• Journal of the Korean Society of Safety
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• v.25 no.1
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• pp.38-43
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• 2010

The smoke density and noxious gas for phenol foam and polyurethane foam were measured according to test methods in ASTM E 662 and KS F 2271. It was observed that phenol foam had the possibility of application for sandwich panel and board compared with polyurethane foam. In the experimental results, phenol foam showed comparatively excellent property than polyurethane foam in smoke density and noxious gas. The polyurethane foam showed comparatively high smoke density and didn't meet the evaluation standard of noxious gas in KS F 2271. From the experimental results of smoke density and noxious gas, it can be said that phenol foam has both comparatively good safety and high possibility of application than polyurethane foam in the building fire of sandwich panel structure because of lower smoke density and noxious gas.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.277-278
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• 2018

Improvement of insulation performance of buildings is a major part. Adiabatic method The adiabatic method minimizes the heat loss of the building. External insulation uses insulation to prevent fire. Ambient air hazards are less prone to fire. When a fire occurs, a phenolic pattern is formed and bond strength with the wall increases. EPS insulation and phenol foam were used to compare external heat transfer and external heat transfer. The heat transfer properties of phenolic foam and styrofoam were evaluated as follows. In the mortar and styrofoam structure, the problem of styrofoam reaching the burning point occurred before the collapse of the mortar, and the phenol foam had a problem in that when the direct fire was continued on the phenol foam. The characteristics of continuous infiltration appeared. In the case of mortar and phenol foam + styrofoam, the heat penetrated into the interior due to the shrinkage due to the shrinkage of the carbon screen on the phenol foam. However, when reinforced with glass mesh on the outer surface, And to reduce infiltration.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.30-34
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• 2016

In this study, we synthesized a phenol foam using a resol-type phenol resin as a research for replacing the polyurethane foam used as an insulator for cryogenic temperature, such as LNG or LPG. Foaming agents for synthesizing a phenolic foam was used HCFC-141b or n-pentane, cyclopentane, n-hexane, cyclohexane and a mixture of HFC-365mfc and HFC-227ea respectively. Cyclohexane as a blowing agent exhibited the most superior insulating performance and compressive strength. The heat resistance of polyurethane foam and phenolic foam blown by the cyclohexane, was higher than polyurethane foam.

• Applied Chemistry for Engineering
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• v.17 no.4
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• pp.357-360
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• 2006

In this study, we studied the physical properties and application of PF foam as heat insulating materials. In the experimental results, the density of PF foam showed $0.030g/cm^3$ and the thermal conductivity showed $0.026kcal/m.h.^{\circ}C$. Also, thermal resistance of the prepared PF foam was volatilized about 71.7 wt% when the temperature was $500^{\circ}C$ (1 h). And the chemical structure of PF foam have a closed cell type in the important properties as heat insulating materials. Therefore, it was confirmed that the prepared PF foam had excellent performance as heat insulating materials.

• Fire Science and Engineering
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• v.24 no.1
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• pp.122-127
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• 2010

The combustion characteristics of phenol foam were analysed using variable external irradiation level (20, 25, 35, 50, and $70kW/m^2$) and in the mixture gas of oxygen/nitrogen. The oxygen index were carried out from the oxygen index tester (KS M ISO 4589-2) and ignition time, critical heat flux, and mass loss rate were carried out from the mass loss calorimeter (ISO 5660-1). As the results of this study, the critical heat flux and average mass loss rate were $28.99kW/m^2$ and $0.56{\sim}1.77g/m^2s$ respectively at the variable external irradiation level. And the limited oxygen index were 45.1% in mixture gas of oxygen/nitrogen. In conclusion, we knew that phenol foam had the best performance than other foam materials in fire safety from all data of this study.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.539-543
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• 2014

Foam type porous silicon carbide ceramics were fabricated by a polymer replica method using polyurethane foam, carbon black, phenol resin, and silicon powder as raw materials. The influence of the C/Si mole ratio of the ceramic slurry and heat treatment temperature on the porous silicon carbide microstructure was investigated. To characterize the microstructure of porous silicon carbide ceramics, BET, bulk density, X-ray Powder Diffraction (XRD), and Scanning Electron Microscope (SEM) analyses were employed. The results revealed that the surface area of the porous silicon carbide ceramics decreases with increased heat treatment temperature and carbon content at the $2^{nd}$ heat treatment stage. The addition of carbon to the ceramic slurry, which was composed of phenol resin and silicon powder, enhanced the direct carbonization reaction of silicon. This is ascribed to a consequent decrease of the wetting angles of carbon to silicon with increasing heat treatment temperature.

• Journal of the Korean Ceramic Society
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• v.49 no.3
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• pp.236-240
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• 2012

The reticulated carbon foam have been used for their excellent properties in terms of thermal management which is getting important in industrial field currently. In this study, we measure the mechanical properties of the reticulated carbon foam which is heat-treated at various temperature from the prepared low-density phenol foam. Simultaneously, we observe microstructures with high resolution transmission microscope and measure the residual oxygen content of carbon foams to figure out the relationship between the apparent change of properties such as weight loss and linear shrinkage during heat treatment. In conclusion, the carbon foam heat-treated at $1400^{\circ}C$ shows the highest strength, and the mechanical behavior is believed to be strongly related to the creation of nano-size graphite crystals from the amorphous carbon during heat treatment. On the other hand, it is turned out that the weight loss occurred at the temperature under $1400^{\circ}C$ comes from the elimination of oxygen in the form of $CO_2$ or CO, but no evidence is found on weight loss mechanism at the temperature above $1400^{\circ}C$.

• Carbon letters
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• v.13 no.2
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• pp.94-98
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• 2012

Herein, macroporous carbon foams were successfully prepared with phenol and formaldehyde as carbon precursors and an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ($BMIPF_6$), as a pore generator by employing a polymerization-induced phase separation method. During the polycondensation reaction of phenol and formaldehyde, $BMIPF_6$ forms a clustered structure which in turn yields macropores upon carbonization. The morphology, pore structure, electrical conductivity of carbon foams were investigated in terms of the amount of the ionic liquid. The as-prepared macroporous carbon foams had around 100-150 ${\mu}m$-sized pores. More importantly, the electrical conductivity of the carbon foams was linearly improved by the addition of $BMIPF_6$. To the best of the author's knowledge, this is the first result reporting the possibility of the use of an ionic liquid to prepare porous carbon materials.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.417-422
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• 2021

In this study, poly isocyanurate foam (PIR), poly urethane foam (PUR), and phenol foam (PF) of organic insulation materials were selected, and investigated using a cone calorimeter, as per ISO 5660-1. Standard materials (PMMA) were used to standardize the fire hazard assessment, and the fire risk was classified and evaluated by Chung's equations-III and IV. The fire performance index-II value of Chung's equations-II was the highest value with PF of 14.77 s²/kW. And the PUR was 0.08 s²/kW, the lowest value of fire performance index-II value. The fire growth index-II value was the lowest value with PF of 0.01 kW/s². And the PUR was 1.14 kW/s², the highest value of fire growth index-II value. The fire performance index-III (FPI-III) of Chung's equations-III had the lowest value for PUR (0.11) and the highest for PF (20.23). The PUR showed the highest value of the fire growth index-III (FGI-III) as 14.25, while the PF exhibited 0.13 regarded as the safest materials. The fire risk index-IV (FRI-IV) value of Chung's equation-IV was in the following order: PUR (130.03) >> PIR (19.13) > PMMA (1.00) > PF (0.01). Therefore, it was concluded that the fire risk associated with PF is the lowest, whereas that associated with PUR is the highest.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.137-138
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• 2019

To overcome the limitation in relation to thermal insulator's selection and installation method that is suitable for exterior insulation and waterproof construction methods, a production basis of thermal insulators of which manufacturing knowhow is held by companies was ensured and future-oriented construction methods to adopt new materials were applied. Performance verification was conducted through performance and mock-up tests of thermal transmittance on the cross sections where the flexible insulators were applied based on the improved prototype and performance data were obtained. To overcome the biggest drawbacks (walking feeling and damage etc.) in the exterior insulation and waterproof construction method, inserting a protective layer between thermal insulator and water-proof layer was proposed, and polypropylene corrugated cardboards.