• Title/Summary/Keyword: photocatalyst

Search Result 675, Processing Time 0.025 seconds

Removal Characteristics of Toluene by the Combined Plasma/Photocatalyst System (플라즈마/광촉매 결합시스템에 의한 톨루엔 제거특성)

  • Yoa, S.J.;Heo, Y.S.
    • Journal of Power System Engineering
    • /
    • v.11 no.2
    • /
    • pp.64-71
    • /
    • 2007
  • The main purpose of this study is to analyze the characteristics of toluene removal by plasma, photocatalyst, and plasma/photocatalyst system with the major parameters such as flow rate, inlet toluene concentration and applied voltage, etc., experimentally. In the combined plasma/photocatalyst process, rates of toluene conversion are represented as 99% at flow rate 250, 500 mL/min while, below 97% at flow rate 1000 mL/min due to the low residence time(reaction time) at the same applied voltage 4173 voltage and toluene inlet concentration 50 ppm. The intermediate products are detected by GC/MS analysis showing the small amounts of benzoic acid, benzyl alcohol and residual ozone concentration $0.04{\sim}0.05$ ppm generated by plasma process in the present system.

  • PDF

A Study on the Reduction of VOCs Generated from Vehicle Interior Parts and Materials Using Visible-light Responsive Photocatalyst (가시광촉매를 이용한 자동차 내장재로부터 발생하는 VOCs의 저감연구)

  • Choi, Sei-Young;Yang, Seung-Gi
    • Elastomers and Composites
    • /
    • v.48 no.3
    • /
    • pp.209-215
    • /
    • 2013
  • On this study, visible-light responsive photocatalyst prepared by sol-gel method was evaluated the effect of the reduction of volatile organic compounds (VOCs) occurred in vehicle interior and its property was examined. According to UV/visible result, visible-light responsive photocatalyst was found that the UV-visible peak is red shift at 420nm, is sensitive in the visible light region. With vehicle interior parts and materials coated visible-light responsive photocatalyst, VOCs was measured by GC/MS. Measuring the VOCs generated from vehicle interior parts and materials, the reduction of VOCs was confirmed.

The photo-removal characteristic of VOCs by photocatalyst/scoria/loess concrete (광촉매가 첨가된 스코리아/황토/콘크리트의 VOCs 제거특성)

  • Ko, Seong-Hyun;Lee, Jae-Hoon;Hong, Chong-Hyun;Ryu, Seong-Phil;Kim, Moon-Hoon;Moon, Kyung-Jong
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2006.05b
    • /
    • pp.585-588
    • /
    • 2006
  • The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

  • PDF

Study of Inorganic Photocatalyst Media for Reused Wastewater (폐수 재이용을 위한 무기계 광촉매 담체 연구)

  • Lee, Gyuyoung;Kim, Jungchul;Lim, Jihyun;Lee, Junwoo;Park, Jeongmi;Lee, Seunghun;Nam, Jukyung;Lee, Yong-Woo
    • Journal of Korean Society on Water Environment
    • /
    • v.31 no.1
    • /
    • pp.42-48
    • /
    • 2015
  • This study focused on effective decomposition methods for low concentrated organic compounds from the reuse of industrial wastewater, and confirmed the possibility through photocatalyst media. Photocatalyst immobilized media was developed to carry on this experiment which confirmed the removal possibility of low concentrated organic compounds. Considering the stability and efficiency of photocatalyst immobilization, inorganic support, hollow bead, and $TiO_2$ nano powder were used. As a result of the removal experiment, the removal efficiencies of acetonitrile, ethanol, IPA(Isopropyl alcohol), methanol were above 75% after 15 minutes while those of acetone, acetaldehyde, urea were 10%, 45%, 20%, respectively after 60 minutes. If further studies were made to increase the surface area of the photocatalyst immobilized media, the efficiency of the removal of low concentrated organic compounds can be improved and this solution can also be used in an actual treatment process.

A study on the photocatalyst filter design using UV-C (UV-C를 이용한 광촉매 필터 디자인에 관한 연구)

  • Han, Sang Yun;Kang, Seung Min
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.29 no.6
    • /
    • pp.276-282
    • /
    • 2019
  • The purpose of this study was to analyze the structure of general filter using ultrafine filter (Profilter), dust collector filter, HEPA (HAPA-High Efficiency Particulate Air) filter, deodorized filters, etc. of air purifiers and to study new types of purified filters that can improve ultrafine dust, harmful gases, and sterilization cleanup performance. The study was also conducted by adding photocatalyst filters to the existing step-by-step filtration filter types, which were proposed in the design three coupling structure filters of the left and right UV-LED installation frames and the photocatalyst coating honeycomb frame. Future research is needed on the effect of photocatalyst filters. This study was to investigate the application and structure of photocatalyst filters to air purifiers.

A Study of Hydrocarbon Reduction with Photocatalysts (광촉매를 이용한 탄화수소 저감 연구)

  • 손건석;고성혁;김대중;이귀영
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.8 no.5
    • /
    • pp.47-53
    • /
    • 2000
  • To overcome the shortage of conventional TWC that is activated at high temperature, higher than 25$0^{\circ}C$, photocatalyst is considered as an new technology. Because the photocatalytic reaction of photocatalyst is not a thermo mechanical reaction, it is necessary to heat the system to start the reaction. It can be activated just by ultra violet light that includes wavelengths shorter than 400 nanometers even at ambient temperature. In this study photocatalytic reduction of hydrocarbon was investigated with a model gas test. To understand the effects of co-existence gases on the hydrocarbon reduction by photoreaction, CO and NO, $O_2, H_2O$ gases those are components of exhaust gases of gasoline engine are supplied with C3H8/N2 to a photoreactor. The photoreactor contains $TiO_2$ photocatalyst powders and a UV bulb. The results show that oxygen is the most important factor to reduce HC emission with photocatalyst. Photocatalyst seems to have a good probability for automotive application to reduce cold start HC emissions.

  • PDF

CO2 Reduction and C2H4 Production Using Nanostructured Gallium Oxide Photocatalyst (산화갈륨 나노구조 광촉매 특성을 이용한 이산화탄소 저감 및 에틸렌 생성 작용)

  • Seo, Dahee;Ryou, Heejoong;Seo, Jong Hyun;Hwang, Wan Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.35 no.3
    • /
    • pp.308-310
    • /
    • 2022
  • Ultrawide bandgap gallium oxide (Ga2O3) semiconductors are known to have excellent photocatalytic properties due to their high redox potential. In this study, CO2 reduction is demonstrated using nanostructured Ga2O3 photocatalyst under ultraviolet (254 nm) light source conditions. After the CO2 reduction, C2H4 remained as a by-product in this work. Nanostructured Ga2O3 photocatalyst also showed an excellent endurance characteristic. Photogenerated electron-hole pairs boosted the CO2 reduction to C2H4 via nanostructured Ga2O3 photocatalyst, which is attributed to the ultrawide and almost direct bandgap characteristics of the gallium oxide semiconductor. The findings in this work could expedite the realization of CO2 reduction and a simultaneous C2H4 production using a low cost and high performance photocatalyst.

Promoting Effect of MgO in the Photodegradation of Methylene Blue Over MgO/MWCNT/TiO2 Photocatalyst

  • Chen, Ming-Liang;Zhang, Feng-Jun;Oh, Won-Chun
    • Korean Journal of Materials Research
    • /
    • v.20 no.7
    • /
    • pp.345-350
    • /
    • 2010
  • For the present paper, we prepared MgO/MWCNT/$TiO_2$ photocatalyst by using multi-walled carbon nanotubes (MWCNTs) pre-oxidized by m-chlorperbenzoic acid (MCPBA) with magnesium acetate tetrahydrate $(Mg(CH_2COO)_2\cdot4H_2O)$ and titanium n-butoxide $(Ti\{OC(CH_3)_3\}_4)$ as magnesium and titanium precursors. The prepared photocatalyst was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The decomposition of methylene blue (MB) solution was determined under irradiation of ultraviolet (UV) light. The XRD results show that the MgO/MWCNT/$TiO_2$ photocatalyst have cubic MgO structure and anatase $TiO_2$ structure. The porous structure and the $TiO_2$ agglomerate coated on the MgO/MWCNT composite can be observed in SEM images. The Mg, O, Ti and C elements can be also observed in MgO/MWCNT/$TiO_2$ photocatalyst from EDX results. The results of photodegradation of MB solution under UV light show that the concentration of MB solution decreased with an increase of UV irradiation time for all of the samples. Also, the MgO/MWCNT/$TiO_2$ photocatalyst has the best photocatalytic activity among these samples. It can be considered that the MgO/MWCNT/$TiO_2$ photocatalyst had a combined effect, the effect of MWCNT, which could absorb UV light to create photoinduced electrons $(e^-)$, and the electron trapping effect of MgO, which resulted in an increase of the photocatalytic activity of $TiO_2$.

Antifungal Properties of Self-actuated Photocatalyst Coated PU Foam (자기구동형 광촉매 코팅에 의한 PU발포체의 항곰팡이 특성)

  • Choi, Sei Young
    • Elastomers and Composites
    • /
    • v.49 no.4
    • /
    • pp.341-345
    • /
    • 2014
  • In this study, self-actuated photocatalyst that titanium dioxide doped by more than two transition metal was coated PU foam. The antibacterial and antifungal activity of self-actuated photocatalyst coated PU foam was characterized without light. The antibacterial property of self-actuated photocatalyst coated PU foam was shown to be reduced more than 96%, and the antifungal property was shown to be reduced more than 99.9%. The durability of self-actuated photocatalyst coated PU foam tested by Weather-O-meter showed the 7% reduction of formaldehyde decomposition from 96.5% before test to 89.8% after test. The observation of surface of PU foam coated with self-actuated photocatalyst showed that the catalyst was firmly attached to the surface of polyester fiber without separation.