• Title/Summary/Keyword: phase behavior

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High Temperature Deformation Behavior of Beta-gamma TiAl Alloy (Beta-gamma TiAl 합금의 고온변형거동)

  • Kim, J.S.;Kim, Y.W.;Lee, C.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.429-433
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    • 2006
  • High Temperature deformation behavior of newly developed beta-gamma TiAl alloy was investigated in this study. The optimum processing condition was investigated with the aid of Dynamic Materials Model (DMM). Processing maps representing the efficiency of power dissipation for microstructural evolution and instability were constructed utilizing the results of hot compression test at temperatures ranging from $1000^{\circ}C$ to $1200^{\circ}C$ and strain rate ranging from $10^{-4}/s$ to $10^2/s$. The Artificial Neural Network (ANN) simulation was adopted to consider the deformation heating. With the help of processing map and microstructural analysis, the optimum processing condition was presented and the role of $\beta$ phase was also discussed in this study.

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Comparison Analysis of Behavior between Differential Equation and Fractional Differential Equation in the Van der Pol Equation (Van der Pol 발진기에서의 미분방정식과 Fractional 미분방정식의 거동 비교 해석)

  • Bae, Young-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.11 no.1
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    • pp.81-86
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    • 2016
  • Three hundred years ago, the fractional differential equation that is one of concept of fractional calculus released. Now, many researchers continue to try best effort applying into the control engineering, mathematics and physics. In this paper, the dynamics equation which is represented by Van der Pol, represent integer order and fractional order that having real order. Then this paper performs the comparisons between integer and real order as time series and phase portrait according to variation of parameter value for real order.

Sintering Behavior of Zirconium Diboride wth Addition of Titanium Boride (붕화 티탄 첨가에 의한 붕화지르코늄의 소결거동)

  • 우상국;한인섭;홍기석;장병구;양준환;김종희
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1099-1106
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    • 1997
  • In the present study, the effect of TiB2 addition on the sintering behavior of ZrB2 ceramics was studied with hot pressing under Ar atmosphere. Hot pressing experiments were carried out in graphite dies at the 1$700^{\circ}C$, 180$0^{\circ}C$ under Ar atmosphere. The sintering density increased with increasing TiB2 contents. With the addition of 10wt% TiB2 almost theoretical density could be achieved by hot-pressing at 180$0^{\circ}C$. Zr-Ti-Fe-B compound in liquid phase was observed from the EDS and WDS analysis. It was considered that sinterability was enhanced due to the mass transfer through liquid phase formed at the sintering temperature. In addition of TiB2, transition metal of groups IV, substitutional solid solution could be formed.

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Effect of Sn Addition on Corrosion Behavior of Mg-4%Zn Casting Alloy (Mg-4%Zn 주조 합금의 부식 거동에 미치는 Sn 첨가의 영향)

  • Han, Jin-Gu;Jun, Joong-Hwan
    • Journal of Korea Foundry Society
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    • v.37 no.3
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    • pp.63-70
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    • 2017
  • In the present study, effects of an addition of Sn on the microstructure and corrosion behavior were investigated in Mg-4%Zn-(0-3)%Sn casting alloys. With an increase in the Sn content, the ${\alpha}-(Mg)$ dendritic cell size was reduced, whereas the total amount of precipitates increased due to the formation of the $Mg_2Sn$ phase. It was found in immersion and electrochemical corrosion tests that the addition of Sn has a detrimental effect on the corrosion resistance of the Mg-4%Zn alloy. Microstructural examinations of the corrosion product and the corroded surface indicated that an accelerated micro-galvanic effect by the $Mg_2Sn-phase$ particles and a less protective corrosion product on the surface were responsible for the increased corrosion rate at a higher Sn content.

Suitable Use of Capillary Number for Analysis of NAPL Removal from Porous Media

  • Jeong, Seung-Woo,
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.25-28
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    • 2004
  • The capillary number is used to represent the mobilization potential of organic phase trapped within porous media. The capillary number has been defined by three different forms, according to types of flow velocity and viscosity used in the definition of capillary number. This study evaluated the suitability of the capillary number definitions for representing TCE mobilization by constructing capillary number-TCE saturation relationships. The results implied that the capillary number should be correctly employed, according to interest of scale and fluid flow behavior. This study suggests that the pore-scale capillary number may be used only for investigating the organic-phase mobilization at the pore scale because it is defined by the pore-velocity and the dynamic viscosity. The Newtonian-fluid capillary number using Darcy velocity and the dynamic viscosity may be suitable to quantify flood systems representing Newtonian fluid behavior. For viscous-force modified flood systems such as surfactant-foam floods, the apparent capillary number definition employing macroscopic properties (permeability and potential gradient) may be used to appropriately represent the desaturation of organic-phases from porous media.

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Behavior of Isolated Pores during Liquid Phase Sintering of $MgO-CaMgSiO_4$ System ($MgO-CaMgSiO_4$ 계 액상소결중의 고립기공거동)

  • 송병무;김정주;김도연
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.7-12
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    • 1985
  • A theoretical model describing the behavior of isolated pores during liquid phase sintering was developed and the experimental results obtained by the $80MgO-CaMgSiO_4$ specimens were given. Most of isolated pores once formed in the interior of specimen were not eliminated because the pressure of trapped non-diffusable gas in the pore like $N_2$ increases very rapidly with pore volume contraction. As sint-ering time increase it was observed that the number of pores decreases whereas the average size of pore increases. This phenomenon was interpreted in terms of the MgO growth during sintering which results in the coalescence of isolated pores. The increase of pore size resulting from pore coalescence was attributed to the main cause of the overfiring phenomena ; the higher sintering temperature or a long time sintering leads to a decrease in density.

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Low Temperature Synthesis of Willemite Powder (Willemite 분말의 저온합성)

  • Son, Se-Gu;Lee, Ji-Hyeon;Lee, Jeong-Mi;Kim, Young-Do
    • Journal of the Korean Ceramic Society
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    • v.45 no.7
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    • pp.401-404
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    • 2008
  • Willemite ($Zn_2SiO_4$) are a wide range of applications such as a phosphor host and an important crystalline phase in glass ceramics, electrical insulators, glazes, and pigments. In this study, Willemite precursors were synthesized with zinc silicate gels from mixture of zinc nitrate solution and various sodium silicate solution by the geopolymer technique. To examine the crystallization behavior, precursors were have been monitored by the XRD. A pure willemite phase was obtained at $900^{\circ}C$. TEM investigations revealed that the sample with 50 nm particle size was obtained via heat-treated at $900^{\circ}C$ for W-3.

Modeling of Diesel Spray Impingement on a Flat Wall

  • Lee, Seong-Hyuk;Ryou, Hong-Sun
    • Journal of Mechanical Science and Technology
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    • v.14 no.7
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    • pp.796-806
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    • 2000
  • To understand the transient behavior of droplets after impingement in a diesel engine, a numerical model for diesel sprays impinging on a flat wall is newly developed by the proposition of several mathematical formulae to determine the post-impingement characteristics of droplets. The new model consists of three representative regimes such as rebound, deposition and splash. The gas phase is modeled in terms of the Eulerian conservation equations, and the dispersed phase is calculated using a discrete droplet model. To validate the new model, the calculated results are compared with several experimental data. The results show that the new model is generally in good agreement with the experimental data. Therefore, it is thought that the new model is acceptable for the prediction of transient behavior of wall sprays.

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Analysis for Densification Behavior and Grain Growth of Nanocrystalline Ceramic Powder under High Temperature (나노 세라믹 분말의 고온 치밀화와 결정립 성장의 해석)

  • Kim, Hong-Gee;Kim, Ki-Tae
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.363-368
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    • 2000
  • Densification, grain growth, and phase transformation of nanocrystalline ceramic powder were investigated under pressureless sintering, sinter forging, and hot pressing. A constitutive model for densification of nanocrystalline ceramic powder was proposed and implemented into a finite element program (ABAQUS). A grain growth model was also proposed by including the effect of applied stress on grain growth when phase transformation occurs. Finite element results by using the proposed models well predicted densification behavior, deformation, and grain growth of nanocrystalline titania powder during pressureless sintering, sinter forging, and hot pressing.

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Age-Hardening Behavior and Structural Changes in a Commercial Dental Au-Ag-Cu-Pd Alloy

  • Kim, Hyung-Il;Park, Seok-Kyu
    • Journal of Biomedical Engineering Research
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    • v.15 no.4
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    • pp.389-394
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    • 1994
  • The age-hardening behavior and the structural changes in a commercial dental Au-Ag-Cu-Pd alloy were investigated by means of hardness test, optical and scanning electron microscopic observation, energy dispersive spectroscopy and X-ray diffraction study. The drastic reduction in hardness by prolonged aging occurred after a rapid increase in hardness at the initial stage by the isothermal aging at $350^{\circ}C$. This softening was due to the broad precipitates formation of the lamellar structure which was composed of the f.c.t. AuCu I ordered f.c.t. phase containing Pd and the f.c.c. Ag-rich $\alpha$1 solid solution f.c.c.phase containing Au.

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