• 제목/요약/키워드: photochemical pollution

검색결과 104건 처리시간 0.024초

김해공항 시정장애 원인의 통계적 분석 (On the Statistic Analysis to the Causes of the Poor Visibilities Occurring at Kimhae International Airport)

  • 진병화;황수진;박만성
    • 한국환경과학회지
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    • 제5권6호
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    • pp.719-725
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    • 1996
  • To research the cause of the low and the poor visibility phenomena of Kimhae international airpot statistically, we analyzed the field routine data for the last five years from 1985 to 1989. The poor visibilities below 1km, 3km, and 5km usually occurred at about 6 o'clock in the morning under the condition of calm or light wind from south to southwest direction, and lasted for from 1 to 3 hours. they were caused by the radiative cooling and the inflow of moisture from the South Sea. The frequency of th low visibility(below 9km) recorded 48.1% a year. And the low visibility below 8km with relative humidity below 70% often occurred in the case of southeast, southwest, and northwest wind. And it reveals a peak at 11:00 a.m.. It is supposed to be caused by the pollutants flowing from the neighbouring industrila complex, Sasang, Jangnim and by the photochemical reaction. And, when the industrial direction from Kimhae international airport, the visibility and the air pollution may become worse and worse by the increased pollutants.

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수도권 지역 대기 중 카보닐화합물의 시.공간적 농도 분포 특성 (Spatial and Temporal Variations of Atmospheric Concentrations of Carbonyl Compounds in Seoul Metropolitan Area)

  • 서영교;정은희;서석준;황윤정;한진석;백성옥
    • 한국대기환경학회지
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    • 제24권2호
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    • pp.206-219
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    • 2008
  • The purpose of this study is to evaluate concentrations of carbonyl compounds during summer season in Seoul metropolitan area. The air samples were collected at 7 sites in this area from June 2001 to June 2003. The carbonyl compounds were analyzed by DNPH/HPLC method. The analytical method applied in this study showed good repeatability, linearity, and sensitivity. The most abundant carbonyl was formaldehyde (average 4.48 ppb), and followed by acetone, acetaldehyde, methyl ethyl ketone, butyraldehyde, propionaldehyde and benzaldehyde, respectively. Concentrations of carbonyl compounds in June were higher than those in August. There was not only higher solar radiation but also higher ozone concentration in June than in August. As a result o photochemical reactions, carbonyl compounds from both primary and secondary sources are likely to contribute to the formation of ozone. The contributions to photochemical ozone creation of two carbonyl compounds such as formaldehyde and acetaldehyde were estimated to be about 70%. Ratios of formaldehyde to acetaldehyde in this study ranged from 1.13 to 4.26, which are generally equivalent levels to those of other urban areas in domestic and foreign countries.

부산 연안역의 오존 농도에 미치는 해풍의 영향 (The Influences of 5ea Breeze on Surface Ozone Concentration in Pusan Coastal Area, Korea)

  • 김유근;이화운
    • 한국환경과학회지
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    • 제5권3호
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    • pp.265-275
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    • 1996
  • Air pollution characteristics and the influence of sea breeze on surface ozone concentration were studied using the data measured at 7 air quality continuous monitoring stations from June to September using 3 years (1990, 1993, 1994) in Pusan coastal area. Among the 246 sea breeze days for research Period, there were approximately 89 sea breeze days (36%) from lune to September, And there were 120 the episode days (68%) of ozone greater than or equal to 60 ppb in summer season. In 89 sea breeze days, the episode day was highly marked as 56 days (63%). So, we knew that the sea breeze greatly affects the occurence of ozone episode day. the ozone concentration under the condition of the sea breeze increase about 40% in the daytime. Frequencies distribution of $O_3$ concentration for sea breeze moved toward high concentration class. The characteristics of ozone concentration in relation to meteorological conditions of sea breeze is significant because we can discover major weather factors for eastablishing an air pollution- weather forecast system. For further. study about meterological approach method for photochemical air pollution, it is necessary to explain the characteristics of atmosphere below 1, 000 m, especially concerning the formation mechanism of inversion layers. And finally, we will study the relationships to synoptic weather conditions and vertical structure and diurnal variation of local wind systems including sea breeze, and the vertical movements of atmosphere in the city.

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도시의 대기오염과 시정감소에 관하여 (On Relationship of Low Visibility to Air Pollution in Cities)

  • 정용승;김태군;정재섭
    • 한국대기환경학회지
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    • 제8권1호
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    • pp.1-6
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    • 1992
  • Using data measured in 1989, a study on variations of visibility and air pollution observed in Seoul, Chongju and Choopoongryong is carried out. Analysis includes on low visibility (< 10km) and smog occurring in the Metropolitan Seoul. It was observed that number of days of visibility less than 10km during 1989 was 56.7% (207 days) for Seoul, 45.7%(167 days) for Chongju and 5.8% (21 days) for Choopoongryong. Chongju is a medium size city (population : a half million) and Choopoongryong is a rural site. In the urban are as, however, the number of low visibility days was relatively large during the winter but with little seasonal variations. In each month these cities recorded more than 10 days of low visibility. The visibility reduction due to mist, fog and haze been occurred with air pollution. In particular, the reduction in a cold season related with an increase in high concentrations of $SO_x$ and aerosols. This type of low visibility occurring in Seoul is a similar type that is occurring in London, U.K. On the other hand, the visibility reduction during in a warm season is related with high concentrations of NOx and other photochemical precursors. The visibility reduction in Seoul during summer is the same type occurring in Los Angeles, U.S.A.

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김해지방의 대기오염 특성 (Characteristics of Air Pollution at Kimhae)

  • 박종길;김종필;김지형
    • 한국환경과학회지
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    • 제8권1호
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    • pp.33-43
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    • 1999
  • This paper aims to describe the characteristics of air pollution using air pollutants concentration and meteorological data observed at Kimhae from December 1996 to November, 1997. The results are as follows : The concentration distribution of sulfur dioxide($SO_2$), carbon monoxide(CO), particulate matter(PM-10), and nitrogen dioxide($NO_2$) is high during the late fall and winter and low during the summer, but ozone concentration is low during the winter season and high during summer season except Jangma period and these distributions appear to be closely connected with insolation and the number of clear day. Diurnal variation of concentrations for sulfur dioxide, particulate matter, and carbon monoxide are high during the rush hours and nighttime and low during the daytime and these variations are distinct toward the winter season. And diurnal variation of nitrogen dioxide concentration has also same pattern and these patterns are closely related to the increasing traffic volume at rush hours. Diurnal variation of ozone concentration is generally increase for daytime and decrease for the late afternoon and are closely related to the insolation and photochemical reaction. The 24 hour average concentrations of air pollutant observed at Kimhae represented a positive correlation and a negative correlation for $O_3$ and also a negative correlation for the meteorological elements such as wind speed and cloud cover.

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A Commentary on Air Pollution Monitoring Programs in Korea

  • Ghim, Young-Sung;Kim, Jin-Young;Shim, Shang-Gyoo;Moon, Kill-Choo
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E1호
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    • pp.21-28
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    • 2002
  • Air quality issues in Korea rapidly changed at the beginning of the 1990s from primary to secondary pollutants starting in Seoul, the capital of Korea. The present frame of national air pollution monitoring networks was established between the end of the 1980s and the beginning of the 1990s. Background monitoring was initiated in the middle of the 1990s in response to increasing public concern about the long-range transport of air pollutants. Apart from the national monitoring, both routine and intensive measurements of fine particles have been made for research purposes since the middle of the 1990s at several background sites. However, air pollution monitoring in urban areas for other purposes was relatively scarce as national monitoring has been concentrated in these areas. Although ozone pollution has become a significant issue in major metropolitan areas every summer, only a little information on ozone precursors is available. During the past few years, the number of national monitoring stations has greatly increased. The government has a plan to gradually expand monitoring items as well as stations. It is anticipated that highly detailed information on both photochemical reactants and products will be available within the next several years. More emphasis will be placed on toxic substances based on risk assessment in monitoring for both research and policy making.

Fabrication and characteristics of NOx gas sensors using WO3 and In2O3 thick films to monitor air pollution

  • 손명우;최정범;황학인;유광수
    • 센서학회지
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    • 제18권4호
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    • pp.263-268
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    • 2009
  • With the increasing number of automobiles, the problem of air pollution from the exhaust gases of automobiles has become a critical issue. The principal gases that cause air pollution are nitrogen oxide or NO$_x$(NO and NO$_2$), and CO. Because NO$_x$ gases cause acid rain and global warming and produce ozone(O$_3$) that leads to serious metropolitan smog from photochemical reaction, they must be detected and reduced. Mixtures of WO$_3$ and $In_2O_3$(WO$_3$:$In_2O_3$=10:0, 7:3, 5:5, 3:7, and 0:10 in wt.%), which are NO$_x$ gas-sensing materials, were prepared, and thick-film gas sensors that included a heater and a temperature sensor were fabricated. Their sensitivity to NO$_x$ was measured at 250$\sim$400$^{\circ}C$ for NO$_x$ concentrations of 1$\sim$5 ppm. The $In_2O_3$ thick-film sensor showed excellent sensitivity($R_{gas}/R_{air}$=10.22) at 300$^{\circ}C$ to 5-ppm NO. The response time for 70 % saturated sensitivity was about 3 seconds, and the sensors exhibited very fast reactivity to NO$_x$.

Analysis of Tropospheric Carbon Monoxide using MOPITT data

  • Lee, Sang-Hee;Park, Gi-Hyuk;Lim, Hyo-Suk;Lee, Joo-Hee
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2002년도 Proceedings of International Symposium on Remote Sensing
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    • pp.373-377
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    • 2002
  • The Measurement of Pollution in the Troposphere (MOPITT) instrument is an eight-channel gas correlation radiometer launched on the Earth Observing System (EOS) Terra spacecraft in 1999. Its main objectives are to measure carbon monoxide (CO) and methane (CH4) concentrations in the troposphere. This work analyzes tropospheric carbon monoxide distributions using MOPITT data in East Asia and compared ozone distributions. In general, seasonal CO variations are characterized by a spring peak and decreased in the summer. Also, this work revealed that the seasonal cycles of CO are spring maximum and summer minimum with averaged concentrations ranging from 118ppbv to 170ppbv. The CO monthly means show a similar profiles to those of O3. This fact clearly indicates that the high concentration of CO in spring is caused by two possible causes: the photochemical CO production in the troposphere, transport of the CO in the northeast Asia. The CO and O3 seasonal cycles in northeast Asia are influenced extensively by the seasonal exchange of the different types of air mass due to the Asian monsoon. The continental air masses contain high concentrations of O3 and CO due to higher continental background concentrations and sometimes due to the contribution of regional pollution. In summer the transport pattern is reversed. The Pacific marine air masses prevail over Korea, so that the marine air masses bring low concentrations of CO and O3, which tend to give the apparent minimum in summer.

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Spatiotemporal variations and source apportionment of NOx, SO2, and O3 emissions around heavily industrial locality

  • Al-Harbi, Meshari;Al-majed, Abdulrahman;Abahussain, Asma
    • Environmental Engineering Research
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    • 제25권2호
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    • pp.147-162
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    • 2020
  • The main objective of this study is to estimate the levels of pollution to which the community is presently exposed and to model the regimes of local air quality. Diurnal, daily, and monthly variations of NO, NO2, SO2, and O3 were thoroughly investigated in three areas; namely, residential, industrial, and terminal in Ras Al-Khafji. There is obvious diurnal variation in the concentration of these pollutants that clearly follows the diurnal variation of atmospheric temperature and main anthropogenic and industrial activities. Correlation analysis showed that meteorological conditions play a vital role in shaping the pattern and transportation of air pollutants and photochemical processes affecting O3 formation and destruction. Bivariate polar plots, an effective graphical tool that utilizes air pollutant concentrations' dependence on wind speed and wind direction, were used to identify prevailing emission sources. Non-buoyant ground-level sources like domestic heating and street transport emissions, various industrial stacks, and airport-related activities were considered dominant emission sources in observatory sites. This study offers valuable and detailed information on the status of air quality, which has considerable, quantifiable, and important public health benefits.

실내 스모그 챔버를 이용한 톨루엔/$NO_x$ 광화학 반응 현상의 관찰 (Photooxidation Reaction of Toluene/$NO_x$ Mixture in an Indoor Smog Chamber)

  • 이영미;이승복;배귀남;김민철;문길주;박주연;김용표
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.167-168
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    • 2003
  • 광화학 스모그는 대기 중으로 배출된 일차 오염물질인 /NO$_{x}$와 휘발성 유기화합물(volatile organic compounds)이 햇빛에 의해 반응하여 오존과 그외 다른 광화학 물질들을(photochemical oxidants) 생성시키는 현상이다. 서울의 경우 이런 VOCs 중에서 가장 많은 양을 차지하는 톨루엔은 광화학 반응을 통해 이차 유기 에어로졸(secondary organic aerosols)을 생성하는 능력이 매우 높은 방향족 화합물이다(Na and Kim, 2001). 지금까지 톨루엔의 이차 유기 에어로졸 생성에 관한 연구와 다른 방향족 탄화수소에 관한 연구가 스모그 챔버 실험을 통해 많이 이루어져 왔다. (중략)

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