• Title/Summary/Keyword: pigment composition

검색결과 168건 처리시간 0.031초

인쇄 모틀의 방지를 위한 제지도공 기술개발 (제2보)-도공안료 조성과 도공량에 따른 도공지의 광학적 특성 변화 (Development of Paper Coating Technologies to Prevent Print Mottle (II)-Optical Properties of Coated Papers Affected by Coating Pigment Composition and Coat Weight)

  • 정준경;신동소;이학래
    • 펄프종이기술
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    • 제29권1호
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    • pp.26-35
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    • 1997
  • A study was carried out to investigate such optical properties of coated papers as brightness, opacity and gloss affected by the coating pigment composition and coat weight using clay, ground calcium carbonate, precipitated calcium carbonate, and plastic pigment as pigments. The effects of drying methods and supercalendering on optical properties were also evaluated. Gloss increased abruptly while brightness and opacity decreased slightly by supercalendering due to surface smoothing and consolidating effects of the coating layers. Optical properties changed little by drying methods. Pigment composition showed significant influences on optical properties. Brightness of coated papers decreased or increased linearly as the coat weight was increased depending on the pigment composition, while opacity increased linearly for all formulations. Gloss increased abruptly at low coat weights for all formulations and approached a plateau value at coat weight of 15-20g/$m^2$. Third order polynomial regression equations relating the coat weight with gloss have been derived and tabulated.

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Analysis on the Pigment Composition of Phytoplankton Assemblages using HPLC (High Performance Liquid Chromatography) in the Adjacent Waters of Nuclear Power Plants in Spring

  • Choi, Hyu-Chang;Kang, Yeon-Shik;Choi, Joong-Ki;Song, Tae-Yoon;Yoo, Man-Ho
    • Journal of the korean society of oceanography
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    • 제39권4호
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    • pp.234-242
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    • 2004
  • The pigment composition and concentration of phytoplankton assemblages using HPLC in the adjacent waters of four nuclear power plants (Yonggwang, Kori, Wolsong and Ulchin) were investigated during the spring blooming in 2004. The mean concentration of chlorophyll a ranged from 563.8 to 2,949.0ng $l^{-1}$, with the lowest concentration at Kori and the highest concentration at Wolsong. Among the carotenoids, the amounts of fucoxanthin and chlorophyll $C_2$ were relatively higher than those of other pigments in the study site. As minor pigments, zeaxanthin, chlorophyll b, 19'-butanoyloxyfucoxanthin, diadinoxanthin, 19'-hexanoyloxyfucoxanthin, chlorophyll $C_3$ and peridinin were detected. The results of pigment composition and concentration showed that diatoms had an important proportion of phytoplankton community when a spring bloom occurred. Cyanobacteria was present relatively low density at the Wolsong and the green alga such as chlorophytes and prasinophytes were abundant at the Yonggwang and Kori, while dinoflagellates characterized by peridinin were common at Ulchin and Kori. The pigment composition and concentration of phytoplankton after passing through the cooling-water system of nuclear power plant were highly variable. No distinct trend of the change of each pigment composition and amount was detected but the variation of fucoxanthin and chlorophyll $C_2$ highly coupled with that of chlorophyll a. We pointed out that the diatom controlled the overall variation of phytoplankton biomass during the spring season.

경복궁 근정전 단청안료의 성분분석 (The composition analysis of Danchung pigments at Geunjeongjeon Hall in Gyeongbokgung Palace)

  • 조남철;문환석;홍종욱;황진주
    • 보존과학연구
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    • 통권22호
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    • pp.93-114
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    • 2001
  • The composition analysis of Danchung pigments at Geunjeongjeon Hall in Gyeongbokgung Palace were carried out by FXRF and MXRD. The analytical result of the inside pigments at Geunjeongjeon showed that these painted in use the mineral pigments. Gold pigment was pure gold(Au).The main composition identified in green pigments were chalcanthite($CuSO_4$.$5H_2O$) and celadonite($K(Mg, Fe, Al)_2$.$(Si, Al)_4O_10(OH)_2$ ). Red pigments werecinnnabar(HgS).The analytical result of the outside pigments at Geunjeongjeon revealed that these applied to the artificial synthetic pigment. Yellow pigment was chromeyellow($PbCrO_4$). The main composition identified in red pigments were red lead($Pb_3O_4$)and hematite($Fe_2O_3$). Green pigments were emeral green($C_2H_3A_s3Cu_2O_8$) and chromegreen($Cr_2O_3$). Blue pigment was lazurite($Na_6Ca2Al_6Si_6O_24(SO_4)_2$), titanium dioxide($TiO_2$) of white pigment.

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DTP 안료 잉크용 고분자 바인더의 Self-crosslinking 공단량체 조성 최적화 연구 (Optimization of Self-crosslinking Comonomer Composition of Polymer Binder for DTP Pigment Ink)

  • 한민우;권웅;박성민;정의경
    • 한국염색가공학회지
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    • 제32권1호
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    • pp.19-26
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    • 2020
  • The previous study reported that the quaternary copolymer of MMA, BA, MAA, and NEA was expected to be a good monomer composition for a binder polymer with good rubbing fastness for digital textile printing(DTP) pigment ink. However, the rubbing fastness of the dyed fabric with the quaternary copolymer binder containing pigment ink is not enough to be commercially used. Therefore, this study aims to optimize MMA:BA:MAA:NEA composition for improved rubbing fastness. And the binder polymer with various MMA:BA:MAA:NEA compositions were synthesized using miniemulsion polymerization. The particle size, viscosity, molecular weight, and Tg of the synthesized binder were evaluated. And the color strength and rubbing fastness of the black pigment ink dyed cotton fabrics with the prepared binders were also evaluated. Then, the stiffness of undyed and dyed cotton fabrics were evaluated to investigate the changes in touch as the binder structure changes.

인공 진주 안료로서 염기성 질산비스무트에 관한 연구 (Properties of Bismuthoxynitrate as a Synthetic Pearl Pigment)

  • 이계주;유병설
    • 약학회지
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    • 제22권1호
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    • pp.22-26
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    • 1978
  • The purposes of this investigation were to study the characteristic properties of bismuthoxynitrate formed by hydrolysis of bismuthnitrate according to various reaction conditions and to propose the property difference between synthesized pearl pigment and bismuthsubnitrate as pharmaceuticals by means of X-ray diffraction, IR, DTA and TGA. The pearl pigment could be obtained by reaction of bismuth nitrate-diluted nitric acid solution with cold water (5.deg.) agitation at lower pH. The pearl pigment was BiO. NO$_{3}$. 2H$_{2}$O. in composition and crystalline form was thin plate of monoclinic system and its combination with water was assumed to be hydrated hydrous form between Bi-H$_{2}$O bond. On the other hand, bismuthsubnitrate was 5BiO.4NO$_{3}$.6H$_{2}$O in composition and crystalline form was pillar of rhombic system and the bond between Bi and H$_{2}$O molecules was assumed to be hydrous form. The different properties between two compounds in structure are presumed to be caused by the hydrolysing conditions of bismuthnitrate respectively.

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일원오악도 안료에 대한 과학적 분석 (A scientific analysis of pigments for the Ilweoloakdo)

  • 한민수;홍종욱
    • 보존과학연구
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    • 통권26호
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    • pp.165-188
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    • 2005
  • From the ancient to these days, there have been used many kinds of pigment which have two types that are inorganic pigment and organic pigment. At the ancient times, natural pigment had been used but the artificially mixed pigment has been used in modern times. By the way, searching for studies has been studied recently, it would be said the ancient pigments such as Danchung, Wall painting and Mural painting are the mainthema. However, studies about the pigments used in modern pictured relics have rarely can be found. Therefore, this analysis of Ilweolokdo would be important at the point of the pigments used in pictures of royal family in modern times and the results can be briefly summarized as below; Firstly, the results of qualitative analysis of the pigments that base or all pigments of picture was detected components of Ca, Fe and As, this results meaning that picture was used filler and basic paint. Secondly, a result of the analysis on the composition elements of the pigments shows that the main components in their composition are ;White - Lead Cyanamide($2PbCO_3$.$Pb(OH)_2$) or Titanium Oxide($TiO_2$)Blue - Ultramarine($2(Na_2O$.$Al_2O_3$ .$2Si_O2$).$Na_2S_2$)Green - Emerald green($C_2H_3A_s3Cu_2O_8$)Gold - Gold(Au), Red-Red Lead($Pb_3O_4$) or Cinnabar(HgS)Black - Carbon(C)Thirdly, X-ray diffraction analysis of crystalline structure for the blue and green pigment peeling off in picture shows that the components of blue pigment is Ultramarine($2(Na_2O$.$Al_2O_3$ .$2Si_O2$).$Na_2S_2$) and green pigment is Emerald green($C_2H_3A_s3Cu_2O_8$). Especially, microcrystalline structure of the green pigment was the shape like a cross section of wood. Consequently, we knew through the analysis of qualitative and microcrystallinestructures seen on the cross section of analyzed pigments layer that the all pigments used in the Ilweoloakdo is possible to use synthetic pigments in modern.

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Copper Phthalocyanine Pigment의 분산을 위한 (2-Dimethylamino)ethyl Methacrylate와 Oligo(ethylene oxide)methyl Ether Methacrylate를 포함하는 잘 규정된 블록 공중합체형 분산제의 원자 이동 라디칼 중합을 이용한 합성 (Synthesis of Well-Defined Block Copolymer Dispersants with (2-Dimethylamino)ethyl Methacrylate and Oligo(ethylene oxide)methyl Ether Methacrylate via ATRP for Dispersing Copper Phthalocyanine Pigment)

  • 김은희;김봉수;정기석;김진구;백현종
    • 폴리머
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    • 제36권1호
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    • pp.104-110
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    • 2012
  • LCD 컬러필터에서 안료의 분산은 컬러 강도를 증가시키는 중요한 요소이므로, 안료를 분산시키기 위한 안료 분산제의 첨가는 필수적이라 할 수 있다. 안료 분산제로서의 고분자는 안료와의 친화성을 가지는 anchoring group과 매체와의 혼화성을 가지는 stabilizing group을 포함하고 있다. 원자 이동 라디칼 중합은 잘 규정된 고분자 합성을 가능하게 하는 중합법으로, 이러한 구조를 포함하는 고분자형 안료 분산제를 얻기 위한 적절한 수단이 될 수 있다. Anchor로서 (2-dimethylamino)ethyl methacrylate를, stabilizer로서 oligo(ethylene oxide)methyl ether methacrylate를 각각 선택해 고분자 분산제를 합성하였다. 고분자의 구조 및 조성이 안료 분산에 미치는 영향을 연구하기 위해 다양한 길이의 stabilizing group을 가지는 diblock copolymer를 합성하여 비교하였다.

Detection of Bacteriochlorophyll-c Containing Species of Green Sulfur Photosynthetic Bacterium Chlorobium vibrioforme

  • Yoshitaka Saga;oka, Hirozo-Oh;Hitoshi Tamiaki
    • Journal of Photoscience
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    • 제9권2호
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    • pp.341-343
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    • 2002
  • Bacteriochlorophyll(BChl)-c containing species of green sulfur photosynthetic bacterium Chlorobium (ChI.) vibrioforme, which has BChl-d mainly, was detected. We obtained colonies on agar plates by spreading the liquid culture of ChI. vibrioforme f. sp. thiosulfatophilum strain NCIB 8327 which contained the high ratio of BChl-c/BChl-d, and transferred each colony into a new liquid medium. These cultures after growing were found to be classified into two categories. One possessed BChl-d as a light-harvesting pigment and the other did BChl-c. No colonies examined here contained both BChls-d and c. Therefore, the presence of both BChls-d and c in our cultures of ChI. vibrioforme was ascribed to the coexistence of two different cells which had BChl-d and c as the chlorosomal pigment, respectively. The change of pigment composition observed in our liquid cultures can be thus explained by the difference of growth rates between two kinds of cells.

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분광분석기를 이용한 안료의 색상분석에 관한 연구 (A study on the color analysis of the pigment by UV-Visible spectroscopy)

  • 정충호;강태희
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.515-521
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    • 2010
  • In this research, we were prepared the glazed ceramic samples by the change of the pigment content and investigated to reveal the standardized color. The chemical composition of the pigment was analyzed using a ICP-OES. XRF mapping and UV-Vis spectroscopy were used to evaluate the color property and surface homogeneity. The color development was observed as a result of analyzing the pigment content and change of the color. The pigment content and the spectral reflection showed the relation of the inverse proportion and the standardized color which could be revealed through analysis data.

신석기시대(新石器時代) 주칠토기(朱漆土器)의 과학적(科學的) 분석(分析)(II) (Scientific Analysis of the Neolithic Red Earthenwares(II))

  • 유혜선;장성윤
    • 박물관보존과학
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    • 제2권
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    • pp.69-76
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    • 2000
  • 본 연구는 동남해안 및 도서지방의 신석기시대 주칠토기 23점에 대한 과학적 분석의 일환으로서 먼저 태토성분, 소성온도, 안료성분 및 안료두께를 분석한 데에 이어 태토성분에 대한 통계적인 고찰 및 경도분석을 통한 안료성분의 역할을 보강하여 재정리한 것이다. 유도결합플라즈마분광기(ICP-AES)와 엑스선형광분석기(XRF)를 사용하여 태토의 성분분석을 실시하였고, 이 분석결과에 대한 다변량해석(PCA : 주성분분석법)을 수행한 결과, 토기의 태토는 범방, 욕지도, 나머지 지역의 3개 군으로 분류되었다. 또 태토와 안료의 경도를 토기 표면으로부터 깊이별로 측정한 결과, 산화철이 다량 포함된 안료층의 경도가 태토층보다 높았고 이를 통해 산화철이 고온소성시 경도를 크게 하는 역할을 했음을 알 수 있었다. 또한 안료층의 경도가 태토층 보다 높은 것은 안료층도 소성되었음을 의미하는 것으로, 토기성형시 안료를 먼저 바른 후 토기가 구워졌음을 유추해 볼 수 있다.