• 제목/요약/키워드: photo-response

검색결과 180건 처리시간 0.024초

폴리이미드막 표면에 직선 편광된 UV광 조사에 의한 프리틸트각 발생과 전기광학특성 (Pretilt Angle Generation and EO Performance in MLC with Polarized UV Light Irradiation Polyimide surface)

  • 서대식;이정호;이창훈
    • 한국전기전자재료학회논문지
    • /
    • 제11권10호
    • /
    • pp.878-884
    • /
    • 1998
  • We have investigated that the monodomain alignment of nematic liquid crystal (NLC) is obtained with polarized ultraviolet(PUV) light irradiation on polyimide (PI) surface. The LC alignment capability increases with increasing the UV light irradiation time. The polarized UV light irradiation on oblique angle of 60。 irradiated on PI surface rotated by 90。 at 10 min. after being normally irradiated on PI surface at 30 min., the generated pretilt angle of NLC is about 2.5。. The pretilt angle of NLC is attributed to the interaction between the LC molecules and the asymmetric triangular structure of polymer surface due to photo-depolymerization of polymer with the oblique UV light on PI surface. The voltage -transmittance and response time characteristics of photo-aligned twisted nematic (TN)-LCD with UV light irradiation time 60 min. were almost same in comparison with the rubbing-treated TN-LCD.

  • PDF

Construction of a 2D Co(II) Coordination Polymer with (4,4)-Connected Topology: Synthesis, Crystal Structure, and Surface Photo-electric Property

  • Li, Jia-Ming
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권4호
    • /
    • pp.1177-1181
    • /
    • 2014
  • A 2D grid-like (4, 4)-connected topology coordination polymer, $[Co(BTA)_2(H_2O)_2]_n$ (1), where HBTA = 2-(1H-benzotriazol-1-yl)acetic acid, has been synthesized by hydrothermal method and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and surface photovoltage spectroscopy (SPS). X-ray diffraction analyses indicated that 1 displays octahedral metal centers with secondary building units (SBUs) [$Co(BTA)_2(H_2O)_2$] bridged by the $BTA^-$ ligands. In the crystal, the 2D supramolecular architecture is further supported by $O-H{\cdots}O$, $O-H{\cdots}N$, $C-H{\cdots}O$ hydrogen bonds and ${\pi}{\cdots}{\pi}$ stacking interactions. The SPS of polymer 1 indicates that there are positive response bands in the range of 300-600 nm showing photo-electric conversion properties. There are good relationships between SPS and UV-Vis spectra.

Analysis of photothermal response in a two-dimensional semiconducting material thermally excited by pulse heat flux

  • Saeed, Tareq;Abbas, Ibrahim
    • Structural Engineering and Mechanics
    • /
    • 제82권4호
    • /
    • pp.469-476
    • /
    • 2022
  • A mathematical model of Lord-Shulman photo-thermal theorem induced by pulse heat flux is presented to study the propagations waves for plasma, thermal and elastic in two-dimensional semiconductor materials. The medium is assumed initially quiescent. By using Laplace-Fourier transforms with the eigenvalue method, the variables are obtained analytically. A semiconductor medium such as silicon is investigated. The displacements, stresses, the carrier density and temperature distributions are calculated numerically and clarified graphically. The outcomes show that thermal relaxation time has varying degrees of effects on the studying fields.

Photo-Fenton 산화공정에서 반응표면분석법을 이용한 축산폐수의 COD 처리조건 최적화 및 예측식 수립 (Optimization and Development of Prediction Model on the Removal Condition of Livestock Wastewater using a Response Surface Method in the Photo-Fenton Oxidation Process)

  • 조일형;장순웅;이시진
    • 대한환경공학회지
    • /
    • 제30권6호
    • /
    • pp.642-652
    • /
    • 2008
  • 본 연구는 축산폐수 중 COD$_{Cr}$을 응집공정 후 Photo-Fenton 공정에 의해 산화분해 최적조건 및 제거 예측식에 수립에 관한 연구이다. 본 연구는 축산폐수 중 COD$_{Cr}$에 대한 Photo-Fenton 산화반응을 이용하여 이들 분해특성을 2차원 반응모델로 추정하기 위해 중심합설계법 대안으로 많이 사용되고 있는 박스-벤켄법(Box-Behnken method)을 이용하였다. 최적조건 수립을 위한 입력변수, 즉 3가지 변수(Fe(II)(x$_1$), $H_2O_2(x_2)$, pH(x$_3$)) 등을 램덤화, 반복화 및 블록화 원리에 따라 실험설계하여 반응값에 대한 예측식을 수학적으로 산출하였다. 수학적 및 통계적으로 산출된 예측식은 Y = 79.3 + 15.61x$_1$ - 7.31x$_2$ - 4.26x$_3$ - 18x$_1{^2}$ - 10x$_2{^2}$ - 11.9x$_3{^2}$ + 2.49x$_1x_2$ - 4.4x$_2x_3$ - 1.65x$_1x_3$와 같이 얻을 수 있었고 COD$^{Cr}$ 제거율(%)의 실측치에 대한 예측치의 적합도(goodness of fit) 검증시 결정계수(coefficient of determination: R$^2$) 0.96으로 에측식을 충분히 설명할 수 있었다. 예측 모형에 대한 최소제곱추정법으로 적합된 반응표면에서 1차 선형항(linear term)은 Fe(II)(x$_1$), $H_2O_2(x_2)$, 그리고 pH(x$_3$)은 상승작용(synergistic effect)으로 반응모델에 유의한 차이를 보였으며(p < 0.001) 그러나 교호항(cross-product term)은 $H_2O_2$ $\times$ pH(x$_2x_3$)와 순수이차항(quadratic terms)의 Fe(II) $\times$ Fe(II)(x$_1{^2}$), $H_2O_2$ $\times$ H$_2O_2$(x$_2{^2}$) 그리고 pH $times$ pH(x$_3{^2}$) 등은 대립적인(감쇠)(antagonistic effect) 작용으로 반응모델에 유의한 차이를 보였다(p < 0.01). 반응 모델에 대한 예측식 수립 후 COD$_{Cr}$ 제거율(%)의 최적조건을 도출하기 위해 정준분석(canonical analysis)와 능선분석(ridge analysis)에 이용한 결과 반응값(결과값: Y)은 84 $\pm$ 0.95%, COD$_{Cr}$ 최적처리를 위한 변수들의 조건은 Fe(II)(X$_1$) = 0.0146 mM, $H_2O_2$(X$_2$) = 0.0867 mM 그리고 pH(X$_3$) = 4.704 등의 결과를 얻을 수 있었다. 또한 이들 최적조건을 이용하여 재현성을 통한 모델검증 결과 높은 신뢰성을 보였다.

가시광 수중 무선통신을 위한 이종접합 유기물 반도체 기반 고감도 포토트랜지스터 연구 (Photo-Transistors Based on Bulk-Heterojunction Organic Semiconductors for Underwater Visible-Light Communications)

  • 이정민;서성용;임영수;백강준
    • 한국전기전자재료학회논문지
    • /
    • 제36권2호
    • /
    • pp.143-150
    • /
    • 2023
  • Underwater wireless communication is a challenging issue for realizing the smart aqua-farm and various marine activities for exploring the ocean and environmental monitoring. In comparison to acoustic and radio frequency technologies, the visible light communication is the most promising method to transmit data with a higher speed in complex underwater environments. To send data at a speedier rate, high-performance photodetectors are essentially required to receive blue and/or cyan-blue light that are transmitted from the light sources in a light-fidelity (Li-Fi) system. Here, we fabricated high-performance organic phototransistors (OPTs) based on P-type donor polymer (PTO2) and N-type acceptor small molecule (IT-4F) blend semiconductors. Bulk-heterojunction (BHJ) PTO2:IT-4F photo-active layer has a broad absorption spectrum in the range of 450~550 nm wavelength. Solution-processed OPTs showed a high photo-responsivity >1,000 mA/W, a large photo-sensitivity >103, a fast response time, and reproducible light-On/Off switching characteristics even under a weak incident light. BHJ organic semiconductors absorbed photons and generated excitons, and efficiently dissociated to electron and hole carriers at the donor-acceptor interface. Printed and flexible OPTs can be widely used as Li-Fi receivers and image sensors for underwater communication and underwater internet of things (UIoTs).

광기법을 이용한 고정도 과도전압측정기 (High Quality Transient Voltage Measuring Device Using Optical Technique)

  • 이복희;길경석;전덕규
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1995년도 추계학술대회 논문집 학회본부
    • /
    • pp.441-443
    • /
    • 1995
  • A new optical-resistive voltage divider, which consists of light emitting diode, optic fiber, PIN-photo diode and a high qualify shielding resistive divider, whose total response time is 7.35 [ns], has been obtained. The optical to electrical signal converter was constructed with GaAsP series light emitting diode. The response characteristics have been verified by applying the Marx impulse voltage generator experimentally. Comparing with the performance of conventional resistive voltage divider, the characteristics of the proposed optical-resistive voltage divider are more excellent in step response and less sensitive to electromagnetic interference.

  • PDF

Recent Progress in WV Films - OCB-WV -

  • Mori, Hiroyuki
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
    • /
    • pp.1501-1504
    • /
    • 2006
  • The WV film successfully enlarged the field of view of the TN mode and made TN popular for larger size applications such as PC monitors. The hybrid alignment of the PDM (polymerized discotic material) layer is also suited for the OCB mode, which is promising as a nextgeneration LCD-TV because of fast panel response and a wide viewing angle. This paper describes recent technological progress in WV films, especially for OCB.

  • PDF

간접 전파광의 수광 효율 향상에 관한 연구 (A Study on the Promotion of Indirect Light Receiving Efficiency)

  • 허수진;정찬수
    • 대한의용생체공학회:의공학회지
    • /
    • 제13권3호
    • /
    • pp.201-208
    • /
    • 1992
  • In the indirect optical bio-telemetry, high frequency response and low minimum detectable optical power can be achieved by using photodiode with small light receiving area which minimizes junction capacitance. But, on the other hand, S/N ratio becomes low because the optical signal current is small. To solve such a problem, we attach plato-convex lens in front of photo diode, The results of comput- er simulation and experiments suggest promotion of light receiving efficiency and possibility of multi- telemetry system through directivity of convex lens in one room.

  • PDF

Reduced graphene oxide를 이용한 전계효과 트랜지스터의 광전기적 특성 (Electrical and Photo-Response Properties of Reduced Graphene Oxide Field-Effect Transistor)

  • 이대영;민미숙;라창호;이효영;유원종
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2012년도 춘계학술발표회 논문집
    • /
    • pp.235-235
    • /
    • 2012
  • Reduced graphene oxide (rGO) 물질을 사용하여 전계효과 트랜지스터를 제작하였고 이의 광전기적 특성을 펄스 레이저와 진공 저온 측정을 통하여 분석하였다. 이를 통하여 rGO 소자의 광소자로써의 이용 가능성에 대하여 고찰하였다.

  • PDF

Optimization of photo-catalytic degradation of oil refinery wastewater using Box-Behnken design

  • Tetteh, Emmanuel Kweinor;Naidoo, Dushen Bisetty;Rathilal, Sudesh
    • Environmental Engineering Research
    • /
    • 제24권4호
    • /
    • pp.711-717
    • /
    • 2019
  • The application of advanced oxidation for the treatment of oil refinery wastewater under UV radiation by using nanoparticles of titanium dioxide was investigated. Synthetic wastewater prepared from phenol crystals; Power Glide SAE40 motor vehicle oil and water was used. Response surface methodology (RSM) based on the Box-Behnken design was employed to design the experimental runs, optimize and study the interaction effects of the operating parameters including catalyst concentration, run time and airflow rate to maximize the degradation of oil (SOG) and phenol. The analysis of variance and the response models developed were used to evaluate the data obtained at a 95% confidence level. The use of the RSM demonstrated the graphical relationship that exists between individual factors and their interactive effects on the response, as compared to the one factor at time approach. The obtained optimum conditions of photocatalytic degradation are the catalyst concentration of 2 g/L, the run time of 30 min and the airflow rate of 1.04 L/min. Under the optimum conditions, a 68% desirability performance was obtained, representing 81% and 66% of SOG and phenol degradability, respectively. Thus, the hydrocarbon oils were readily degradable, while the phenols were more resistant to photocatalytic degradation.