• Title/Summary/Keyword: physical transition

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Preparation and Characterization of Novel Temperature and pH Sensitive (NIPAM-co-MAA) Polymer Microgels and Their Volume Phase Change with Various Salts (pH 감응성 NIPAM-co-MAA 고분자 마이크로젤의 제조 및 분석과 염 종류에 따른 부피상 변화)

  • Khan, Mohammad Saleem;Khan, Gul Tiaz;Khan, Abbas;Sultana, Sabiha
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.794-801
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    • 2013
  • Novel microgels of N-isopropylacrylamide (NIPAM)-co-methacrylic acid (MAA) (NIPAM-co-MAA) with different contents of N,N-methylene bis acrylamide (MBA) were prepared by emulsion polymerization technique and were studied by Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS) and zeta potential measurement. Effect of pH, temperature and different salts concentration on the microgel particles was investigated. DLS results have shown that the hydrodynamic radius of the microgel increased upon increasing pH and decreased upon increasing temperature. The swelling/deswelling behaviors as determined by DLS showed the ionic repulsions of the carboxyl group of the methacrylic acid and hydrophobic interaction of NIPAM. The effect of various salts on volume phase transition temperature (VPTT) was also investigated. Upon increasing salt concentration, VPTT became broad and shifted to a lower temperature. Electrophoretic mobility measurements showed an increase with increasing pH and temperature at a constant ionic strength.

Nugget Formation and Dynamic Resistance in Resistance Spot Welding of Aluminum to Steel

  • Chang H. S.
    • International Journal of Korean Welding Society
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    • v.5 no.1
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    • pp.53-59
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    • 2005
  • Auto industry has employed resistance spot welding(RSW) to join steel sheets for structural rigidity of automobile body. Driven by the need to reduce weight and fuel consumption, car companies have been evaluating aluminum intensive vehicles(AIVs) as a way to reduce vehicle weight without downsizing. During the transition from all steel-construction vehicle body to aluminum intensive body, joining aluminum to steel sheets emerges as a serious contender in automobile body. This paper deals with application of transition material to RSW aluminum to steel. Placing transition material insert between the aluminum/steel interface was found very effective to overcome physical incompatibility between aluminum and steel. Use of transition insert allows for two separate weld nuggets to be formed in their respective aluminum/aluminum and steel/steel interfaces. This RSW processes was monitored with the aid of dynamic resistance sampling. Typical patterns in sampled dynamic resistance curves indicated formation of sound nugget. The growth of two separate nuggets was examined by micro-cross section test.

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A New Transition Criterion for Stratified and Nonstratified Flows in Pipes

  • Sung, Chang-Kyung;Chun, Moon-Hyun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.219-226
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    • 1996
  • A two-step approach has been used to obtain a new transition criterion for the stratified and nonstratified flow in horizontal pipe: (1) In the first step, a more general expression than the existing models for the flow transition criterion has been derived from the analysis of singular points and neutral stability conditions, or the parallel lines conditions of the transient one-dimensional two- phase flow equations of two-fluid model. (2) In the second step, introducing simplifications and incorporating a parameter into the general expression obtained in the first step to satisfy a number of physical conditions a priori specified, a new simple flow transition criterion for horizontal pipes has been derived. Comparison between results predicted by the present theory with the experimental data and theories in the pipe flow conditions, show good agreement.

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A Study on the transition planning case of transformation in Buildings (건축물의 공간변화에 따른 전이설계 사례에 관한 연구)

  • Do, Kyu-Hwan;Choi, Eui-Sun
    • Journal of The Korean Digital Architecture Interior Association
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    • v.4 no.1
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    • pp.17-25
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    • 2004
  • The architectural space is the involuntary place where man lives and experiences, and as a 3 dimensional space through the continuous experience with the concept of 4th dimension of time, it provides the observers with the dramatic space imagery. These kinds of space experiences are experienced mentally and perceptively through the physical elements of inner and outer space of the architectural buildings, and this space imagery is created here by all the space composing elemensts of the building. These space experiences are caused by the changing processes of the space characteristics, and the observers perceive the changes in space characteristics. These changing processes of inner and outer space, space versus space, and unit space, which are perceived by the observer, could be called as 'the transition' and thd changes of the space characteristics as 'the transition characteristics'.

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Velocity Oscillations in the Chromosphere and the Transition Region above Plage Regions

  • Kwak, Hannah;Chae, Jongchul
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.81.4-82
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    • 2017
  • We investigate velocity oscillations in the active region plage by using the high-spatial, high-spectral and high-temporal resolution spectral data acquired by the Interface Region Imaging Spectrograph (IRIS). From the Mn I $2801.907{\AA}$ (lower chromosphere), C II (lower transition region) and Si IV (middle transition region) lines, we measure the line of sight Doppler velocity at different atmospheric layers, and present results of wavelet analysis of the plage region with a range of periods from 2 to 8 minutes. In addition, we present correlations of the oscillations from the lower chromosphere to the middle transition region. Finally, we will discuss the regional dependence of the oscillation properties on physical properties such as temperature and magnetic field inclination.

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A Study on the transition planning case of transformation in Museum (박물관의 공간변화에 따른 전이설계 사례에 관한 연구)

  • Do, Kyu-Hwan;Choi, Eui-Sun
    • Journal of The Korean Digital Architecture Interior Association
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    • v.6 no.1
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    • pp.13-23
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    • 2006
  • The architectural space is the involuntary place where man lives and experiences, and as a 3 dimensional space through the continuous experience with the concept of 4th dimension of time, it provides the observers with the dramatic space imagery. These kinds of space experiences are experienced mentally and perceptively through the physical elements of inner and outer space of Museum, and this space imagery is created here by all the space composing elemensts of Museum. These space experiences are caused by the changing processes of the space characteristics, and the observers perceive the changes in space characteristics. These changing processes of inner and outer space, space versus space, and unit space, which are perceived by the observer, could be called as 'the transition' and the changes of the space characteristics as 'the transition characteristics'.

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Pressure Effects on Zircaloy-4 Steamside Corrosion and Hydrogen Pick-up

  • Ok, Young-kil;Kim, Yong-soo
    • Nuclear Engineering and Technology
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    • v.30 no.5
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    • pp.396-402
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    • 1998
  • Experiments on the steamside corrosion and hydrogen pick-up of Zircaloy-4 under high pressure up to 10.3MPa are carried out to estimate the pressure effects on the kinetics. Temperature and reaction time are determined to be 37$0^{\circ}C$ and 72hours for the pre-transition test and $700^{\circ}C$ and 210minutes for the post-transition test, respectively. Results show that under 10.3MPa pressure the oxidation reaction is 50% and 100% enhanced in the pre-and the post-transition regime, respectively. Total amount of hydrogen uptake in the reaction is proportionally increased as corrosion weight gain is elevated. However, pick-up fraction is not affected by the high pressure. The fraction is almost twice greater than that in the waterside corrosion. Edges in the specimens play a certain role in the enhancement, especially in the post-transition regime. To identify physical property changes of oxide film such as micro-cracks or micro-pores, careful and thorough examination must be needed with some special techniques.

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Preparation of Biodegradable Thermo-responsive Polyaspartamides with N-Isopropylamine Pendent Groups (I)

  • Moon, Jong-Rok;Kim, Ji-Heung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.1981-1984
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    • 2006
  • Novel amphiphilic, thermo-responsive polyaspartamides which showed both LCST (lower critical solution temperature), and sol-gel transition were prepared and characterized. The polyaspartamide derivatives were synthesized from polysuccinimide, the polycondensate of aspartic acid monomer, via successive nucleophilic ring-opening reaction by using dodecylamine and N-isopropylethylenediamine (NIPEDA). At the intermediate composition ranges, the dilute aqueous solution exhibited a thermally responsive phase separation due to the presence of LCST. The phase transition temperature was controllable by changing the content of pendent groups. In addition, a physical gelation, i.e. the sol-gel transition was observed from the concentrated solutions, which was elucidated by dynamic viscoelastic measurements. These novel injectable and thermo-responsive hydrogels have potential for various biomedical applications such as tissue engineering and current drug delivery system.

Investigation on 2D Transition Metal Chalcogenide Using Angular-Resolved Photoelectron Spectroscopy (각도분해 광전자 분광법을 이용한 2차원 전이금속 칼코겐 화합물의 전자구조 연구)

  • Park, Soohyung
    • Ceramist
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    • v.22 no.4
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    • pp.350-356
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    • 2019
  • Recently, transition metal dichalcogenide (TMDC) monolayers have been the subject of research exploring the physical phenomenon generated by low dimensionality and high symmetry. One of the keys to understanding new physical observations is the electronic band structure of 2D TMDCs. Angle-resolved photoelectron spectroscopy (ARPES) is, to this point, the best technique for obtaining information on the electronic structure of 2D TMDCs. However, through ARPES research, obtaining the long-range well-ordered single crystal samples always proves a challenging and obstacle presenting issue, which has been limiting towards measuring the electronic band structures of samples. This is particularly true in general 2D TMDCs cases. Here, we introduce the approach, with a mathematical framework, to overcome such ARPES limitations by employing the high level of symmetry of 2D TMDCs. Their high symmetry enables measurement of the clear and sharp electronic band dispersion, which is dominated by the band dispersion of single-crystal TMDCs along the two high symmetry directions Γ-K and Γ-M. In addition, we present two important studies and observations for the direct measuring of the exciton binding energy and charge transfer of 2D TMDCs, both being established by the above novel approach.

Investigation of Spin Reorientation in Ga Substituted Y-type Hexaferrite based on Mössbauer Spectroscopy

  • Lim, Jung Tae;Kim, Jeonghun;Kim, Chul Sung
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1708-1711
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    • 2018
  • The polycrystalline sample of $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ Y-type hexaferrite, doped with Ga-cation, was prepared by using the solid-state reaction method. The crystalline structure of sample was investigated by x-ray diffractometer (XRD), and the magnetic properties of sample were measured by vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ spectrometer. The crystal structure of prepared sample was determined to be rhombohedral with space group R-3m. From the temperature dependence of the magnetization curves under 100 Oe between 4.2 and 740 K, two temperature-dependent magnetic transitions occurred in the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample. $M{\ddot{o}}ssbauer$ spectra of the sample were analyzed at various temperatures ranging from 4.2 to 620 K, and the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample showed abrupt changes in $H_{hf}$ and $E_Q$ at 200 K, indicating the spin transition effect. We have also determined the magnetic transition temperature $T_C$, in addition to the temperature dependent magnetization and ZVC measurements.