• Journal of Environmental Science International
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• v.6 no.4
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• pp.351-357
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• 1997

In the Atmosphere under the various physical and chemical condition different chemical reactions occur and there are a number of air pollutants which are generated by photochemical reaction by absorbing solar energy. Therefor various testing simulation was done as foundation work to develop the numerical model for the prediction of concentration of air pollutants. It was shown change of msjor air pollutants concentration In according to variation of photodissociation speed constant, Kl and Initial condition of air pollutants concentration which plays major role In photochemical reaction. The photochemical reaction model which was used In this study Is found to be useful for understanding relationship among the concentration of reacting air pollutants and the prediction of concentration of air pollutants in urban atmosphere.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.2
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• pp.197-206
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• 2007

There are several methods for the hydrogen production such as steam reforming of natural gas, photochemical method, biological method, electrolysis and thermochemical method, etc. Many researches have been widely performed for the hydrogen production method having low production cost and high efficiency. In this paper, the patents concerning the photochemical hydrogen production method were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2005. Patents were gathered by using key-words searching and filtered by filtering criteria. The patent application trend was analyzed by the years, countries, companies, and technologies.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.3
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• pp.361-371
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• 2006

This study examines ozone episodes occurred during the intensive sampling periods (Jun. 1-30, 2004) in the air of Seoul metropolitan area. During that period, there were 8 events (or days) in which 1 hr averaged ozone concentrations were greater than 100 ppbv. The photochemical analysis of ozone chemistry (i.e., budget and formation and destruction strengths of ozone) was carried out using a photochemical box model. Peaks in diurnal ozone variations during ozone episode periods occurred were concurrent with the sudden change of the slope of $NO_{2}/NO$ ratio, suggesting significant correlation with photochemical reactivity. In addition, the ozone peaks were concurrent with high concentrations of ozone precursors, peroxy radicals of $HO_{2},\;CH_{3}O_{2},\;and\;RO_{2}$. High ozone levels during the ozone episodes are likely to be affected by ozone destruction rate.

• Bulletin of the Korean Chemical Society
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• v.26 no.8
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• pp.1190-1196
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• 2005

Halopyrroles, N-substituted 2-halopyrroles were prepared by halogenation of N-substituted pyrroles with NBS, NCS, or surfuryl chloride. N-Substituted 3-halopyrroles were synthesized by acid-catalyzed thermal and photochemical isomerization reactions of N-substituted 2-halopyrroles. Both the thermal and photochemical reactions were acid-catalyzed. For the acid-catalyzed isomerization, a mechanism of [1,3] bromine shift followed by deprotonation is operated. For the acid-catalyzed photoisomerization, an excited triplet state of 2-protonated N-benzyl-2-halopyrrole produces an intermediate N-substituted pyrrole complex with halonium ion which is equilibrated with N-substituted pyrrole plus halonium ion, and then the halonium ion newly adds to 3-position of N-substituted pyrrole followed by deprotonation to afford N-benzyl-3-halopyrrole.

• Bulletin of the Korean Chemical Society
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• v.24 no.11
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• pp.1618-1622
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• 2003

The photochemical reactions of methanolic nalidixic acid (NAL) solution in the absence and in the presence of air have been investigated using 300 nm UV light. From the reactions, 1-ethyl-7-methyl-4-oxo-4-hydro-1,8-naphthyridine (EMDN),formic acid, and formaldehyde are produced. In the presence of air, hydrogen peroxide is also detected along with the products listed above. The presence of oxygen during the irradiation of methanolic NAL solution effects on the product yield. The initial quantum yields of the products and of the NAL decomposition are determined. Possible reaction pathways for the photochemical reaction are suggested on the basis of the products analysis.

• Journal of Photoscience
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• v.9 no.3
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• pp.57-63
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• 2002

A homopolymer containing anthracene groups, poly[6-(9-anthryloxy)hexyl methacrylate] (PAn) was prepared and the effect of oxygen on its photochemical reaction was studied by UV and IR absorption spectroscopy in order to understand its photochemical behavior. Photochemical reaction of the PAn in THF solution under an atmosphere of air resulted in the formation of endoperoxide at the beginning stage of reaction followed by photodimerization reaction after all the oxygen was consumed, whereas photodimerization and endoperoxide formation took place concomitantly in the film state. The photoreversible reaction of the anthracene photodimer groups in the polymer by photolysis with 254 nm UV light was not efficient. The IR absorption spectral changes of the PAn film upon irradiation indicate that various photooxidation products were produced in the atmosphere of air.

• Proceedings of the Korea Society of Environmental Biology Conference
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• 2000.11a
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• pp.21-21
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• 2000

• Journal of the Microelectronics and Packaging Society
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• v.27 no.4
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• pp.77-81
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• 2020

Resistive RAM (ReRAM) is a strong candidate for the next-generation nonvolatile memories which use the resistive switching characteristic of transition metal oxides. The resistive switching behaviors originate from the redistribution of oxygen vacancies inside of the oxide film by applied programming voltage. Therefore, controlling the oxygen vacancy inside transition metal oxide film is most important to obtain and control the resistive switching characteristic. In this study, we introduced an applying electric field into photochemical metal-organic deposition (PMOD) process to control the oxidation state of metal oxide thin film during the photochemical reaction by UV exposure. As a result, the surface oxidation state of FeOx film could be successfully controlled by the electric field-assisted PMOD (EFAPMOD), and the controlled oxidation states were confirmed by x-ray photoelectron spectroscopy (XPS) I-V characteristic. And the resistive switching characteristics with the oxidation-state of the surface region could be controlled effectively by adjusting an electric field during EFAPMOD process.

• YAKHAK HOEJI
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• v.44 no.1
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• pp.36-40
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• 2000

The photodegradation of pefloxacin, photolabile fluoroquinolone antibacterial agent, was studied. In the presence of $N_2$, photodegradation of pefloxacin was suppressed. The singlet oxygen and free radical generated in the reaction media proceeded photochemical reaction. The photodegradation of peflxacin was sensitized by benzophenone, a triplet state sensitizer.

• Journal of Photoscience
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• v.10 no.1
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• pp.49-60
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• 2003

How stereo selectivity in singlet and triplet photocycloaddition and photocyclization reactions, respectively, is linked to spin selectivity and how this link affects our understanding of photochemical reaction mechanisms, is described in this review. As illustrative examples, the Paterno-Buchi reaction and the Norrish-Yang cyclization are described with emphasis on triplet biradical structure and dynamics.