• Journal of the Korean Wood Science and Technology
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• 제30권3호
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• pp.34-41
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• 2002

This study investigated the thermogravimetric analysis of two types of cured tannin-based adhesives from wattle and pine, with three hardeners of paraformaldehyde, hexamethylenetetramine and TN (tris(hydroxyl)nitromethan), at a temperature of 170℃ and a heating rate of 5, 10, 20 and 40℃/min for 10 minutes. The 5 minutes cured wattle tannin-based adhesive with each hardener at 170℃ was also tested to compare the degree of curing. It was found that thermogravimetric analysis could be used to measure the degree of curing of a thermosetting adhesive. The TG-DTG curves of all the adhesive systems were similar and showed three steps in a similar way to a phenolic resin. This means that each adhesive system is well cross-linked. However, a high thermal decomposition rate was shown at 150 to 400℃ in the case of the pine tannin sample with TN (tris(hydroxyl)nitromethan). The Flynn & Wall expression was used to evaluate the activation energy for thermal decomposition. As the level of conversion (𝛼) increased, the activation energy of each system increased. The activation energy of the wattle tannin-based adhesive with paraformaldehyde was higher than the others.

• Journal of the Korean Wood Science and Technology
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• 제24권4호
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• pp.1-6
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• 1996

Extracts from bark have been studied with a view to producing water-proof wood adhesives. Lately many softwoods, such as radiata pine from New Zealand and larch from Siberia, Russia, have been imported and utilized, and their residual barks would be expecting as potential raw materials for something useful chemicals. The great effort toward utilization of bark extractives as a chemical feedstock has been made on a worldwide level. However few report has been done for the utilization of tree bark extractives in Korea. Hot-water extracts were prepared from barks of Japanese larch(Larix leptolepis). Siberian larch(Larix gmelinii) and Radiata pine(Pinus radiata). The effect of various factors, such as particle size, liquor ratio, extraction temperature, and reaction time, on the extractive yields was discussed. Particle sizes affected the hot-water extractives: the finer the particle size, the higher extractives and extract efficiency. Higher temperature and higher liquor ratio were more effective. Extractives from Japanese larch were relatively less than those from Siberian larch and Radiata pine barks. Formaldehyde precipitates was the highest in extractives of Radiata pine barks. It could be concluded that Siberian larch bark was the best raw material for tannin adhesives, because its extractive yield was higher than those of the other barks.

• 한국의류학회지
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• 제35권2호
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• pp.218-229
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• 2011

Dyeing properties of cotton and ramie fabrics with pine needles colorants were studied by investigating the analysis of pine needles colorants, the effect of dyeing conditions (such as dye concentration, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for pine needles extract was 285nm, and pine needles colorants produced a yellow color. From FT-IR and GC-MS results, it was assumed that chromophoric substance from pine needles extracts were mixed with flavonol tannin and flavanol tannin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. Post-mordanting was more effective than pre-mordanting and the dye uptake of fabrics improved by mordanting. The colorfastness of dyed fabrics showed a low rating; however, colorfastness to washing and dry cleaning of cotton fabrics mordanted with N.Cu, and friction fastness of ramie fabric mordanted with Cu improved. The dyed fabrics showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in fabrics dyed with pine needles extracts.

• 복식문화연구
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• 제18권2호
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• pp.371-381
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• 2010

The pine needles can be used for four seasons in normal living and it can be taken friendly everywhere as it is distributed over 50% in Korea. The pine needles consist of vitamins, protein, minerals, essential oil and enzyme related to antimicrobial activity. It has effect like high blood pressure, neuralgia and hanged over by terpene, glucokinin, rutin, apigenic acid and tannin. Also the extract of them can be used for dyeing of fabrics. However, the extract components and effects of them are not well known yet. Therefore, the purpose of this study was to investigate the volatile components of the pine needles extract and functionality. The pine needles extract was dyed into various fabrics(nylon, silk, wool and soybean) and mordanted with Al, Cu, Cr, Fe and Sn. The extracted aroma compounds were compared by gas chromatography-mass spectrometry. The major volatile compounds of pine needles verified by using SPME were alpha-pinene, beta-pinene, beta-phellandrene, caryophyllene, ethanon, benzen. A total of 15 compounds were identified by using the SPME fibers. In the UV-visible spectra, the maximum absorption of wavelength of the pine needles ethanol extract appeared at 460, 630nm for chlorophyll component and at 237, 281nm for tannin component with the pine needles distilled water extract. Most of sample showed high antibacterial effect in none mordant but wool fabric showed high antibacterial effect in mordants. The result of UV block test showed a superior ability of blocking ultraviolet ray infiltration in all sample.

• Journal of the Korean Wood Science and Technology
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• 제47권1호
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• pp.80-89
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• 2019

Pine barks are important biomass resources because they are utilised in the production of pine wood and rosins. However, no chemical study has been conducted on the hydrophilic status of pine barks in Indonesia. This aim of this study is to explore the hydrophilic extracts of the barks from six Pinus species (P. elliotii, P. caribeae, P. oocarpa, P. merkusii P. montezumae, and P. insularis). The hydrophilics of pine barks were analysed using gas chromatography-mass spectrometry. The presence of polyphenol contents in the ethanol extracts obtained from the barks of six Pinus species was determined using the tannin-formaldehyde method, Folin-Cioucalteu assay, and vanillin-HCl assay. The ethanol and hot water soluble extractives derived from inner barks were higher in quantity when compared to those derived from the outer bark samples. The polyphenol measurement showed that the highest value of total phenol content was derived from the outer bark of P. montezumae whereas those of the total phenol and tannin- formaldehyde contents were derived from the inner and outer barks of P. oocarpa. GC-MS analysis revealed that nitrogenous compounds are dominant constituents in the inner and outer barks of the six species, followed by sugars and monophenolics, respectively.

• 한국초지조사료학회지
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• 제22권1호
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• pp.59-68
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• 2002

본 연구는 산림부산물인 지엽류를 보다 효율적으로 활용할 수 있는 방안을 모색하고자 졸참나무지엽과 소나무지엽에 대한 사료가치를 구명하였으며 그 결과를 요약하면 다음과 같다. 일반조성분인 조단백질 함량은 참나무지엽과 소나무지엽이 각각 6.00∼7.89%, 5.15∼6.06%로 참나무지엽이 다소 높았으며 생육이 진행됨에 따라 참나무지엽은 감소하였으나 소나무지엽은 생육시기에 크게 영향을 받지 않았다. 조지방 함량은 각각 1.90∼2.68%, 6.30∼6.33%로 소나무지엽이 현저하게 높은 수준이었고, 조섬유 7 함량은 각각 33.3∼35.2%, 33.7∼34.8%로 비슷하였으며 생육이 진행됨에 따라 증가하는 경향이었다. 그리고 조회분 함량은 각각 3.13∼2.78%, 2.11∼l.93%로 참나무지엽이 약간 높았다. 무기물 함량은 Ca, Mg, Mn, Cu가 소나무 지엽보다 참나무지엽이 높은 수준이었고 P, K, Na, Fe, Zn은 비슷한 수준이었으며 생육이 진행됨에 따라 대부분 감소하는 경향이었다. 소나무지엽과 참나무지엽의 ABF 함량은 각각 47.7∼52.0%, 46.1∼48.1%로 비슷하였으며 생육이 진행됨에 따라 증가하였고(P<.05), NDF 함량은 각각 64.1∼67.9%, 65.0∼66.5%로 비슷하였으며 생육이 진행됨에 따라 소나무지엽은 증가하였으나(P<.05) 참나무지엽은 비슷하였다. 건물소화율은 소나무지엽이 51.7∼48.4%로 생육이 진행됨에 따란 감소하였고, 참나무지엽은 53.0%∼51.4%로 비슷하였다. 가소화양분층량은 참나무지엽이 50.9∼52.4% 이었고, 소나무지엽은 47.7∼51.1%로 생육이 진행됨에 따라 감소하였으며(P<.05), 상대적 사료가치는 참나무지엽과 소나무지엽이 비슷하였고 생육이 진행됨에 따라 낮아지는 경향이었다. 탄닌 함량은 참나무지엽과 소나무지엽이 각각 2.96%, 6.27%로 소나무지엽이 높았으며 지엽을 건조하였을 때 각각 2.46%, 4.79%로 탄닌 함량이 낮아지는 경향이었다.

• Asian-Australasian Journal of Animal Sciences
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• 제18권9호
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• pp.1262-1266
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• 2005

Twelve Korean native goats, spontaneously infected with mixed species of Eimeria were used to study the possible direct anticoccidial effect of feeding condensed tannin-containing plants on the production of Eimeria oocysts. The effects of feeding pine (Pinus densifora) needles, oak (Quercus acutissima) leaves and lucerne chaff on coccidia oocyst output were studied for a period of 10 days post-feeding. The results indicate that feeding fresh pine needles (40 g condensed tannins (CT) dry matter (DM)/day/goat) and oak leaves (40 g CT DM/day/goat) in combination with lucerne chaff had rapid anticoccidial activities in goats as demonstrated by a sharp decrease in oocyst production. Two days after feeding, the numbers of oocysts per gram of faeces (OPG) from the goats fed pine needles with lucerne chaff, and from goats fed oak leaves reduced by 40% and 44% compared to pre-feeding, respectively. On the sixth day after commencing feeding pine needles and oak leaves, the reduction was 81% and 72%, respectively. Ten days after feeding pine needles and oak leaves, the OPG was reduced by 93% and 85%, respectively compared to pre-feeding. Statistical analysis showed that feeding pine needles and oak leaves to goats naturally infected with coccidia significantly (p<0.001) reduced the numbers of oocysts compared to the control group fed lucerne chaff only. Four clinically important species of coccidia, Eimeria parva, Eimeria ninakohlyakimovae, Eimeria christenseni and Eimeria arloingi were identified in Korean native goats.

• Journal of the Korean Wood Science and Technology
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• 제33권2호통권130호
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• pp.29-39
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• 2005

Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

• Journal of the Korean Wood Science and Technology
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• 제25권1호
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• pp.23-27
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• 1997

Alkali-soluble extracts were prepared from barks of Japanese larch(Larix leptolepis). Siberian larch(Larix gmelineii) and Radiata pine(Pinus radiata) The effect of various factors, such as particle size, liquor ratio, extraction temperature, and reaction time, on the extracts yield was investigated. Particle sizes affected the alkali-soluble extracts; the finer the particle size, the higher extracts and extract efficiency. High temperature and high liquor ratio were more effective. In the range of 0.25% to 1% NaOH concentration, alkali extracts were increased with the increasing alkali concentration. However, extract yields were leveled off above 0.5% alkali concentration. Extractions with NaHCO3 were almost equivalent to those of NaOH extraction. 1% NaOH and 1% NaHCO3 resulted in the highest yields of alkaline extracts. Extracts from Japanese larch were lower than those from Siberian larch and Radiata pine barks. Siberian larch bark was the best raw material for tannin adhesives, because its extractive yield was higher than those of the other barks. Concerning pH of alkaline media during extraction, small increases of the extract yields were resulted at range of pH 7 to pH 9, while a large increases from pH 9.0 to pH 12. This phenomenon is attributed to higher alkalinity.

• 한국의류산업학회지
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• 제14권4호
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• pp.648-659
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• 2012

This research categorizes fundamental data needed to develop eco-friendly fabrics treated with bamboo leaf & pine leaf extracts. The effect of mordant on those fabrics was analyzed through the measurement of mechanical properties and the estimation of primary hand values for cotton and silk fabrics dyed with bamboo leaf and pine leaf extracts that were later treated with various mordants. When cotton was dyed with bamboo leaves and pine leaves extracts, EM, WT, 2HB, 2HG, 2HG5, LC, T, and W increased however, RT, SMD, and RC decreased compared to raw cotton fabric. The B, G, and MIU increased after mordant treatment to the dyed cotton and resulted in a stiffer and rougher cotton's hand. EM, WT, RT, MIU, WC, T, and W increased (in terms of silk); however, LT, B, 2HB, G, 2HG, 2HG5, MMD, SMD, and LC decreased compared to raw silk fabric. Similar to the dyed cotton, mordant treatment increased the MIU and LC of dyed silk subsequently, the hand became stiffer and rougher. A greater tannin adsorption results in an increased mechanical property and the primary hand value. For both fabrics, mordant treatment made its smoothness drop. However, the scale of drop for cotton was significant, while the scale of the drop for silk was minor. In terms of type of mordant, femordant and natural-mordant treatment influenced the tensile, shear, surface properties of fabrics, and primary hand values more than Cu-mordant and synthetic-mordant in addition, this increased the stiffness, hardness, and roughness of fabrics.