• 제목/요약/키워드: physical and chemical properties

검색결과 2,930건 처리시간 0.03초

Physical Properties of Mercaptopyruvic-acid Layer Formed on Gold Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2611-2616
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    • 2011
  • We studied the physical properties of the mercaptopyruvic-acid layer formed on gold surfaces, which has the interactions with the titanium dioxide surface for design of gold- titanium dioxide distribution. Surface force measurements were performed, using the atomic force microscope (AFM), between the surfaces as a function of the salt concentration and pH value. The forces were analyzed with the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory, to evaluate the potential and charge density of the surfaces quantitatively for each salt concentration and each pH value. The difference in the properties reflected the effect of the isoelectric point on the surface forces. The forces were interpreted for the evaluation with the law of mass action and the ionizable groups on the surface. The salt concentration dependence of the surface properties, found from the measurement at pH 8.0, was consistent with the prediction from the law. It was found that the mercaptopyruvic-acid layer had higher values for the surface charge densities and potentials than the titanium dioxide surfaces at pH 8, which may be attributed to the ionized-functional-groups of the mercaptopyruvic-acid layer.

폴리비닐알콜과 이온성고분자로 제조된 나노분리막 (NANOFILTRATION MEMBRANES BASED ON POLY(VINYL ALCOHOL) AND IONIC POLYMERS)

  • 오남운;제갈종건;이규호
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 춘계 총회 및 학술발표회
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    • pp.124-126
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    • 1998
  • 1. INTRODUCTION : With good physical and chemical properties as a membrane material, poly(vinyl alcohol) (PVA) has been widely used for the preparation of several kinds of membranes for different applications. Considering such good physical chemical properties, some people have tried to use it for the formation of reverse osmosis (RO) membranes with a good chemical stability as well as high flux and high rejection rate. However, unfortunately, the performance of the RO membranes based on PVA has not been satisfactory yet. The PVA RO membranes thermally crosslinked have shown very low flux and relatively low salt rejection. In this experiment, ionic polymers such as sodium alginate and chitosan were used together with PVA to increase the nanofiltration performance of the PVA membranes.

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Relationship between Printability and Rheological Properties of UV-curable Flexographic Ink

  • Jeong, Kyoung-Mo;Koseki, Ken'ichi
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.209-213
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    • 2006
  • Relationship between printability and rheological properties of UV flexographic (flexo) inks were investigated. UV flexo suspensions of carbon black in liquid medium having various binding materials such as acylate pre-polymer, di/multi-functional monomer, and diluents, were used as sample inks. Inks were characterized on a rheometer in terms of steady and dynamic behaviors. To understand the rheological properties of UV flexo inks, we must determine the specific rheological properties of chemical and/or physical interactions of their components (pigments, functional monomers, and pre-polymers). In particular, we discussed the influence of multi-functional monomers and the relationship between the rheological properties and transient networks formed by carbon black. In this study, we investigated the interrelationships between rheological properties of UV flexo inks and chemical and/or physical interactions of their components. To investigate correlations between the printability and the rheological behaviors induced by interfacial interactions between ink compositions, we carried out rheological tests of UV ink suspensions. The results were compared with printing tests so as to find out the relationship between printability and rheological properties of ink.

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농산물 저온유통용 내수 골판지 상자의 제조 (제1보) -섬유의 종류, 습윤지력증강제 및 방습제 첨가에 따른 골판지 원지의 물리적 특성 - (Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(I) - Effects of Fiber Types, Wet Strength Agents and a Moisture-Proof Chemical on the Physical Properties of Base Papers for Corrugated Board Boxes -)

  • 조중연;민춘기;신준섭
    • 펄프종이기술
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    • 제35권2호
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    • pp.26-32
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    • 2003
  • For the purpose of manufacturing water-resistant corrugated board boxes for agricultural products in the cold chain system, the effects of fiber types, wet strength agents and a moisture-proof chemical on the properties of the base papers were investigated first. PAE(polyamide amine epichlorohydrin) showed better performance than MF(melamine formalde-hyde) over broad stock pH ranges, which was prefered as wet strength agent for the paper grade. When short fibers(AOCC, KOCC) were mixed with long fiber(UKP) in certain ratios, some physical properties of the paper made with mixed fibers were similar to those of the paper made with UKP only. Paper containing AOCC showed the biggest increase in water resistance when PAE was added to the stock. Synergistic effects in moisture-proof and some mechanical properties of paper were appeared when PAR was added internally, together with the coating of a moisture proof chemical on the sheets.

물성조사와 폴리머 시멘트 몰타르 제조를 통한 FRP폐기물의 재활용 기술개발 (Development of FRP Waste Recycling Technology by Property Invesitigation and Polymer Cement Mortar Manufacturing)

  • 김용섭
    • 대한조선학회논문집
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    • 제40권1호
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    • pp.55-62
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    • 2003
  • This study has investigated physical and chemical properties of FRP waste, has manufactured polymer cement mortar using a crushed waste with sand and has evaluated its capability to develop the economical waste recycling technology. The study has investigated tension strength, hardness test and impact test as physical properties and also thermogravimetric characteristics and analyzed infrared spectroscope as chemical properties. Then the study has manufactured polymer cement mortar and has analyzed how the FRP waste fine aggregate replacement ratio has an effect on compression strength. Noticing admixture can complement strength drop occurred by the FRP waste fine aggregate replacement, the study examined an optimum rate of admixture addition and its reaction through electron microscope photos.

Properties of Precursor Pitch Derived from Petroleum Residue

  • 유해일;이규동;권영배
    • 한국기계연구소 소보
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    • 통권15호
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    • pp.37-46
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    • 1985
  • Properties of Precursor pitch derived from petroleum residue were studied physical and chemical analysis method for investigation of production of pitch fiber. For preparing of those precursor pitches it was carried out a temperature and time variation experiment i reactor. It was demonstrated the precursor pitch prepared in this study to have a similar properties to Ashland precursor pitch capable of bulk mesophase formation from the results of the basic analysis, that is, molecular weight distribution, coking yield, carbon content, chemical composition, etc.

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전기로 및 전로슬래그 골재의 품질에 대한 고찰 (A Study on the Properties of Electric Arc Furnace Slag and Converter Slag Aggregate)

  • 유정훈;조영권;김관호;이준구;심종성;박철우
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.149-152
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    • 2006
  • In this paper, we researched and compared the properties of steel slag(is divided with electric arc furnace slag and converter slag) as concrete aggregate by measuring physical and chemical characteristics of it. The steel slag mainly contains SiO2 and CaO as the chemical composition. The reaction with water and a little of free CaO in the slag causes slag's volume to expanse. Therefore, we used several aging methods in order to decrease the characteristics of slag volume expansion. The physical properties of steel slag aggregate is researched and then the strength of concrete with the steel slag aggregate is measured.

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Silica와 Glass Fiber에 의한 Polychloroprene의 보강(補强) (Reinforcement of Polychloroprene by means of Silia and Glass Fiber)

  • 유종선;백남철
    • Elastomers and Composites
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    • 제23권3호
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    • pp.223-229
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    • 1988
  • The effect of triazine thiol derivative on the physical properties of silica-polychloroprene(CR) composites and glass fiber(MGF)-CR composites was investigated. Optimum cure time of the MGF composites filled with 2-dibuthylamino-4, 6-dithiol-s-triazine(DBT) was the fastest one, while maximum torque was the best in case of the silica composites filled with s-triazine-2,4,6-trithiol(TAT) on the Oscillating Disk Rheometer(ODR) test. Stress-strain curves of the composites showed that the physical properties such as 100% modulus, 300% modulus, tensile strength of the silica composites filled with DBT was very satisfactory and the silica composites filled with TAT was higher density of crosslinking than other crosslinked elastomer. In aging properties, elastomer filled DBT and TAT were progress post-curing reaction with increasing of aging time and it have been improved the tensile strength and crosslinking density.

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Analysis of the utilization of existing test data for phase-in substance registration under the Act on the Registration and Evaluation, etc. of Chemical Substances

  • Choi, Bong-In;Kwak, Yeong-Don;Jung, Yu-Mi;Ryu, Byung-Taek;Kim, Chang Gyun
    • Environmental Analysis Health and Toxicology
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    • 제30권sup호
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    • pp.4.1-4.7
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    • 2015
  • Objectives Approximately 2000 phase-in substances are subject to registration according to the Act on the Registration and Evaluation, etc. of Chemical Substances (K-REACH), and the expected testing cost is 2.06 trillion Korean won assuming all the test data required for registration are acquired. The extent to which these enormous test costs can be reduced depends on the availability of existing data that can be used to meet the requirements of the K-REACH we examined the current availability of test data that can be used for chemical substance registration. Methods We analyzed the possibility of utilizing the existing test data obtained from 16 reference databases for 369 of 518 kinds of phase-in substances subject to registration that were reported in last October 2014. Results The physical and chemical properties were available for 57.1% of substances, whereas data regarding human hazards and environmental hazards were available at considerably lower rates, 8.5% and 11.8%, respectively. Conclusions Physical and chemical properties were available for a fairly high proportion, whereas human hazards and environmental hazards were reported for considerably fewer substances.

감마선 조사처리가 지류의 물성에 미치는 영향 (The Effect of Gamma ray irradiation on Paper Properties)

  • 정혜영;최경화;박지희;정필문;최종일
    • 펄프종이기술
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    • 제42권3호
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    • pp.43-49
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    • 2010
  • Recently, the use of fumigants for pest control of paper cultural heritages are limited because of the high toxicity of fumigants and the production of environment-harmfully compounds. Therefore, many non-chemical methods have been discussed and experimented. And it is recently focused on gamma radiation, which is one of non-chemical methods, for pest control of paper cultural heritage in Korea. In this paper, we carried out a gamma ray irradiation of papers including Hanji, copy paper, filter paper and then analyzed a physical properties and optical properties of paper sample to estimate the effect of gamma ray irradiation on paper properties. In result, gamma radiation have adverse effect on a physical properties and optical properties of paper, especially Hanji. Therefore, we have to carefully consider about using of gamma ray for pest control of paper cultural heritages.