• Title/Summary/Keyword: photographic emulsion

Search Result 32, Processing Time 0.033 seconds

The Additive Effect of Polyoxyethylene Compounds on the Photographic Characters of Photographic Emulsion

  • Youn, Min-Young;Ahn, Hong-Chan;Kang, Tai-Sung
    • Journal of Photoscience
    • /
    • v.7 no.2
    • /
    • pp.45-46
    • /
    • 2000
  • The polyoxyethylene compounds were added into the photographic emulsion during the physical ripening of photo sensitive silver halide crystal in this emulsion. The polyoxyethylene compounds improved the photographic properties of the film to a great extent increasing the photo sensitivity and decreasing the fog density.

  • PDF

Spectral Sensitization and Photographic Characteristics of 9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-sulfopropyl)Benzoxazolo Carbocyanine Triethyl Ammonium Set (9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-sulfopropyl)Benzoxazolo Carbocyanine Triethyl Ammonium Salt의 분광증감과 사진특성)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
    • /
    • v.8 no.3
    • /
    • pp.51-56
    • /
    • 2005
  • In this paper, we describe a study on the relationship between spectral sensitization and photographic characteristics of color paper. The photographic emulsion used in this study is a green-sensitizing emulsion. U.V maximum absorption peak value of 9-phenyl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt was observed 507nm, and wedge spectrograms maximum peak value of color paper added dye to photographic emulsion was shown 553nm. As compared with the absorption peak of the dye in methanol solution, the sensitizing peaks of 9-phenyl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt have red shifts of 46nm. The photographic characteristics of green-sensitizing emulsion were obtained contrast(2.6), speed(48-57), fog(0.08). Therefore, benzoxazolo carbocyanine dye is of industrial importance as green-sensitizing dye in the spectral sensitization of photographic emulsion.

  • PDF

SPECTRAL SENSITIZATION OF BENZOXAZOLO CARBOCYANINE DYE IN PHOTOGRAPHIC EMULSION

  • Kim, Yeoung-Chan
    • Journal of Photoscience
    • /
    • v.5 no.1
    • /
    • pp.45-46
    • /
    • 1998
  • The green-sensitive silver halide emulsion layer has been studied UV-Vis absorption band of 9-methvl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt in methanol solution and 10% methanol containing 10$^{-2}$ M KCl. the products were observed at 502nm and 540nm(J-band), respectively. The maximum spectral sensitivity of sensntizing silver halide emulsion showed at 546nm. In conclusion, benzoxazolo carbocyanine dye can be used as a green-sensitizing dye for the photographic emulsion.

  • PDF

Studies on the Photographic Emulsion Manufacture for Color Paper and Hardening Test (천연색 인화지용 사진유제 제조와 경막 시험에 관한 연구)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
    • /
    • v.8 no.4
    • /
    • pp.43-50
    • /
    • 2005
  • In this paper, we describe a study on the relationship between photographic emulsion manufacture and hardening test of color paper. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The hardener used in this study is a 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt. The hardening test of photographic emulsion was studied respectively at pH 5.5, 7, 8.5 and about increasing temperature. Novel hardener can be used in photo-graphic emulsion of color paper and showed very good hardening effect.

  • PDF

Studies on the Hardening Test of Gelatin Emulsion Layers by Derivatives of Symmetrical Triazine (대칭적 Triazine 유도체들에 대한 젤라틴 유제층의 경막 시험에 관한 연구)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
    • /
    • v.9 no.1
    • /
    • pp.1-7
    • /
    • 2006
  • In this paper, we describe a study on the relationship between photographic emulsion manufacture and hardening test of films. The hardeners were prepared by condensation of equimolar amounts of trichlorotriazine with benzene- or naphthalene-based amino or oxy acids at 0 to 5$^{\circ}C$ and at pH 7, and used as hardening agents for gelatin. The hardening test of photographic emulsion was studied at pH 5.5. For example I(R=ONa) had strong hardening properties, I substituted with an aminobenzosulfonate moiety (R=$NHC_6H_4-p-SO_3Me$ where Me = K, Na) was a much weaker gelatin hardener, and when substituted with amino- or oxynaphthalene derivative (II, III) did not harden gelatin at all. Compound with 2 dichlorotriazine groups as IV exhibited strong hardening properties. The hardener can be used in photographic emulsion of film and showed very good hardening effect.

  • PDF

The Spectral Sensitization and the Photographic Characteristics of Sensitizing Dye for Photographic Emulsion (사진유제용 증감색소의 분광증감과 사진특성)

  • Kim, Yeoung-Chan;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
    • /
    • v.13 no.1
    • /
    • pp.87-98
    • /
    • 1996
  • In this study, benzoxazolo carbocyanine dye was used as sensitizer for photographic emulsion, and the photographic characteristics were examined. The basic properties of sensitizer such as stability in various solvents were examined. The sensitizer was very stable in methanol, acetonitrile, acetone, dimethylformamide, and chloroform solution. Absorption spectra of benzoxazolo carbocyanine dye $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride show the monomer-J-aggregation characteristics. Compared to the absorption peak of the monomer in pure methanol solution, the red shifts of the monomer-J-aggregate peaks of benzoxazolo carbocyanine dye of $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride are 34nm respectively, and the sensitizing peak of benzoxazolo carbocyanine dye in photographic emulsion has red shift of 34nm. Therefore, if was concluded that benzoxazolo carbocyanine dye can be used as green sensitizing dye for the spectral sensitization of photographic emulsion.

SPECTRAL SENSITIZATION AND PHOTOGRAPHIC CHARACTERISTICS OF NAPHTHOTHIAZOLO CARBOCYANINE DYE

  • Kim, Yeoung-Chan
    • Journal of Photoscience
    • /
    • v.3 no.2
    • /
    • pp.65-69
    • /
    • 1996
  • In this paper, it was studied about the red-sensitive layer. UV-Vis data of the dye at monomeric and J-state were considered with respect to their performance(contrast, density and fog) in photographic emulsion. The sensitizing effect of the dye is found to be strongly structuredependent. Naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

  • PDF

A Stability on the Solvents of Spectral Sensitizer for Photographic Emulsion (사진유제용 분광증감색소의 용매에 대한 안정성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.14 no.2
    • /
    • pp.65-70
    • /
    • 1997
  • The symmetric naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. The stability on the solvents of naphthothiazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then all of solvents were stabilized sensitizer. The maximum absorption peak range in various solvents was $600nm{\sim}612nm$. But it was identified that only methanol can be used to photographic emulsion.

A Study on the Photographic Characteristics and Crystalline Forms about Photographic Emulsion Prepared from Photographic Gelatine with Polyvinylpyrrolidone (사진용(寫眞用) 제라틴과 Polyvinylpyrrolidone으로 제조(製造)된 사진유제(寫眞乳劑)의 할로겐은(銀) 결정(結晶) 및 사진특성(寫眞特性) 연구(硏究))

  • Kang, Tai-Sung
    • Journal of radiological science and technology
    • /
    • v.1 no.1
    • /
    • pp.55-59
    • /
    • 1978
  • The photographic characteristics have been studied in relation with various molecular weights of Polyvinylpyrrolidone(PVP). The shape of silver halogen crystals by physical ripening of mixture of photographic gelatine and various molecular weights of PVP were observed. Then, the photographic characteristics have been studied by chemical ripening. Results were concluded as follows: 1. All of the crystals have formed in the shape of (100) or (111). 2. Photographic characteristics were inferior by using PVP of higher molecular weight. 3. Photographic characteristics were superior by using PVP of lower molecular weight. 4. Photographic characteristic were compared with various Emulsion thickness and Tested Resolving power.

  • PDF

Spectral Sensitization and Photographic Characteristics of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.366-371
    • /
    • 2003
  • In this paper, it was studied about the red-sensitive layer. UV-Vis data of the dye at monomeric and J-state were considered with respect to their performance(contrast, speed, density and fog) in photographic emulsion. The sensitizing effect of the dye is found to be strongly structure-dependent. Naphthctbiazolo carbocyanine dye can be used as red sensitizing dye for the spectral sensitization of photographic emulsion.