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Racemic and enantiomeric effect of tartaric acid on the hydrophilicity of polysulfone membrane

  • Sharma, Nilay;Purkait, Mihir Kumar
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.257-275
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    • 2016
  • The enantiomeric and racemic effects of tartaric acid (TA) on the properties of polysulfone (PSn) ultrafiltration membranes were studied in terms of morphology and hydrophilicity (HPCT) of membrane. Asymmetric membranes were prepared by direct blending of polyvinyl pyrrolidone (PVP) with D-TA and DL-TA in membrane casting solution. FTIR analysis was done for the confirmation of the reaction of PVP and TA in blended membranes and plain PSn membranes. Scanning electron microscope (SEM), field emission scanning electron microscope (FESEM) and atomic force microscopy (AFM) were used for analyzing the morphology and structure of the resulting membranes. The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and HPCT. PWF increased from $52L/m^2h$ to $79.9L/m^2h$ for plain and D-TA containing PSn membrane, respectively. Water contact angle also found to be decreased from $68^{\circ}$ to $55^{\circ}$. In Additionally, permeation and rejection behavior of prepared membranes was studied by bovine serum albumin (BSA) solution. A considerable increase in BSA flux (from $19.1L/m^2h$ for plain membrane to $32.1L/m^2h$ for D-TA containing membrane) was observed. FESEM images affirm that the pore size of the membranes decreases and the membrane permeability increases from 0.16 to 0.32 by the addition of D-TA in the membrane. D-TA increases the HPCT whereas; DL-TA decreases the HPCT of PSn membrane. PVP (average molecular weight of 40000 Da) with D-TA (1 wt%) gave best performance among all the membranes for each parameter.

A Preliminary Assessment of Groundwater Chemistry for Agricultural Water Supply in the Mangyeong-Dongjin Watershed (만경-동진강 유역 지하수의 화학적 특성에 대한 농업용수 측면의 예비적 평가)

  • Choi, Hanna;Kwon, Hong-Il;Yoon, Yoon-Yeol;Kim, Yongcheol;Koh, Dong-Chan
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.65-75
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    • 2021
  • We investigated hydrochemical and stable isotope characteristics of groundwater in a large agricultural plain, the Honam plain, to evaluate the adequacy of agricultural water supply. For preliminary assessment for the area, we collected 23 groundwater samples from domestic wells and conducted hydrochemical and water stable isotope analysis. Groundwater in the study area is mainly Ca-HCO3 type resulting from water-rock interactions. Stable oxygen and hydrogen isotopic compositions indicated that recharge water is derived from precipitation while some sampling sites had evaporation signatures. Irrigation water quality using sodium absorption ratio and salinity hazard showed most of the groundwater samples were found to be suitable for irrigation. The groundwater in the southwestern part of the study area was affected by both seawater intrusion and agricultural activities, indicating a higher possibility of groundwater contamination near the coastal areas. Elevated concentrations of nitrate and phosphate ions in the groundwater are considered to be influenced by anthropogenic activities such as fertilizer application. It is expected that this study would be able to provide preliminary information on groundwater quality for agricultural water supply in the Mangyeong-Dongjin watershed.

Experimental Study on Pressure Loss of Flow Parallel to Rod Bundle with Spacer Grid (지지격자가 있는 봉다발과 축방향으로 평행한 유동의 압력손실에 관한 실험적 연구)

  • Lee, Chi-Young;Shin, Chang-Hwan;Park, Ju-Yong;In, Wang-Kee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.689-695
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    • 2012
  • The friction factor in a rod bundle and the loss coefficient at a spacer grid were examined. As a test section, 25 smooth rods, 9.5 mm in diameter and 2000 mm in length, were prepared and installed in a $5{\times}5$ square array in a square channel. In this case, the P/D (Pitch-to-Diameter ratio) was 1.35. In this work, plain (i.e., no mixing vanes), split-vane, and hybrid-vane spacer grids were tested. In a bare rod bundle (i.e., no spacer grid), the measured friction factors were in good agreement with the previous correlations. Among the spacer grids tested, the hybrid-vane spacer grid presented the largest friction factor in the rod bundle and loss coefficient. This may be because of the flow pattern change induced by large relative plugging of the flow cross section and mixing vane geometry. At Re=$5{\times}10^5$, the predicted loss coefficients of plain, splitvane, and hybrid-vane spacer grids were approximately 0.79, 0.80, and 0.88, respectively.

Sedimentary Facies and Geomorphological Development of Alluvial Plain at Neungsan-ri, Buyeo, Korea (부여 능산리 충적평야 퇴적상과 지형발달)

  • Yoon, Soon-Ock;Kim, Ae-Sun;Hwang, Sang-Ill
    • The Korean Journal of Quaternary Research
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    • v.24 no.1
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    • pp.35-45
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    • 2010
  • The aims of this study are to clarify the geomorphological development of a alluvial plain and discuss the vegetation environments and agriculture activities in the Wangpo-River alluvial plain at Neungsan-ri, Buyeo by analyzing geomorphological classification, sedimentary facies and age datings. The alluvial plain at Wangpo-River was formed by the influences of Geum-River with the sea-level rising during the Holocene. The basin of Wangpo-River consists of natural levees, back marsh-type alluvial plains, valley plains and hills. The natural levees by Geum-River largely distributes at the area where Wangpo-River flows to Geum-River and the alluvial plains at the middle and lower reach are the back marsh areas of Geum-River. Moreover, the area along Wangpo-River show higher contents of coarse materials and thinner peat sediments than the back marsh. The lower sandy deposits in the alluvium of Wangpo-River was formed with the influences of human in the Bronze Age during the sea level falling and the peaty deposits was formed due to the water level rising of Wangpo-River during the sea level rising in the early Iron Age.

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Effect of the Various Admixtures to Improvement of Concrete Using Over-added Blast Furnace Slag at Early Age (고로슬래그 미분말을 다량 사용한 콘크리트의 초기품질 향상에 미치는 각종 혼합재료의 영향)

  • Lee, Ju-Sun;Pei, Chang-Chun;Ryu, Gum-Sung;Koh, Kyung-Taek;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.733-736
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    • 2008
  • This study, with the purpose for early quality improvement of concrete which used large quantity of fly ash, changed various admixture material type and reviewed the basic characteristics. First off, the flow overall was highest when polycarb onic Acid high early strength AE water reducing agent was displaced, while air amount satisfied target level only in the case of plain, and setting time was shown best by getting 30 more minutes than plain and about 3 more hours than conventional when KOH is displaced. Compressive strength was shown best at age 1 day and 3 days when KOH was displaced, and at age 28 days when fine particle cement was displaced. By and large, this study concludes that concrete quality improvement admixture material that used large amount of fly ash showed worse effects than plain, therefore it is determined that there need be more study for development of concrete early quality improvement admixture material that used large amount of fly ash.

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Improvement of the Quality on High Volume Fly-Ash Concrete Corresponding to the Addition of Various Admixtures (각종 혼합재료의 첨가에 따른 플라이애쉬 다량 사용 콘크리트의 초기품질 향상)

  • Lee, Ju-Sun;Pei, Chang-Chun;Ryu, Gum-Sung;Koh, Kyung-Taek;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.737-740
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    • 2008
  • This study, with the purpose for early quality improvement of concrete which used large quantity of fly ash, changed various admixture material type and reviewed the basic characteristics. First off, the flow overall was highest when polycarb onic Acid high early strength AE water reducing agent was displaced, while air amount satisfied target level only in the case of plain, and setting time was shown best by getting 30 more minutes than plain and about 3 more hours than conventional when KOH is displaced. Compressive strength was shown best at age 1 day and 3 days when KOH was displaced, and at age 28 days when fine particle cement was displaced. By and large, this study concludes that concrete quality improvement admixture material that used large amount of fly ash showed worse effects than plain, therefore it is determined that there need be more study for development of concrete early quality improvement admixture material that used large amount of fly ash.

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Experimental investigation on durability performance of rubberized concrete

  • Guneyisi, Erhan;Gesoglu, Mehmet;Mermerdas, Kasim;Ipek, Suleyman
    • Advances in concrete construction
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    • v.2 no.3
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    • pp.193-207
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    • 2014
  • The study presented herein aims to investigate the durability related properties of rubberized concrete. Two types of waste scrap tire rubber were used as fine and coarse aggregate, respectively. The rubber was replaced with aggregate by three crumb rubber and tire chips levels of 5, 15, and 25% for the rubberized concrete productions. In order to improve the transport properties and corrosion resistance of rubberized concretes, SF was replaced with cement at 10% replacement level by weight of total binder content. The transport properties of the rubberized concretes were investigated through water absorption, gas permeability, and water permeability tests. The corrosion behavior of reinforcing bars embedded in plain and silica fume based rubberized concretes was investigated by linear polarization resistance (LPR) test. The results indicated that the utilization of SF in the rubberized concrete production enhanced the corrosion behavior and decreased corrosion current density values. Moreover, the reduction in the water and gas permeability coefficients was observed by the incorporation of SF in plain and especially rubberized concretes.

An Experimental Study on the Engineering Properties of Ultra-High Strength Concrete according to Types of Mineral Admixtures (광물질 혼화재 종류에 따른 초고강도 콘크리트의 공학적 특성에 관한 실험적 연구)

  • Joung Hyun-Woong;Kang Hoon;Lee Sang-Soo;Song Ha-Young;Kim Eul-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.29-32
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    • 2005
  • In this study, the experiment was carried out to investigate and analyze the strenth properties and flowability of ultra-high strength concrete accroding to types of mineral admixtures. The main experimental variables were water/binder ratio 25.0, 27.5 and 30.0$\%$, water content 155, 160, 165, and 170kg/$m^{3}$ and mineral admixtures such as fly ash, silica fume and meta kaolin. According to the test results, the principle conclusions are summarized as follows. 1) In case of using admixtures, superplasticizer amount need more than plain concrete. 2) According to kinds of admixtures, the viscosity of concrete show much difference. 3) The compressive strength of concrete that use admixtures becomes low in early-age strength, but appeared by higher than plain concrete in long-term strength. 4) Meta kaolin is excellent in side but has viscosity enlargement efficiency a little. But, problem estimates that is not to make design strength 600 and 700kgf/$cm^{2}$ if use mixing condition with water-binder ratio properly.

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Investigation of the High Strength Mortar in accordance with various Non-water based liquid types (물이 아닌 액체의 종류 변화에 따른 공강도 모르터의 특성분석)

  • Han, Dong-Yeop;Park, Byung-Kwan;Baek, Dae-Hyun;Song, Yong-Won;Kim, Tae-wan;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.61-64
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    • 2007
  • This study progressed fresh mortar test and hardening mortar test as a characteristic analysis of high strength mortar that is not water but replaced liquid, and the results are summarized as following. As a characteristic of fresh mortar, the flow that is following by the changes of the kind of replaced liquid decreased in order of E, M, A, K, O, L, G, and H, and it is indicated that liquid except H, the flow was better then others. The test show the bending strength of G, L, K, O at and H were more increased then plain as the replaced liquid change on the first day, and on the 28th day, G, L, and K was more increased then plain. The compressive strength of G, K, and O was similar with P(-10) at the first day. On 7th day, the test show G, and L was more increased then P(-10), and other replaced liquid were similar or decreased. On the 28th day, G, K, and A was similar with P(-10) and it is decreased in order of E, L, O, and H.

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Food Components and Sensual Characterization of Commercial Plain-dried Silver-stripe Round Herring (시판 소건 샛줄멸의 식품성분 및 관능 특성)

  • Kim, Hyung-Jun;Yoon, Min-Seok;Park, Yong-Seok;Ha, Jin-Hwan;Jung, In-Kwon;Heu, Min-Soo;Kim, Jin-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1457-1464
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    • 2008
  • For the effective use of under-utilized resources, silver-stripe round herring (SSRH), the plain-dried SSRH was investigated and compared with boiled-dried SSRH and boiled-dried anchovy on the food component and sensual characterization. Moisture content and salinity of the plain-dried SSRH were 31.9% and 7.6%, respectively. Moisture content of the plain-dried SSRH was higher, while the salinity was lower than those of boiled-dried SSRH and anchovy. According to the results of peroxide value, fatty acid composition, Hunter b value, and browning index, the rancidity was higher in plain-dried SSRH than in boiled-dried SSRH and anchovy. When compared to the boiled-dried SSRH and anchovy, the plain-dried SSRH was higher in calcium and phosphorus contents, while lower in total content of amino acid. According to the results of hot-water soluble-N, trichloroacetic acid-N, free amino acid, and taste value, the taste of plain-dried SSRH was superior to those of the boiled-dried SSRH and anchovy. The results of chemical components and sensory evaluation indicated that the plained-dried SSRH could be substituted for boiled-dried anchovy classified into special grade, if fish odor of SSRH can be improved.