• Title/Summary/Keyword: phenols

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Post-coital antiimplantation and pregnancy interruption potency of the seeds of Crotalaria juncea Linn

  • Malashetty, Vijaykumar B.;A., Sharanabasappa;Patil, Saraswati B.
    • Advances in Traditional Medicine
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    • v.4 no.2
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    • pp.70-76
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    • 2004
  • Petroleum ether, benzene and alcohol extracts of the seeds of C. juncea were tested for antiimplantation and pregnancy interruption activities in female albino rats. Of these three extracts, the alcohol extract was found to be the most effective in causing antiimplantation and pregnancy interruption activities. These adverse effects on fertility are reversible upon withdrawal of the extract treatments. The alcohol extract was found to possess estrogenic activity. After subjecting to preliminary phytochemical screening, the alcohol extract showed positive tests for alkaloids, steroids, glycosides, saponins, flavonoides, fixed oils, phenols and tannins.

Phenolic Compounds in Plant Foods: Chemistry and Health Benefits

  • Naczk, Marian;Shahidi, Fereidoon
    • Preventive Nutrition and Food Science
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    • v.8 no.2
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    • pp.200-218
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    • 2003
  • Phenolic compounds in food and plant materials belong to the simple phenols, phenolic acids, coumarins, flavonoids, stilbenes, tannins, lignans and lignins, all of which are considered as secondary plant metabolites. These compounds may be synthesized by plants during normal development or in response to stress conditions. Phenolics are not distributed uniformly in plants. Insoluble phenolics are components of cell walls while soluble ones are present in vacuoles. A cursory account of phenolics of cereals, beans, pulses, fruits, vegetables and oilseeds is provided in this overview. The information on the bioavailability and absorption of plant phenolics remains fragmentary and diverse. Pharmacological potentials of food phenolics ave extensively evaluated. However, there are many challenges that must be overcome in order to fully understand both the function of phenolics in plant as well as their health effects.

Antioxidant Activities of Agrimonia pilosa Ledeb: In Vitro Comparative Activities of Its Different Fractions

  • Chen, Lei;Kang, Young-Hwa
    • Korean Journal of Plant Resources
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    • v.27 no.6
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    • pp.642-649
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    • 2014
  • The antioxidant potentials of the methanol extract and its various fractions from Agrimonia pilosa Ledeb were measured as 1,1-diphenyl-2-picrylhydrazyl (DPPH), and 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) radical scavenging abilities as well as the reducing power decreasing NO in vitro. The methanol extract of Agrimonia pilosa Ledeb showed significantly strong scavenging effects on free radicals of DPPH, ABTS, and NO. Hexane fraction (HF), ethyl acetate fraction (EF) and n-butyl alcohol fraction (BF) were prepared by solvent fractionation. By comparison of polyphenol contents among BF and HF, EF with high polyphenol contents showed the highest DPPH, ABTS, and NO scavenging effects with the value of 50.2%, 80.4%, and 65.7%, respectively, at the highest tested dose. HPLC analysis revealed the presence of various phenolic compounds in EF of Agrimonia pilosa Ledeb. These results suggest that EF could be considered as natural antioxidant sources and dietary nutritional supplements to prevent oxidation-related diseases.

On-line SPE-HPLC Method using Alumina Filtering to Selectively Extract Phenolic Compounds from Environmental Water

  • Lee, Sung-Kwang
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3755-3759
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    • 2010
  • A on-line SPE (solid phase extraction)-HPLC preconcentration method was developed for the determination of phenolic compounds at trace levels in environmental water sample. XAD-4 and Dowex 1-X8 were used as sorbent in the on-line SPE-HPLC method for the selective enrichment of nine phenolic compounds, which are included in the priority pollutants list of the US EPA. Also alumina prefiltering considerably reduced the amount of interfering peaks due to humic substances that could accumulated due to the preconcentration step and prevent quantification of polar phenolic compounds in environmental water samples. This method was used to determine the phenolic compounds in tap and river water and superiority to the US EPA 625 method in its enrichment factor, pretreatment time, recoveries, and detection limit. The limits of detection were in the range of $0.3-0.9\;{\mu}g/L$ in tap water sample.

Synthesis of N-Azaaryl Anilines: An Efficient Protocol via Smiles Rearrangement

  • Xia, Shuai;Wang, Li-Ying;Sun, Heng-Zhi;Yue, Huan;Wang, Xiu-Hua;Tan, Jia-Lian;Wang, Yin;Hou, Di;He, Xiao-Yan;Mun, Ki-Cheol;Kumar, B. Prem;Zuo, Hua;Shin, Dong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.394-398
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    • 2013
  • An efficient process for the synthesis of N-azaaryl anilines via Smiles rearrangement as a tool. A variety of N-azaaryl anilines were generated by the reaction of substituted phenols, substituted anilines, aminopyridines and chloroacetyl chloride or pyridols, under base condition in good to excellent yields.

Evaluation of New Selective Molecularly Imprinted Polymers for the Extraction of Resveratrol from Polygonum Cuspidatum

  • Cao Hui;Xiao Jian Bo;Xu Ming
    • Macromolecular Research
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    • v.14 no.3
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    • pp.324-330
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    • 2006
  • Four different molecularly imprinted polymers (MIPs) were prepared using resveratrol as the template, methacrylic acid (MAA) or acrylamide (AA) as functional monomers, 2,2-azobisisobutyronitrile (AIBN) as the initiator, and thermo- or photo-induced polymerization. The ability of the different polymers to rebind selectively not only the template but also other phenols was evaluated. In parallel, the influence of the different templates and functional monomers used during polymer syntheses on the performance of the obtained MIPs was also studied through different rebinding experiments. The binding ability and selectivity of the polymer were studied by static balance method and Scatchard analysis. It was concluded that AA-based polymer by photo-induced polymerization presents the best properties to be used as a selective absorbent for the extraction of resveratrol.

Biological Activities of the Water Soluble Fraction from the Overground Part of Panax ginseng (인삼잎의 수용성 분획의 생리활성)

  • Hahn Dug Ryong
    • Proceedings of the Ginseng society Conference
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    • 1988.08a
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    • pp.139-140
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    • 1988
  • In the screening of those components with comparatively strong xanthine oxidase inhibition activities from Panax ginseng folium. trifolin. panasenoside. kaempferol and so far unconfirmed phenol whose chemical structure still without elucidation have been discovered as such components. Specific inhibitors of xanthine oxidase are thought to be therapeutically useful for the treatment of gout. Such opinion is considered to be useful to support the thought that ginseng folium is effective for the adjustment of gout. Although trifolin. panasenoside. and kaempferol are well known flavonoids. further studies on unidentified new phenols should be continued.

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Headspace-Solid Phase Microextraction (HS-SPME) Analysis of Korean Fermented Soybean Pastes

  • Lee, Seung-Joo
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.700-705
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    • 2009
  • In this study, the volatile compounds in 9 commercial fermented soybean pastes were extracted and analyzed by headspace-solid phase microextraction (HS-SPME) and gas chromatography-mass spectrometry (GC-MS), respectively. A total of 63 volatile components, including 21 esters, 7 alcohols, 7 acids, 8 pyrazines, 5 volatile phenols, 3 ketones, 6 aldehydes, and 6 miscellaneous compounds, were identified. Esters, acids, and pyrazines were the largest groups among the quantified volatiles. About 50% of the total quantified volatile material was contributed by 5 compounds in 9 soybean paste samples; ethyl hexadecanoate, acetic acid, butanoic acid, 2/3-methyl butanoic acid, and tetramethyl-pyrazine. Three samples (CJW, SIN, and HAE) made by Aspergillus oryzae inoculation showed similar volatile patterns as shown in principal component analyses to GC-MS data sets, which showed higher levels in ethyl esters and 2-methoxy-4-vinylphenol. Traditional fermented soybean pastes showed overall higher levels in pyrazines and acids contents.

Studies on the Sanitary Scientific Utilization of Asphalt (II) Air Oxidation of Asphalt. (아스팔트의 위생학적 이용에 관한 연구(제 2보))

  • 우세홍;이성호;김선덕;주대수
    • Journal of Environmental Health Sciences
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    • v.3 no.1
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    • pp.53-56
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    • 1976
  • The air oxidations of asphalt at temperatures ranging from 190$\circ$C to 270$\circ$C were studied for changes in physical properties, proportions and chemical characteristics of asphalt compositions, weak acid and very weak acid contents. The following results were obtained: 1) Oils and resins of asphalt components are oxidized to asphaltenes by blowing(Air oxidation) 2) At 270$\circ$C, asphaltenes begin to undergo a change into benzene insoluble after approximately 12 hours of air oxidation. 3) Weak acid increases at the oxidation temperature below 200$\circ$C. While very weak acid, presumably phenols, generally increases without regard to the blowing(Air oxidation) temperature.

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A Study of Removal of Phenol by Peroxidase Extracted from Oenanthe javanica (Blume) DC (미나리 Peroxidase를 이용한 Phenol제거에 관한 연구)

  • 탁창준;최한영;신정식;나규환;이장훈
    • Journal of Environmental Health Sciences
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    • v.23 no.4
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    • pp.121-126
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    • 1997
  • Peroxidase as one of the organic enzyme catalyst is useful for the oxidation treatment of various aromatic compounds such as phenols. The peroxidase content of Oenanthe javanica was 24.85 unit/g-fw in leaf, 5.74 unit/g-fw in stem, and 34.69 unit/g-fw in root respectively. The crude peroxidase extracted from Oenanthe javanka can be kept under low temperature (-70$\circ$C) condition for 6 months with the maximum 1% activity reduction. The optimum conditions of removal for 100 ppm phenol was pH 6, hydrogen peroxide 3.5 mM, peroxidase activity 8 unit/ml, temperature 20$\circ$C respectively. In the wide range of concentration from 50 ppm to 750 ppm phenol reveals average 54% removal rate under the same peroxidase activity (8 unit/ml) and different amount of hydrogen peroxide proportional to phenol concentration. Especially at the concentration of 100 ppm the maximum phenol removal rate was 72%.

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