• 제목/요약/키워드: photochemical pollution

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CB4를 이용하여 부산 지역의 오존 전구 물질의 배출량에 대한 오존 농도의 민감도 (Sensitivity of Ozone Concentrations to Ozone Precursor Emissions In Busan Metropolitan Area Using the Carbon Bond Mechanism IV)

  • Lee, Hwa-Woon;Roh, Soon-A;Kim, Heon-Sook
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.362-363
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    • 2003

  • Photochemical ozone is formed from nitrogen oxides (NOx) and volatile organic compounds(VOCs) through non-linear interactions between chemical reactions and meteorology, and the relationship between precursors and photochemical ozone will be changed to match the emission distribution and meteorological fields. It is generally known that for some conditions the process of ozone formation is controlled almost entirely by NOx and is largely independent of VOC, while for other conditions ozone production increases with increasing VOC and does not increase(or sometimes even decreases) with increasing NOx (omitted)

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Air Pollution Trends in Japan between 1970 and 2012 and Impact of Urban Air Pollution Countermeasures

  • Wakamatsu, Shinji;Morikawa, Tazuko;Ito, Akiyoshi
    • Asian Journal of Atmospheric Environment
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    • 제7권4호
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    • pp.177-190
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    • 2013

  • Air pollution trends in Japan between 1970 and 2012 were analyzed, and the impact of air pollution countermeasures was evaluated. Concentrations of CO decreased from 1970 to 2012, and in 2012, the Japanese environmental quality standard (EQS) for CO was satisfied. Concentrations of $SO_2$ dropped markedly in the 1970s, owing to use of desulfurization technologies and low-sulfur heavy oil. Major reductions in the sulfur content of diesel fuel in the 1990s resulted in further decreases of $SO_2$ levels. In 2012, the EQS for $SO_2$ was satisfied at most air quality monitoring stations. Concentrations of $NO_2$ decreased from 1970 to 1985, but increased from 1985 to 1995. After 1995, $NO_2$ concentrations decreased, especially after 2006. In 2012, the EQS for $NO_2$ was satisfied at most air quality monitoring stations, except those alongside roads. The annual mean for the daily maximum concentrations of photochemical oxidants (OX) increased from 1980 to 2010, but after 2006, the $98^{th}$ percentile values of the OX concentrations decreased. In 2012, the EQS for OX was not satisfied at most air quality monitoring stations. Non-methane hydrocarbon (NMHC) concentrations generally decreased from 1976 to 2012. In 2011, NMHC concentrations near roads and in the general environment were nearly the same. The concentration of suspended particulate matter (SPM) generally decreased. In 2011, the EQS for SPM was satisfied at 69.2% of ambient air monitoring stations, and 72.9% of roadside air-monitoring stations. Impacts from mineral dust from continental Asia were especially pronounced in the western part of Japan in spring, and year-round variation was large. The concentration of $PM_{2.5}$ generally decreased, but the EQS for $PM_{2.5}$ is still not satisfied. The air pollution trends were closely synchronized with promulgation of regulations designed to limit pollutant emissions. Trans-boundary OX and $PM_{2.5}$ has become a big issue which contains global warming chemical species such as ozone and black carbon (so called SLCP: Short Lived Climate Pollutants). Cobeneficial reduction approach for these pollutants will be important to improve both in regional and global atmospheric environmental conditions.

  • https://doi.org/10.5572/ajae.2013.7.4.177 인용 PDF KSCI

광화학챔버를 이용한 오존발생 특성 연구 (Characteristics of Ozone Production in Photochemical Smog Chamber)

  • 홍유덕;한진석;공부주;이상욱;이석조;이덕길
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.171-173
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    • 2003

  • 광화학스모그 챔버의 성능을 평가하기 위하여 파장별 광도시험, 광원의 NO$_2$ 광분해 상수, pure air experiment 등 성능실험을 수행하고, VOCs 종류 및 VOCs/NOx 비가 오존생성 및 입자상물질의 생성에 미치는 영향과 온도, 습도가 오존생성에 미치는 영향 등을 평가하였다. (중략)

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하계 광화학모델을 이용한 수도권지역의 고농도 오존 사례 모사 (Photochemical Modeling for the Ozone Episode on Summer in Metropolitan Area)

  • 이종범;장명도
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.143-144
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    • 2003

  • 최근 서울을 포함한 수도권지역은 물론 그 지역의 풍하지역에서 조차도 오존오염이 지속적으로 악화되고 있는 실정이다. 이에 대해 보다 정확한 원인 규명 및 그에 따른 대책 수립을 위하여 많은 연구가 진행되고 있다. 광화학모델링은 오존오염의 원인 규명 및 대책수립을 위해 정확도 향상이 요구된다. 본 연구에서는 광화학모델인 MODELS-3/CMAQ(1999)을 적용하여 수도권지역에서 빈번히 발생하는 2002년 하계 오존 고농도 현상을 모사하였다. (중략)

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