• Title/Summary/Keyword: phase behavior

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Preparation of PVDF Membrane by Thermally-Induced Phase Separation

  • Heo, Chi-Haeng;Lee, Kyung-Mo;Kim, Jin-Ho;Kim, Sung-Soo
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.27-33
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    • 2007
  • PVDF membrane formation via TIPS was performed for PVDF/DBP and PVDF/DMP systems. PVDF/DBP system showed solid-liquid phase separation behavior, while PVDF/DMP system has liquid-liquid phase separation characteristic as well as solid-liquid phase separation characteristic. PVDF contents and cooling conditions had great influence on structure, and the effects of each parameter were examined. Spherulitic structure was obtained due to the dominant PVDF crystallization. Diluent rejected to the outside of spherulite occupied the surface of the PVDF spherulites to result in the microporous spherulite formation and micro-void between spherulites. PVDF/DMP system had competitive solid-liquid and liquid-liquid phase separation depending on the cooling path.

Microstructure and deformation behavior of nanostructured dual-phase steel (나노 결정립 이상 조직강의 미세조직 및 변형거동)

  • Ko, Y.G.;Lee, K.M.;Lee, C.W.;Kum, D.H.;Shin, D.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.445-448
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    • 2009
  • The present work deals with microstructure and tensile deformation of nanostructured dual-phase steel consisting of ferrite and martensite phases. Prior to deformation, a fully martensite phase is prepared and then processed by equal channel angular pressing (ECAP) and subsequent annealing. Room-temperature tensile properties are examined and compared to those of dual-phase steels with coarse grains. Due to the combined effects coming from the grain refinement of both phases and their uniform distributions, the nanostructured dual-phase steel exhibits better strength and ductility than coarse grained counterpart, achieving ${\sim}1\;GPa$ and ${\sim}20%$ for tensile strength and elongation, respectively.

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Irradiation-induced BCC-phase formation and magnetism in a 316 austenitic stainless steel

  • Xu, Chaoliang;Liu, Xiangbing;Xue, Fei;Li, Yuanfei;Qian, Wangjie;Jia, Wenqing
    • Nuclear Engineering and Technology
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    • v.52 no.3
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    • pp.610-613
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    • 2020
  • Specimens of austenitic stainless steel were irradiated with 6 MeV Xe ions to two doses of 7 and 15 dpa at room temperature and 300 ℃ respectively. Then partial irradiated specimens were subsequently thermally annealed at 550 ℃. Irradiation-induced BCC-phase formation and magnetism were analyzed by grazing incidence X-ray diffraction (GIXRD) and vibrating sample magnetometer (VSM). It has been shown that irradiation damage level, irradiation temperature and annealing temperature have significant effect on BCC-phase formation. This BCC-phase changes the magnetic behavior of austenitic stainless steel. The stress relief and compositional changes in matrix are the driving forces for BCC-phase formation in austenitic stainless steel during ion irradiation.

Phase Behavior of Reversibly Associating Star Copolymer-like Polymer Blends

  • June Huh;Kim, Seung-Hyun;Jo, Won-Ho
    • Macromolecular Research
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    • v.10 no.1
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    • pp.18-23
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    • 2002
  • We theoretically consider blends of two monodisperse one-end-functionalized homopolymers (denoted by A and B) capable of forming clusters between functional groups (stickers) using weak segregation theory. In this model system resulting molecular architectures via clustering resemble star copolymers having many A- and B-arms. Minimizing the total free energy with respect the cluster distribution, the equilibrium distribution of clusters is obtained and used for RPA (Random Phase Approximation) equations as input. For the case that polymers are functionalized by only one kind of sticker, the phase diagrams show that the associations promote the macrophase separation. When there is strong affinity between stickers belonging to the different polymer species, on the other hand, the phase diagram show a suppression of the macrophase separation at the range of high temperature regime, as well as the phase coexistence between a disordered and a mesoscopic phase at the relatively lower temperatures.

Chromatographic Separation of Some Phenol Derivatives Using $\alpha$-Cyclodextrin in Mobile Phase ($\alpha$-씨클로덱스트린을 이동상으로 사용한 몇 가지 페놀 유도체들의 크로마토그래피적 분리)

  • 문영자;김봉희
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.75-84
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    • 1997
  • Chromatographic retention behavior and separation of various phenol derivatives on a Partisil 10 ODS 3 column-with mobile phase containing $\alpha$-cyclodextrin-were systematically studied. The decrease in k' values caused by the addition of cyclodextrins in the mobile phase was based on the formation of an inclusion complex, resulting in weakening of the hydrophobic interaction between solutes and the stationary phase. The content of the organic solvent in the mobile phase also influenced k' values of the solutes, and k' values increased with a decrease of the content of organic solvent in the mobile phase. A simple equation has been derived that reveals the hyperbolic dependence of the capacity factor on the total concentration of cyclodextrin. A plot of the reciprocal of the capacity factor against (CD)$_T$ gives a straight line and the dissociation constant, K$_D$, of the inclusion complex can be calculated from the slope. The capacity factor decreased with increasing temperature. The enthalpy was calculated from the slope of van't Hoff plots. Under optimum conditions, some mixtures of phenol derivatives were able to separated successfully.

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Purification and Characterization of Crystalins by Aqueous Two-Phase Extraction

  • Bermudez, Ondrea;Forciniti, Daniel
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.6
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    • pp.395-401
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    • 2001
  • Crystallins are a family of water-soluble proteins that constitute up to 90% of the wa-ter-soluble proteins in mammalian eye lenses, We present in this paper an alternative purification method for these proteins using polyethylene glycol/dextran aqueous two-phase extraction. Un-der the appropriate conditions, we were able to recover the γ-crystallin fraction essentially free of the remaining proteins. High concentrations of salt at a neutral pH maximize the recovery of γ-crystallins in the top phase and minimize the contamination by the other proteins present in the lenses. The proposed protocol decreases the separation time by about 50%. The complex partition behavior observed for these proteins reflects a delicate balance between protein/phase-forming species(various polymers and salts) and protein interactions. This is evidenced, in part, by the role played by the largest proteins in this group as a "pseudo"phase-forming species.

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Phase Modulation Efficiency of the Electrooptic Modulator using GaAs/AlGaAs (GaAs/AlGaAs을 이용한 전계광학 변조기의 위상변조 효율)

  • 최왕엽;박화선;이종창;변영태;김선호
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.11a
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    • pp.192-193
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    • 2002
  • In this paper we investigate the phase modulation efficiency in the electrooptic phase modulator using PPpinNN GaAs/AlGaAs W-type waveguide. The phase change is affected by the refractive index change taking place inside the depletion region. The behavior of the modulator can be understood in terms of two electric field-related and two carrier-related effects linear electrooptic, quadratic electrooptic, plasma, and bandgap shift. As a result, the phase modulation efficiency was measured about 34.6($^{\circ}$/V$.$mm) for the TE polarized light. The quadratic electrooptic coefficient R 5.82${\times}$10$\^$-15/($\textrm{cm}^2$/V$^2$) is Obtained ant the Phase efficiency Caused by the quadratic electrooptic effect is about 10 times larger than that from the conventional linear electrooptic effect.

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