• 한국인쇄학회지
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• 제21권1호
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• pp.71-80
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• 2003

Printing inks are mainly composed of pigment and vehicles. Among these components, the Vehicle affect the rheologic property of the ink the most but pigment content or characteristic also affect to the fluidity property not less than the vehicle. In the study, with the same vehicle on each sample, by making the sample to increase pigment content gradually. It can be examined the influence of the pigment to the fluidity of ink. In result we found that the viscosity value of the low shear rate rang has relatively higher value with increasing the pigment content in the ink. According to higher pigment content, yield stress and thixotropy index increases gradually. Structure recovery of the ink is that, the higher pigment content's ink, the less changing shear rate, and it takes less time to recover.

• 한국인쇄학회지
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• 제21권2호
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• pp.75-87
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• 2003

Printing inks are mainly composed of pigment and vehicles. Among these components, the Vehicle affect the rheologic property of the ink the most but pigment content of characteristic also after to the fluidity property not less than the vehicle. In the study, It is tested effect to the ink fluidity and structure recovery according to change the pigment particle size. The ink fluidity have been observed by using rheometer at the various conditions and it has been tested to observe what the ink fluidity has different means. In result We have found that the viscosity value of the low shear rate range has relatively higher value with decreasing the pigment particle size in the ink. Also, it has been found that when the pigment particle size decreases, the yield stress gradually increase. In the case of ink's structure recovery, when the pigment particle size decreases in the ink, the less changing shear rate, and it takes less time to recover.

• 한국재료학회지
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• 제16권10호
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• pp.599-605
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• 2006

N-(3-triethoxysilylpropyl)-1,4-diaminoanthrquinone-2,3-dicarboximide (TESP-DADI), an organic blue pigment, has been prepared and incorporated into silica solid matrix reacting triethyl orthosilicate (TEOS) via sol-gel method. Morphology and microstructure of resulting hybrid pigment were studied employing SEM and TEM. The micrographs and particle size distributions showed that uniform pigment can be obtained employing TEOS-based sol-gel method forming silica core. Particle size distribution of dispersed pigment in water was examined using the technique of dynamic light scattering. The ensuing pigment dispersion ink was subjected to various physicochemical evaluation such as viscosity, surface tension, inkjet stability, storage stability, and color change as inkjet ink using spectrophotometric, and microscopic techniques.

• 펄프종이기술
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• 제37권2호
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• pp.47-56
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• 2005

In technology of ink-jet coating, Image quality from correlation between paper and ink depends on the properties of printer and ink as well as those of paper material. Generally, According to the quality of ink that consists of colorants from 5 to 20 percent, It seems that absorption behavior of each ink is different. In this study, we studied to estimate the effects of dye and pigment ink on the absorption and printing properties using 2-type papers on the market and 3-type silica-based coated papers whose pore structure is different. Using the theory of contact angle to evaluate the absorption property, it was possible to measure the baseline length between paper and ink, volume of droplet as well as contact angle. Also, It was possible to calculate wetting energy(mN/m) and spreading coefficient(mN/m) using the surface tension of each ink. These measurements were available to estimate ink-jet qualities.

• 한국염색가공학회지
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• 제29권4호
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• pp.202-210
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• 2017

In recent years, the water-based ink have been widely used in various industrial applications due to environmental problems. Dispersibility of the pigment for applications of the water-based ink is the one of the most important technical factors to produce uniform color products. Thus, in this study, the three-roll mill process was used to improve the dispersion of the water-based ink. The results indicated that the three-roll mill reduced the size of pigment particles in the ink more than 50%. In addition, the dispersant showed an important role to maintain the dispersion stability of the pigment in the water-based ink over 120 hours. We also confirmed the optimum contents of the ink stock solution, drying temperature and drying time by the colorimeter and colorfastness tests on produced PET synthetic suedes.

• 한국재료학회지
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• 제24권2호
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• pp.73-80
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• 2014

Ink-jet printing technology has been widely attractive due to its facility for direct and fine printing on various substrates. Recent studies have focused on expanding the application of ink-jet printing technology from general consumer use and design companies to the prototype production of precision parts and parts manufacturing. The use of ink-jet printing technology in decorated tableware, tiles, and other ceramic products also has many advantages. The printing process is fast and can be adaptable to various kinds of objects because there is no direct contact point between the printer and the substrates to be printed. For application to ceramic product decoration, inks containing highly dispersed inorganic nano-pigments are required. Here we report the synthesis and characterization of blue $CoAl_2O_4$ nanopigment for ink-jet printing. Blue ceramic ink based on the obtained $CoAl_2O_4$ pigment was prepared by dissolving $CoAl_2O_4$ pigment in a mixed solution of ethylene glycol and ethanol with volume ratios of 7:3 and 8:2, respectively, to obtain the appropriate viscosity for ink-jet printing. The ink solution contained 15 wt% of $CoAl_2O_4$ pigment and Cetyltrimethyl ammonium bromide(CTAB) and Sodium dodecyl sulfate(SDS) as dispersive agents. The prepared blue ceramic ink was stably jetted and formed a sphere-shaped droplet from an ink-jet printer.

• 한국염색가공학회지
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• 제32권1호
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• pp.19-26
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• 2020

The previous study reported that the quaternary copolymer of MMA, BA, MAA, and NEA was expected to be a good monomer composition for a binder polymer with good rubbing fastness for digital textile printing(DTP) pigment ink. However, the rubbing fastness of the dyed fabric with the quaternary copolymer binder containing pigment ink is not enough to be commercially used. Therefore, this study aims to optimize MMA:BA:MAA:NEA composition for improved rubbing fastness. And the binder polymer with various MMA:BA:MAA:NEA compositions were synthesized using miniemulsion polymerization. The particle size, viscosity, molecular weight, and Tg of the synthesized binder were evaluated. And the color strength and rubbing fastness of the black pigment ink dyed cotton fabrics with the prepared binders were also evaluated. Then, the stiffness of undyed and dyed cotton fabrics were evaluated to investigate the changes in touch as the binder structure changes.

• 한국인쇄학회지
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• 제21권1호
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• pp.1-10
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• 2003

Printing ink is faced various shear stress situation until it transfer to the printed substrate through the press. And in each shear stress condition the ink is needed to keep the appropriate viscosity according to the condition. The change of printing ink viscosity has been explained by well-known through the viscosity profile curve. But actually, the quality of printed paper depends on the ink behavior after transfer the substrates. Like this, to look into the behaviour of the ink on the printed substrate, it is needed the experiment of the ink structure recovering by rheology study. In this study, by controling the $CaCO_3$ content in the ink, after investigating the effect of the ink's structure recovery of the pigment concentration, we intend to predict the printing quality of the ink behvior on the substrate depending on pigment content.

• Journal of Forest and Environmental Science
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• 제18권1호
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• pp.97-105
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• 2001

The main objective of this study was to investigate effects of pigment mixed with different ratio on the double coated paper. Mineral pigments such as clay and ground calcium carbonate(GCC) as well as hollow sphere plastic pigment were used to evaluate the physical, optical properties and printabilities of double coated paper. The physical properties such as gloss and smoothness, and the printability(ink gloss) of double coated paper were measured to evaluate the effects of the bottom layer on improving the properties of top layer. The data indicated that the usage of hollow sphere plastic pigment for the bottom layer coating improved the surface properties of double coated paper, and that ink gloss was significantly influenced by the structure of bottom layer even when hollow sphere plastic pigment was used for the bottom layer coating.

• 한국재료학회지
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• 제16권7호
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• pp.422-429
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• 2006

Studies were performed on preparation of organic-inorganic hybrid silica dye in a dispersing ink system. The silica was subjected to surface modification using 3-aminopropyltrimethoxysilane (APTMS) in order to promote the chemical reactivity of the raw silica. On the surfaces of the aminosilane-functionalised silica, red vinylsulfone-containing azo dye was adsorbed. The dye was found to have chemically reacted with the aminosilane-grafted silica surface, which was proven by FT-IR spectra. Studies on morphology and microstructure were performed employing scanning electron microscopy. The SEM micrographs and particle size distributions showed that a homogeneous pigment can be obtained employing silica as a core. Particle size distribution was also examined using the technique of dynamic light scattering. The ensuing pigment was subjected to various physicochemical evaluation such as inkjet property, storage stability, color change as inkjet ink using printer, spectrophotometric, microscopic techniques. Studies on hybrid dyes from the silica surface demonstrated that, in general, stable pigments for inkjet dispersion ink were obtained.