• 제목/요약/키워드: photo-crosslinkable polymer

검색결과 15건 처리시간 0.027초

광중합 가능한 폴리머 표면에 in-situ 광배향법을 이용한 액정배향특성 (Liquid Crystal Aligning Capabilities Using the in-situ Photo-alignment Method on Photo-crosslinkable Polymer Surface)

  • 황정연;정은아;서대식;정재형;한은주
    • 한국전기전자재료학회논문지
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    • 제14권11호
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    • pp.917-921
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    • 2001
  • Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable Polyimide (Pl) based polymer and blending photopolymer surfaces were investigated. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (Pl and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

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광중합 가능한 폴리머 표면에 in-situ 광배향법을 이용한 프리틸트각 제어 (Control of Pretilt Angle using a in-situ Photoalignment Method on Photo-Crosslinkable Polymer Surface)

  • 정은아;황정연;서대식;김재형;한은주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.350-353
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    • 2001
  • Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various photo-crosslinkable polyimide (PI) based polymer and blending photopolymer surfaces were stuided. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyirnide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively, However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

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광중합 가능한 폴리머 표면에 in-situ 광배향법을 이용한 프리틸트각 제어 (Control of Pretilt Angle using a in-situ Photoalignment Method on Photo-crosslinkable Polymer Surface)

  • 정은아;황정연;서대식;김재형;한은주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.350-353
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    • 2001
  • Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable polyimide (PI) based Polymer and blending photopolymer surfaces were studied. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decal (de), and cholesterol (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

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새로운 광중합 가능한 폴리머의 프리틸트각 발생의 메카니즘 (Mechanisms of Pretilt Angle Generation on the New Photo-crosslinkable Polymers)

  • 황정연;서대식;김재형
    • 한국전기전자재료학회논문지
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    • 제14권7호
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    • pp.595-599
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    • 2001
  • The mechanisms of pretilt angle generation for a nematic liquid cystal (NLC) using a photodimerization method with obliquely polarized UV exposure on the various new photo-crosslinkable polymer were studied. A good thermal stability of all the photo-crosslinkable polymers was obtained by thermogravimetric analysis (TGA) measurement until 450$\^{C}$. High pretilt angle of the NLC was observed by polarized UV exposure on the three kinds of the photo-crosslinkable polymers containing biphenyl(BP), decyl(de), and cholesteryl(chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the two kinds of the photo-crosslinkable polymers containing fluorine and chalcone group. Consequently, the high NLC angle generated is attributable to the biphenyl and alkyl moieties, and photo-dimerized chalcone group of the photopolymer.

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새로운 광중합 가능한 폴리이미드계 몰리머을 이용한 액정 배향 특성 (Liquid Crystal Aligning Capabilities on a New Photo-Crosslinkable Polyimide Based Polymer)

  • 황정연;서대식;이상렬;김재형;한은주
    • 한국전기전자재료학회논문지
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    • 제14권5호
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    • pp.430-434
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    • 2001
  • We synthesized a new photo-crosslinkable polymer (polyimide (PI)-chalcone-biphenyl (BP)) and liquid crystal (LC) aligning capabilities for nematic (N) LC with obliquely polarized UV exposure on a photo-crosslinkable polymer were studied. The high pretilt angle in NLC was obtained by polarized UV exposure on a PI-Chal-BP surface for 3 min. The high pretilt angle generated in NLC is attributed to the biphenyl moieties and the photo-dimerized chalclone group of a photopolymer. Also, good thermal stability of a PI-Chal-BP were obtained by thermogravimetric analysis (TGA) measurement until 450$^{\circ}C$. Finally, good voltage-transmittance curves and response time were observed by UV exposure on a PI-Chal-BP surface for 3min.

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광중합 가능한 폴리이미드계 폴리머의 광중합법을 이용한 고프리틸트각의 제어 (Control of High Pretilt Angle Using the Photodimerization Method on the Photo-Crosslinkable Polymide Based Polymer)

  • 황정연;서대식;이상렬;김재형
    • 한국전기전자재료학회논문지
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    • 제14권4호
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    • pp.341-344
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    • 2001
  • We synthesized a photo-crosslinkable polymide (polymide (PI)-chalcone-biphenyl (BP)) based polymer and control of pretilt angle for a nematic liquid crystal (NLC) using two kinds of the photodimerization methods by polarized UV exposure the photopolymer surfaces was studied. Pretilt angle of the NLCs using a conventional photodimerization method could be varied between 0$^{\circ}$ and 3$^{\circ}$, by controlling the condition of UV exposure. Pretilt angle of the NLCs using the conventional photodimerization method was higher than a in-situ photodimerization method.

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Control of Pretilt Angles on Various Photo-Crosslinkable Polyimide based Polymers by Photodimerization

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik;Suh, Dong-Hack
    • KIEE International Transactions on Electrophysics and Applications
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    • 제11C권4호
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    • pp.133-137
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    • 2001
  • In this research, we synthesized various photo-crosslinkable polyimide based polymers. The control of pretilt angles for a nematic liquid crystal (NLC) using the photodimerization method on the photopolymers was studied. A good thermal stability of the photopolymers was measured by thermogravimetric analysis (TGA) measurement until 450C. High pretilt angles of the NLC were otained by polarized UV exposure on the photopolymers containing biphenyl (BP), decyl (de), and cholesteryl (chal) groups, respectively. However, low pretilt angles of the NLC were measured by polarized UV exposure on the photopolymers containing fluorine and chalcone groups. The high NLC pretilt angles generated are attributable to the biphenyl and alkyl moieties, and the photodimerized chalocone group of the photopolymers. Additionally, good voltage-transmittance and response time characteristics were observed by UV exposure on the photopolymers.

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광폴리머 표면에 In-situ 광중합법을 이용한 네마틱액정의 배향 효과에 관한 연구 (A study on alignment effects for Nematic Liquid Crystal by in-situ Photodimerization Method on a photopolymer surface .)

  • 정은아;황정연;서대식;김재형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.951-954
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    • 2001
  • We investigated the aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various photopolymer surfaces. High Pretilt angle of the NLC can be measured by obliquely polarized UV exposure of 30$^{\circ}$on a photo-crosslinkable polyimide (PI) based polymer surface for 3 min. The pretilt angle of the NLC generated on the photopolymer surface using the in-situ photodimerization method was higher than that of a blending photopolymers (PI and cinnamate materials).

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Synthesis and characterization of Reactive Banana-Shaped Mesogens

  • Choi, Min-Ho;Choi, E-Joon;Kim, Young-Chul;Park, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.854-857
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    • 2006
  • The synthesis of ester type, banana-shaped, photo - crosslinkable mesogens is described. The reactive mesogens, derivatives of 1,3-phenylene bis{4-[4'- (alken-1-yloxy)-biphenyl-4-carboxylate]benzoate}s, were synthesized varying the length of alkyl end groups. The obtained monomers and polymers were characterized by FT/IR, NMR spectroscopy, DSC, polarized optical microscopy, and X-ray diffractometry.

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백금전극과 감광성 고분자를 이용한 ISFET 포도당 및 자당센서의 감지성능 개선 (The Improvement of Sensing Performance of ISFET Glucose and Sucrose Sensors by Using Platinum Electrode and Photo-crosslinkable Polymers)

  • 조병욱;장원덕;김창수;박이순;손병기
    • 센서학회지
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    • 제4권4호
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    • pp.23-28
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    • 1995
  • 백금작업전극과 광가교화된 효소고정화막을 가진 ISFET 포도당 및 자당센서가 제조되었다. 효소반응의 부산물인 과산화수소수($H_{2}O_{2}$)는 백금전극표면에서 분해되어 센서의 감지특성을 개선시키고, 광가교화 고분자(PVA-SbQ)가 효소고정화막으로 이용되어 센서의 응답시간을 단축하였다. 그리고 백금전극의 면적변화에 따라 센서의 응답크기는 증가하였다. 센서의 응답시간은 $3{\sim}5$분이었으며, $30{\sim}300mg/dl$의 포도당 및 자당농도에서 센서의 선형적인 응답을 보였다.

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