mun;Chang, Geun Soo
    • Plant Journal
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    • v.13 no.3
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    • pp.36-46
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    • 2017
  • In the reaction furnace of modified Claus process, chemical equilibrium reactions and kinetic reactions occur simultaneously. The main kinetic components are hydrogen ($H_2$), carbon monoxide (CO), carbonyl sulphide (COS) and carbon disulphide ($CS_2$). The equilibrium calculations, empirical correlations and sulfur recovery technology providers' (licensors) data for kinetic components (COS and $CS_2$) in the reaction furnace were analyzed to evaluate the amount of kinetic components by applying them to five different projects in which GS Engineering & Construction participated. Kinetic components ($H_2$ and CO) are also calculated and the results are analyzed to evaluate the impact of temperature in the reaction furnace and the waste heat boiler. Total required $O_2$ deviations for combustion in the reaction furnace are additionally shown, with and without side reactions. A full understanding of side reactions in the modified Claus process can help to improve sulfur recovery efficiency and optimize equipment design.

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A Study on Combustion Characteristics of the Bio-drying SRF in 5 Ton/day Scale Combustion Boiler (5톤/일 규모의 연소보일러에서 Bio-drying 고형연료의 연소특성 연구)

  • Kim, Dong-Ju;Yoon, Young-Sik;Jeong, Bup-Mook;Park, Yeong Su;Seo, Yong-Chil;Lee, Byung-Sun
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.600-605
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    • 2018
  • In this study, the combustion characteristics were investigated based on the biodrying solid recovered fuel (SRF) in a 5 Ton/day scale combustion boiler. The composition of the combustion gas containing the biodrying SRF was analyzed, the particulate matter, and its HCl content was determined with the air pollutant process test method. Mass balance, carbon balance, and combustion efficiency were calculated according to the equivalence ratio (ER) method; the energy recovery efficiency of the combustion boiler was also analyzed. The overall combustion efficiency of the biodrying SRF was 97.3 % and the energy recovery efficiency was 80.2%.

A Heat Exchanging Characteristics of Organic Rankine Cycle for Waste Heat Recovery of Coal Fired Power Plant (화력발전용 복수기 폐열 회수를 위한 유기랭킨사이클 시스템 열교환 특성 해석)

  • Jeong, Jinhee;Im, Seokyeon;Kim, Beomjoo;Yu, Sangseok
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.64-70
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    • 2015
  • Organic Rankine cycle (ORC) is an useful cycle for power generation system with low temperature heat sources ($80{\sim}400^{\circ}C$). Since the boiling point of operating fluid is low, the system is used to recover the low temperature heat source of waste heat energy. In this study, a ORC with R134a is applied to recover the waste energy of condenser of coal fired power plant. A system model is developed via Thermolib$^{(R)}$ under Simulink/MATLAB environment. The model is composed of a refrigerant heat exchanger for heat recovery from coal fired condenser, a drum, turbine, heat exchanger for ORC heat rejection, storage tank, water recirculation pump and water drip pump. System analysis parameters were heat recovery capacity, type of refrigerants, and types of turbines. The simulation model is used to analyze the heat recovery capacity of ORC power system. As a result, increasing the overall heat transfer coefficient to become the largest of turbine power is the most economical.

The Road to RNA Silencing is Paved with Plant-Virus Interactions

  • Palukaitis, Peter
    • The Plant Pathology Journal
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    • v.27 no.3
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    • pp.197-206
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    • 2011
  • RNA silencing has had a large impact on biology in general, as well as on our understanding of plant-pathogen interactions, especially interactions between plants and viruses. While most of what we know about the mechanism of RNA silencing was deduced in the last 12 years, many of the interactions between plants and viruses, as well as virus-virus interactions in plants, which we now know are manifestations of RNA silencing, were the subject of decades of work from numerous laboratories. These laboratories were examining the nature and extent of phenomena such as recovery from infection, the formation of dark green islands resistant to re-infection, synergy between unrelated viruses and cross-protection between related viruses, all first described in the late 1920s. In this review, the relationships between these phenomena and their place in the defense mechanism we call RNA silencing will be described, to show how they are all linked.

Approximate Optimum Thermal Design Analysis of Combined Cycle Power Plant (복합화력 발전플랜트의 근사 최적 열설계 해석)

  • Jeon, Y.J.;Shin, H.T.;Lee, B.R.;Kim, T.S.;Ro, S.T.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.782-787
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    • 2001
  • An optimum thermal design analysis of the combined cycle power plant with triple pressure heat recovery steam generator was performed by the numerical simulation. The optimum design module used in the paper is DNCONF, a function of IMSL Library, which is widly known as a method to search for the local optimum. The objective function to be minimized is the cost of total power plant including the steam turbine power enhancement premium. The result of this paper shows that the cost reduces if the design point of power plant becomes the local optimum, and many calculations at various initial conditions should be carried out to get the value near the global optimum.

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Performance Analysis of the Integrated Gasification Combined Cycle Power Plant with Steam Integration (증기연계 공정을 가지는 석탄가스화 복합발전플랜트의 성능해석)

  • Lee, Chan
    • The KSFM Journal of Fluid Machinery
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    • v.12 no.1
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    • pp.43-50
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    • 2009
  • Waste heat recovery process designs and performance analyses are conducted on the IGCC(Integrated Gasification Combined Cycle) power plants integrated with two different coal gasification and gas cleanup processes by Shell and GE/Texaco. Through the analysis results, the present study provides the steam integration concept between the HRSG and the chemical processes of IGCC power plant, and investigates the effect of steam integration on the power generation of IGCC power plant. The present simulation results show less steam power output and higher overall IGCC efficiency of the Shell-based power plant than the GE/Texaco.

Heat Recovery Characteristics of the Hot Water Supply System with Exhaust Heat Recovery Unit Attached to the Hot Air Heater for Plant Bed Heating in the Greenhouse (온풍난방기의 배기열을 이용한 지중 난방용 온수공급시스템의 열회수특성)

  • 김영중;유영선;장진택;강금춘;이건중;신정웅
    • Journal of Biosystems Engineering
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    • v.25 no.3
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    • pp.221-226
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    • 2000
  • Hot air heater with light oil burner is the most common heater for greenhouse heating in the winter season in Korea. However, since the thermal efficiency of the heater is about 80∼85%, considerable unused heat amount in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The heat recovery system is made for plant bed or soil heating in the greenhouse. The system consisted of a heat exchanger made of copper pipes, ${\Phi}12.7{\times}0.7t$ located in the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tank. The total heat exchanger area is 1.5$m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to the performance test it could recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690\ell$/hr from the waste heat discharged. The exhaust gas temperature left the heat exchanger dropped to $100^{\circ}C$ from $270^{\circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{\circ}C$ from $21^{\circ}C$ at the water flow rate of $690\ell$/hr. By the feasibility test conducted in the greenhouse, the system did not encounter any difficulty in operations. And, the system could recover 220,235kJ of exhaust gas heat in a day, which is equivalent of 34% of the fuel consumption by the water boiler for plant bed heating of 0.2ha in the greenhouse.

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Induced Drought Tolerance by the Insecticide Imidacloprid in Plant (살충제 이미다클로프리드에 의한 식물 가뭄 내성 유도)

  • Han, Song-Hee;Kim, Chul-Hong;Lee, Jang-Hoon;Kim, In-Seon;Kim, Young-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.29 no.2
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    • pp.159-164
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    • 2010
  • Imidacloprid is a systemic insecticide which has been used widely in various crops to control insects. In the present study, we demonstrated that pre-treatment of imidacloprid significantly induced tolerance to drought in plant. Relative water content, chlorophyll levels, and recovery rate upon rehydration after drought stress in tobacco plants pre-treated with imidacloprid were higher levels than the control plants. Induced drought tolerance by imidacloprid treatments in red pepper was also demonstrated by measurement of recovery rate and fresh weight upon drought stress. Taken together, our results suggest that imidacloprid, in addition to exerting direct insecticidal activity, may also protect plants by induced tolerance to drought in plant.

A study on a new method of LQG/LTR for nonminimum phase plant by using zero structure (영점구조를 이용한 비 최소위상 플랜트의 새로운 LQG/LTR 방법연구)

  • 서병설;강진식
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10a
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    • pp.208-212
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    • 1991
  • LQG/LTR method cannot applied to nonminimum phase plant. In this paper, we present a new approximation method which guaratee the approximation error equal to zero and exact loop transfer recovery. Zero structure of plant and approximated plant are considered in approximation procedure. It is shown that the properties of plant and approximated plant at pole and zero frequency response are exactly same. It is shown by example that the suggested method can avoide the NMP plant constraint arised in designing LQG/LTR.

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