• 제목/요약/키워드: photo

검색결과 4,234건 처리시간 0.033초

Polyethylene Glycol에 의한 수록한지(手漉韓紙)의 광(光) 변색(變色) 억제(抑制) (Control of the Photo-induced Discoloration of the Handmade Korean Paper with Polyethylene Glycol)

  • 전철;박수안
    • 한국산림과학회지
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    • 제89권2호
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    • pp.161-166
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    • 2000
  • 지류문화재의 소재로 주로 사용되어온 수록한지를 네 종류로 구분하고 이를 PEG 분자량과 농도별에 따른 광 변색 억제 효과를 태양의 분광분포와 거의 흡사한 xenon arc 등(燈)을 조사(照射)해 시험한 바 다음과 같이 요약할 수 있었다. 1) Polyethylene glycol을 분산제로 사용한 미 표백 한지는 광 조사 이후 PEG 분자량과는 관계없이 10시간까지는 백색도가 급속히 떨어지는 경향을 보였으나 그 이후부터는 점진적으로 향상되는 경향을 나타내 광 변색 억제의 효과가 있음을 알 수 있었다. 2) 약품 표백을 실시한 한지는 20시간 이후부터 백색도가 증가하는 현상이 나타나 시간이 지체될 뿐 변색 억제의 효과는 있음을 알 수 있었다. 3) 황단규근(黃團葵根)을 분산제로 사용해 초지(秒紙)한 한지(韓紙)는 PEG 400-20%에 침지했을 때 백색도가 가장 낮았으나 광 조사 후는 백색도 차가 가장 적어 광 변색 억제효과가 가장 컸음을 알 수 있었다. 4) 광 열화에 의한 표면현상으로 제일 먼저 나타나는 황변(黃變) 현상을 PEG 침지로써 억제할 수 있음을 b*+값이 감소하는 것으로 알 수 있었고 명도 저하 역시 L* 값의 증가로 상당량 억제할 수 있음을 알 수 있었다.

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다이오드 레이저와 PhotoMed, Methyl Pheophorbide A, Radachlorin®을 이용한 녹농균에 대한 항균 광역학 요법 (Antimicrobial Photodynamic Therapy on Pseudomonas aeruginosa Using a Diode Laser and PhotoMed, Methyl Pheophorbide A, or Radachlorin®)

  • 송영규;육근돌;김지원
    • 대한임상검사과학회지
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    • 제56권1호
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    • pp.52-58
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    • 2024
  • 광역학 요법(photodynamic therapy)은 특정 파장의 빛에 의해 활성화되는 광민감제(photosensitizer)를 사용하여 세포 내 산소를 활성화시키는 치료 방법으로, 항생제 내성균에 의한 상처 감염의 치료에 유망한 접근 방법이다. 일반적으로 건강한 사람에게 비병원성인 녹농균(Pseudomonas aeruginosa, P. aeruginosa)은 특정 병원성 징후를 보이지 않지만, 피부 손상이나 면역력이 저하된 사람들에서는 패혈증과 같은 심각한 질병을 유발할 수 있다. 항생제는 P. aeruginosa 감염에 대한 전통적인 치료법이나 약물 오용으로 인한 항생제 내성의 증가는 이러한 감염을 관리하는 데 큰 어려움을 준다. 본 연구에서는 P. aeruginosa의 억제제로서 광민감제(PhotoMed, Methyl pheophorbide A, Radachlorin®)와 다이오드 레이저를 이용한 광역학 치료 효과를 조사하는 것을 목표로 했다. P. aeruginosa 현탁액과 광민감제(PhotoMed, Methyl pheophorbide A, Radachlorin®)를 페트리 접시에 접종하여 30분 후 다이오드 레이저를 사용하여 3 J/cm2의 에너지 밀도로 조사했다. 그 결과, P. aeruginosa는 PhotoMed에서 79.65%, Methyl pheophorbide A에서 47.36%, Radachlorin®에서 40.91%의 사멸률을 보였다. 이번 연구는 P. aeruginosa를 억제하기 위한 가장 효과적인 접근법이 PhotoMed와 다이오드 레이저를 이용한 광역학 치료임을 보여준다.

Photo or Solar Ferrioxalate Disinfection Technology without External Hydrogen Peroxide Supply

  • Cho, Min;Jeong, Joon-Seon;Kim, Jae-Eun;Yoon, Je-Yong
    • Environmental Engineering Research
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    • 제12권5호
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    • pp.238-243
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    • 2007
  • The Fenton reaction, which refers to the reaction between ferrous ions and hydrogen peroxide to produce the OH radical, has not been widely applied to the disinfection of microorganisms despite being economic and environmentally friendly. Cho et al. have previously proposed the neutral photo ferrioxalate system as a solution to the problems posed by the Fenton reaction in acidic conditions, but this system still requires an external hydrogen peroxide supply. In the present study, we developed a simple disinfection technology using the photo or solar ferrioxalate reaction without the need for an external hydrogen peroxide supply. E. coli was employed as the indicating microorganism. The study results demonstrated the effectiveness of the photo ferrioxalate system in inactivating E. coli without any external hydrogen peroxide supply, as long as dissolved oxygen is supplied. Furthermore, the solar ferrioxalate system achieved faster inactivation of E. coli than an artificial light source at similar irradiance.

Electrochromic Pattern Formation by Photo Cross-linking Reaction of PEDOT Side Chains

  • Kim, Jeong-Hun;Kim, Yu-Na;Kim, Eun-Kyoung
    • Macromolecular Research
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    • 제17권10호
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    • pp.791-796
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    • 2009
  • An electrochemically and photochemically polymerizable monomer, 2-((2,3-dihydrothieno[3,4-b] [1,4]dioxin-2-yl)methoxy)ethyl methacrylate (EDOT-EMA), was explored for patterning of poly(3,4-ethylenedioxythiophene) (PEDOT) via side chain cross-linking. The polymer from EDOT-EMA was deposited electrochemically to produce polymeric EDOT (PEDOT-EMA), which was directly photo-patterned by UV light as the side EMA groups of PEDOT-EMA were polymerized to give cross-linked EMA (PEDOT-PEMA). Absorption and FTIR studies of the UV-exposed film (PEDOT-PEMA) indicated that the photo-patterning mainly originated from the photo cross-linking of the methacrylates in the side-chain. After irradiation of the film, the conductivity of the irradiated area decreased from $5.6{\times}10^{-3}$ S/cm to $7.2{\times}10^{-4}$ S/cm, possibly due to bending of the conductive PEDOT channel as a result of the side chain cross-linking. The patterned film was applied to a solid state electrochromic (EC) cell to obtain micro-patterned EC cells with lines up to 5 ${\mu}m$ wide.

Solution processed organic photodetector utilizing an interdiffused polymer/fullerene bilayer

  • Shafian, Shafidah;Jang, Yoonhee;Kim, Kyungkon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.348-348
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    • 2016
  • Low dark current (off-current) and high photo current are both essential for a solution processed organic photodetector (OPD) to achieve high photo-responsivity. Currently, most OPDs utilize a bulk heterojunction (BHJ) photo-active layer that is prepared by the one-step deposition of a polymer:fullerene blend solution. However, the BHJ structure is the main cause of the high dark current in solution processed OPDs. It is revealed that the detectivity and spectral responsivity of the OPD can be improved by utilizing a photo-active layer consisting of an interdiffused polymer/fullerene bilayer (ID-BL). This ID-BL is prepared by the sequential solution deposition (SqD) of poly(3-hexylthiophene) (P3HT) and [6,6] phenyl C61 butyric acid methyl ester (PCBM) solutions. The ID-BL OPD is found to prevent undesirable electron injection from the hole collecting electrode to the ID-BL photo-active layer resulting in a reduced dark current in the ID-BL OPD. Based on dark current and external quantum efficiency (EQE) analysis, the detectivity of the ID-BL OPD is determined to be $7.60{\times}1011$ Jones at 620 nm. This value is 3.4 times higher than that of BHJ OPDs. Furthermore, compared to BHJ OPDs, the ID-BL OPD exhibited a more consistent spectral response in the range of 400 - 660 nm.

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Multi-scale agglomerates and photocatalytic properties of ZnS nanostructures

  • 만민탄;이홍석
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.267.2-267.2
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    • 2016
  • Semiconductor photo-catalysis offers the potential for complete removal of toxic chemicals through its effective and broad potential applications. Various new compounds and materials for chemical catalysts were synthesized in the past few decades. As one of the most important II-VI group semiconductors, zinc sulfide (ZnS) with a wide direct band gap of 3.8 eV has been extensively investigated and used as a catalyst in photochemistry, environmental protection and in optoelectronic devices. In this work, the ZnS films and nanostructures have been successfully prepared by wet chemical method. We show that the agglomerates with four successive scales are always observed in the case of the homogeneous precipitation of zinc sulfide. Hydrodynamics plays a crucial role to determine the size of the largest agglomerates; however, other factors should be invoked to interpret the complete structure. In addition, studies of the photocatalytic properties by exposure to UV light irradiation demonstrated that ZnS nanocrystals (NCs) are good photo-catalysts as a result of the rapid generation of electron-hole pairs by photo-excitation and the highly negative reduction potentials of excited electrons. A combination of their unique features of high surface-to volume ratios, carrier dynamics and rich photo-catalytic suggests that these ZnS NCs will find many interesting applications in semiconductor photo-catalysis, solar cells, environmental remediation, and nano-devices.

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Photo-Plethysmography를 이용한 정상과 재접합 수지 혈류량의 비교 (Comparison of normal and replantation digital blood flow using photo-plethysmography)

  • 남기창;김성우;나동균;김덕원
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 학술대회 논문집 정보 및 제어부문
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    • pp.322-324
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    • 2004
  • Up to the present, digital replantation patients has appealed different symptoms due to blood circulatory failure. But, the level of blood circulatory failure has been evaluated only by clinical symptoms, or angiography. According to the cases of digit replantation is increasing, then objective evaluation methods of the level of blood circulation failure is needed other than patient's subjective symptoms and complaints. Although angiography, doppler, electromagnetic flowmeter, laser blood flowmeter, mechanical blood flowmeter has been used for the evaluation of the blood circulatory failure, the result was affected by time, place, surrounding temperature, patient's body temperature, and even emotion. Therefore, it is pointed out with lack of availability, feasibility and reproducibility. Thus, we compared digital blood flow of dominant hand to non dominant hand, and replanted fingers to opposite normal fingers from developed photo-plethysmography. The average digital blood flow showed no difference in normal digits each other, but, replanted digits showed average of 53% (9 - 100 %) compare to opposit normal digits. As it measure relative blood flow for circulatory failure of tissue such as fingers and toes more sensitively, reliably. In conclusion, it is expected that photo- plethysmography will be very useful for diagnosis, curative effect, prognosis of blood circulatory failure in digital replantation patient.

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포토몽타주(Photo-montage)를 응용한 패션 일러스트레이션 연구 (Application of Photo-montage on Fashion Illustration)

  • 노윤선
    • 디자인학연구
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    • 제16권3호
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    • pp.291-298
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    • 2003
  • 패션 일러스트레이션은 빠르게 변화하는 현대의 생활환경에서 예술과 산업의 여러 분야에 응용되어 폭이 넓어지고 있다. 실물이 없어서 사진으로 표현하기 어려운 분야, 특히 앞서가는 유행경향을 표현해야 하는 트랜드 북(trend book) 등에서 많이 활용되고 있다. 학계와 패션 업계에서는 점차 패션 일러스트레이션의 중요성을 인식하여 단순히 의복제작과 연결되는 설명도로서의 패션 일러스트레이션 뿐만 아니라 복식 전반의 이미지 전달을 위한 표현을 폭 넓게 연구하고 있다. 본 연구에서는 독특한 표면 재질 효과를 통하여 현대 패션의 복합적인 이미지 전달을 위하여 포토몽타주를 응용한 패션 일러스트레이션을 연구하였다. 연구의 내용 및 방법은 국내외 도서자료와 논문을 통해 패션 일러스트레이션과 포토몽타주에 대한 문헌조사를 하였으며, 패션의 복합적인 이미지 전달을 중심으로 총 5점의 실물을 제작하였다.

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TiO2 광측매를 이용한 Cu(II)-EDTA의 산화에서 용존산소와 Cu(II)와 EDTA 초기 당량의 영향 (The effect of dissolved oxygen and initial complextation of Cu(II) and EDTA on photooxidation of Cu(II)-EDTA by TiO2)

  • 정흥호;성기웅;조영현;이영석;최상원
    • 한국환경과학회지
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    • 제11권1호
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    • pp.85-91
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    • 2002
  • The effects of initial concentration of dissolved oxygen content, Cu(II) and EDTA in an aqueous Cu(II)-EDTA solution on $TiO_2$ photo-oxidation of EDTA were investigated using $TiO_2$ (Degussa P-25) and UV irradiation at $20{\circ}C$. In the presence of dissolved oxygen and/or Cu(II) the photo-oxidation rates of EDTA were enhanced. The rates linearly increased in the range of initial Cu(II) concentration below 1.79 mM, while abode this concentration those were kept constant. The trend or the EDTA photo-oxidation rates appeared to be akin to the Langmuir-Hinshelwood equation farm and the k values calculated were 0.05 mM/min for the free-EDTA system, and 0.17 mM/min far the Cu(II)-EDTA system. These meant the aqueous EDTA decomposition was enhanced due to weakening of the intra-molecular bond strength of EDTA by complexation with Cu(II) added. It was concluded the decomposition of aqueous EDTA by $TiO_2$ photo-oxidation was maximum in the presence of dissolved oxygen supplied by air purging and of Cu(II) with its concentration for 1:1 Cu(II)-EDTA complexation ratio.

TiO2 Paste에 PEG 첨가에 따른 DSSC의 효율 특성 (DSSCs Efficiencies of PEG Additive In TiO2 Paste)

  • 권성열;양욱;장자항
    • 한국전기전자재료학회논문지
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    • 제27권11호
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    • pp.746-752
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    • 2014
  • Photo electrode is an important component of DSSC, so this paper did some research on it. Through the method of adding PEG additive into $TiO_2$ paste, the electrical characteristics and efficiencies of DSSCs with photo electrode surface area were studied. In the case of not adding PEG in $TiO_2$ paste, $26{\mu}m$ thickness $TiO_2$ photo electrode shows 5.081% efficiency. The highest short circuit current density was $10.476mA/cm2^$. The structure of porous $TiO_2$ film can be controlled through changing the PEG additive amount in $TiO_2$ paste and the molecular weight of PEG. When the additive amount of PEG 20,000 in $TiO_2$ paste reaches 5%, the peak efficiency with $26{\mu}m$ thickness $TiO_2$ photo electrode was 5.387% and its highest current density were $11.084mA/cm^2$.