• Title/Summary/Keyword: photo-curing

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The development of biodegradable resin for scaffold fabrication using micro-stereolithography and curing characteristics analysis of the resin (마이크로 광 조형기술을 이용한 인공지지체의 제작을 위한 생분해성 수지의 개발 및 경화 특성 파악)

  • Lee J.W.;Cho D.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.147-148
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    • 2006
  • A research on scaffold fabrication has been progressed in many research groups. However, the mechanical properties of existing biodegradable materials are still not satisfactory. But, PPF (poly (propylene fumarate)) has a good mechanical property in comparison to other biodegradable materials. Nevertheless, the viscosity of the synthesized PPF is too high to fabricate structures using micro-stereolithography. Therefore, the viscosity of the resin was made low by adding the diethyl fumarate and this material could be used in micro-stereolithography apparatus. Then, a photoinitiator was added for photo crosslinking of the DEF/PPF resin. 2.5D and 3D scaffolds were fabricated our system and curing characteristics of the resin were analyzed through the experiment.

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A STUDY ON THE SHEAR BOND STRENGTH OF ESTHETIC RESTORATIVE MATERIALS TO DENTAL AMALGAM (아말감과 심미성 수복재료와의 전단 결합강도에 관한 연구)

  • Jeong, Hye-Jeon;Min, Byung-Soon
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.129-141
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    • 1995
  • Composite resin and glass-ionomer cement can be used for the purpose of repair of defective amalgam restoration. The purpose of this study was to evaluate of shear bond strength of esthetic restorative materials to dental amalgam. The materials used in this study were Photo Clearfil Bright(light curing composite resin), Clearfil F II(chemical curing composite resin), Fuji II LC(light curing glass-ionomer cement), Fuji II (chemical curing glass-ionomer cement), All-Bond 2(intermediary), and Scotchbond Multi-Purpose (intermediary). A total of 120 acrylic cylinders with amalgam were divided into 8 groups After amalgam condensation, all specimens were stored for 48 hours in water at $37^{\circ}C$ and tested with Instron universal testing machine between amalgam and composite resins and glass-ionomer cements. The data were analyzes statiscally by ANOVA and Duncan test. The following results obtained ; 1. The shear bond strength of bonded composite resin to amalgam was higher than bonded glass-ionomer cement(P<.001). 2. The group 4 had highest shear bond strength with 15.45kgf/$cm^2$ and the group 5 had lowest shear bond strenght with 3.26kgf/$cm^2$(P<.001). 3. In the group 3, 4, 5, 6, the group 3, 4 with All-Bond 2 had higher shear bond strength than the group 5, 6 with Scotch bond MP both in light-curing and in chemical curing. 4. Both in composite resin and glass-ionomer cement, chemical curing materials had higher shear bond stength than light curing materials(P<.001).

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A Study on the reduction of surface roughness by analyzing the thickness of photocurable sculpture (광조형물의 패턴두께에 따른 표면 거칠기 저감을 위한 공정연구)

  • Kim, Young-Su;Yang, Hyoung-Chan;Kim, Go-Beom;Dang, Hyun-Woo;Doh, Yang-Hoi;Choi, Kyung-Hyun
    • Journal of Power System Engineering
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    • v.20 no.4
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    • pp.75-82
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    • 2016
  • In this paper, we developed a 3D printing system using a photo-curing resin in order to reduce the surface roughness of a sculpture produced with the 3D printer. Using the pattern of the resulting variable thickness, that gave rise to a stepped shape, and the area error of the photo-curable sculpture, a study was carried out for the process to reduce the surface roughness. At a given value of stage velocity (40~70 mm/s) and output air pneumatic pressure (20~60 kPa), the minimum pattern thickness of the pattern was achieved $65{\mu}m$ and the maximum pattern thickness of up to $175{\mu}m$. To increases the pattern resolution to about $40{\mu}m$, the process conditions should be optimized. 3D surface Nano profiler was used to find the surface roughness of the sculpture that was measured to be minimum $4.7{\mu}m$ and maximum $8.7{\mu}m$. The maximum surface roughness was reduced about $1.2{\mu}m$ for the maximum thickness of the pattern. In addition, a FDM was used to fabricate the same sculpture and its surface roughness measurements were also taken for comparison with the one fabricated using photo-curing. Same process conditions were used for both fabrication setups in order to perform the comparison efficiently. The surface roughness of the photo-curable sculpture is $5.5{\mu}m$ lower than the sculpture fabricated using FDM. A certain circuit patterns was formed on the laminated surface of the photo-curable sculpture while there was no stable pattern on the laminated surface of the FDM based sculpture the other hand.

A study on Amine Synergist Effect in UV Curing System (UV 경화 시스템에서 Amine Synergist의 효과에 대한 연구)

  • Kim, Ji-Cheol;Moon, Seok-Young
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.1
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    • pp.29-38
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    • 2004
  • With increasing interests in environment matters over the world, incessant efforts to develop products which meet these environmental requirements have been made also in paint industry. Among the efforts in this field, UV(Ultra Violet) curing system is focused as one of most potential system. It is because this system not only proved to be environmentally friendly compared with heat curing system or other system but also has economical merit of smaller facility, less energy consumption, and better productivity. Superior properties in many application is surely one of its dominant merit. With these advantage UV system is applied to a variety of industrial fields and expected to have continuous growth in the future. As practical application of UV system has shown lasting progress, R&D on basic material of this system keeps up with. This is a study on photo-initiator that is a fundamental substance in UV curing method and amine, its aid for better effect. After reviewing on them in the aspects of function, economy, and stability, optimal foumula is pursued through experiments when applied to real products.

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Synthesis and Curing Behavior of UV-curable Polycarbonate-based Polyurethane Methacrylate : Effect of Polyol Molecular Weight, Contents of Photoinitiator and Monomers on the Flexibility and Properties (자외선 경화형 폴리카보네이트계 폴리우레탄 메타아크릴레이트의 합성과 경화거동 : 폴리올 분자량, 광개시제 및 모노머 함량이 유연성과 물성에 미치는 영향)

  • Park, Eun-Suk;Hwang, Hyeon-Deuk;Park, Cho-Hee;Lee, Yong-Hee;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.47-55
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    • 2011
  • UV-curable coatings have been used in various industries due to their advantages such as high mechanical property, good solvent resistance, fast curing process and low volatile organic compounds. However, a lack of flexibility of UV-cured films is a weak point for the pre-coated system of roll-to-roll process. In this study, UV-curable polycarbonate-based methacrylates were synthesized with polycarbonate diol, isophorone diisocyanate and 2-hydroxyethylmethacrylate to improve flexibility of the UC-cured films. The effects of polyol molecular weight, content of photoinitiator and monomers on the UV-curing behavior, flexibility and properties were investigated. The UV-curing behavior was measured by a photo-DSC, the pendulum hardness, tensile strength, viscoelastic properties were also evaluated.

Experiment and Numerical Study on Thermal Characteristics of UV-NIL Process Considering the Cure Kinetics of Photo-polymer (레진의 경화 반응을 고려한 UV-NIL공정의 열특성에 관한 실험 및 수치해석 연구)

  • Kim, Woo-Song;Park, Gyeong-Seo;Nam, Jin-Hyun;Yim, Hong-Jae;Jang, Si-Yeol;Lee, Kee-Sung;Jeong, Jay;Lim, Si-Hyeong;Shin, Dong-Hoon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1847-1850
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    • 2008
  • The process conditions during ultraviolet nanoimprint lithography (UV-NIL) process such as temperature, stamping pressure, UV irradiation, etc. are effective factors for successful imprinting of complex and fine patterns. In this study, the effects of aluminum mold on the thermal characteristics of UV-NIL process were investigated through imprinting experiments and numerical simulations. The temperature of polymer resin on mold was measured to study thermal characteristics during UV curing. From the experimental and numerical results, the importance of curing reaction control for UV-NIL process was discussed for deformation characteristics.

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Fabrication of Photosensitive Polymer Resistor Paste and Formation of Finely-Patterned Thick Film Resistors (감광성 폴리머 저항 페이스트 제조와 미세패턴 후막저항의 형성)

  • Kim, Dong-Kook;Park, Seong-Dae;Yoo, Myong-Jae;Sim, Sung-Hoon;Kyoung, Jin-Bum
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.622-627
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    • 2009
  • Using an alkali-solution developable photosensitive resin and a carbon black as a conductive filler, photo-patternable pastes for polymer thick film resistor were fabricated and evaluated. A photo solder resist (PSR), which is usually used as protecting layer of printed circuit board (PCB), was used as a photosensitive resin so that ultraviolet exposure and alkali-aqueous solution development of paste were possible. After fabricating the photosensitive polymer resistor paste, the electrical properties of thick film resistors were measured using PCB test boards. Sheet resistance was decreased with increasing amount of carbon black, but the developability was limited in excess loading of carbon black. The sheet resistance was also reduced by re-curing and the change rate was smaller in higher carbon black loading. Moreover, finely patterned meander-type thick film resistors were fabricated using photo-process and large resistance up to several tens of sheet resistance could be obtained in small area by this technique.

Olefin Metathesis Curing Reaction of Essential Oils in Korean Dendropanax Lacquer (Olefin Metathesis를 이용한 황칠 Essential Oil의 경화 반응에 관한 연구)

  • Kim, Mi Ri;Lee, Won Hwi;Yoo, Hye Jin;Kim, Jong Sang;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.16 no.4
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    • pp.146-151
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    • 2015
  • Raw sap of essential oil in Korean Dendropanax lacquer was extracted with ethanol, and which was cured by using ROMP (ring opening metathesis polymerization, one of olefin metathesis). Curing behavior with subsequent film properties were studied and compared with conventional curing (under ambient conditions) and UV photo curing. The compositional changes of major ingredients in the lacquer before and after curing were studied by using GC-MS (gas chromatography mass spectrometry). ROMP-cured coating film showed higher gel contents (40%) as compared to those of conventional (8%) and UV curing (25%). ROMP curing with 2 wt% Grubbs' catalyst at $100^{\circ}C$ completed curing reaction within 2 h, which was much faster than that of conventional curing. The quality of coating film prepared with ROMP was more homogeneous and wrinkle-free as compared with that with UV curing. It was found that major ingredients of sesquiterpenes, such as ${\alpha}$-selinene, ${\beta}$-selinene, and ${\delta}$-cadinene were reacted in ROMP, as well as polyacetylenes.

Transparent Sol-Gel Hybrid Dielectric Material Coatings for Low k Passivation Layer

  • Yang, Seung-Cheol;Oh, Ji-Hoon;Kwak, Seung-Yeon;Bae, Byeong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1453-1456
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    • 2009
  • Transparent sol-gel hybrid dielectric material (hybrimer) coating films were fabricated by spin coating and photo or thermal curing of sol-gel derived oligosiloxane resins. Hybrimer coating films are suitable as the passivation layer of TFT in AMLCD due to low dielectric constant, small loss tangent, low leakage current density, high transmittance and thermal stability.

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