• Title/Summary/Keyword: phase II system

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Analysis of Medicinal Plants in Cosmetics(II) The HPLC Separation and Quantitation of Artemisia Extract in Cosmetic SOAP (화장품중 생약성분의 분석(II) 화장비누중의 쑥추출액의 함량분석)

  • Im, Ho-Bin;Choe, Sang-Won;Kim, Jin-U
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.16 no.1
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    • pp.40-46
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    • 1990
  • A method was described for the analysis of Artemisia extract in cosmetic soap. Esculetin-6-methylether was used as indicator ingredient for analysis of Artemisia extract. It was isolated from the plant and purified with silicagel column. The structure was conformed with IR, NMR and MASS spectroscopy. The Artemisia extract in sample was isolated with chloroform and interfering com- pounds were eliminated with silicagel column. The Artemisia extract was determined by reverse phase high- performance liquid chromatography with a fluorescence detector and a solvent system of H2O/THF/MeOH. The recorveries of Artemisia extract were 93.9-106.1% in the cosmetic soap.

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The Relationship between the Mineral Characteristics and Spectral Induced Polarization for the Core Rock Samples from the Gagok Skarn Deposit (가곡 스카른 광상의 암석시료에 대한 광물특성과 광대역 유도분극 반응과의 관련성)

  • Heo, Seo-Young;Oh, Ji-Ho;Yang, Kyoung-Hee;Hwang, Jin-Yeon;Park, Sam-Gyu
    • Economic and Environmental Geology
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    • v.45 no.4
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    • pp.351-363
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    • 2012
  • In order to develop the evaluation techniques for the potential sulfide ore reserves, the relationships between the modal vol.%, grain sizes and textural characteristics of the constituent minerals (e.g., sulfides, oxides and skarn minerals) and the Spectral Induced Polarization (SIP) phase differences are examined for the nine rock cores collected from the Gagok Pb-Zn skarn deposit. The Gagok Pb-Zn skarn deposit occurs mainly along the intrusive contact between the Cretaceous granitic rocks and Cambrian Myobong slate and Pungchon limestone. The nine rock cores have been grouped into three showing distinctive SIP phase differences: the highest (Group I), intermediate (Group II) and lowest (Group III). In relation with the modal vol.% of minerals, Group I is characterized by higher pyrrhotite (25-38 vol.%) and amphibole (40-55 vol.%); Group II by intermediate pyrrhotite (7-13 vol.%) and higher garnet (44-68 vol.%); and lower pyrrhotite (1-7 vol.%) and higher pyroxene (24-66 vol.%) stand for Group III. Furthermore, the grains of all the major constituent minerals become smaller from Group I (<5 mm) through Group II (<2.5 mm) to Group III (<1.6 mm). In particular, the pyrrhotite contents and their grain sizes show logarithmic correlation with the SIP phase differences, Although we present here the results solely from nine samples, the systematic interrelations especially for pyrrhotite indicate the potential ability of SIP measurements as a new mine-evaluation technique for the sulfide ore reservoir.

Development of Marine Virus-like Particles Live/Dead Determination Method for the Performance Evaluation of Ballast Water Treatment System (선박평형수처리장치 성능 평가를 위한 해양 바이러스 생사판별 방법 개발)

  • Hyun, Bonggil;Woo, Joo-Eun;Jang, Pung-Guk;Jang, Min-Chul;Lee, Woo-Jin;Bae, Mi-Kyung;Shin, Kyoungsoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.431-438
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    • 2021
  • To prepare more stringent regulations for USCG Phase II ballast water management, this study investigated the staining efficiency of SYBR Green I(SGI) and SYBR Gold(SG) on the virus-like particle (VLP). A dye with high staining efficiency was applied to the treated water that was passed through the ballast water treatment system (BWTS). VLP staining was observed most clearly under the 100-fold and 200-fold dilution of the stock solution when the volume of filtered samples was 0.5 mL to 2 mL. The staining efficiency of SGI and SG did not show a significant difference. On the other hand, the green fluorescence of viruses in the sample stained with SGI was more pronounced than in the samples stained with SG (expressed yellow fluorescence), making it easier to observe. The abundance of VLP in the test water and control water treatments that did not pass through the two types of BWTS (electrolysis type, UV + electrolysis type) was approximately 109 - 1010 VLP 100 mL-1. In contrast, no stained VLP was observed in the treated water treatments. Moreover, SGI was confirmed to be effectively stained under various salinity conditions, including seawater, brackish water, and freshwater. Further verification tests and development of staining methods under various BWTS are required, but the SGI staining method is believed to be a good alternative to the VLP live/dead determination of the USCG Phase II type approval test.

A Study on the Elution Behavior of Pd-Isonitroso ethylacetoacetate imine Chelates by Reversed-phase High Performance Liquid Chromatography (역상 고성능 액체 크로마토 그래피에 의한 Pd(II) - isonitrosoethylacetoacetate imine 유도체 킬레이트의 용리거동에 관한 연구)

  • Kim, Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.20-30
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    • 1993
  • Liquid Chromatographic behavior of Pd(II) in Isonitosoethylacetoacetate imine IEAA-NR: R=H, CH3, C2H5, n-C3H7, n-C4H9, C6H5-CH2) Chelates were investigated by reversed phase high performance 1iquid chromatography on Micropak MCH-5 Column using Methanol /water as mobile phase. The optimum condition for the separation of Pd-Isonitrosoethylacetoacetate imine chelates were examined with respect to the flow rate, mobile phase strength. It was found that Pd(IEAA-NR)2 chelates were eluted in an acceptable range of the capacity factor value (0 $\leq$ log k' $\leq$ 1), The dependence of the logarithm of capacity factor(k') on the volume fraction of water in mixture with in the binary mobile phase was examined. Also, the dependence of k'on the liquid-liquid extraction distribution constant in methanol-water / n-alkane extraction system was on system was invert tigated for Pd(IEAA-NR)2. Both kinds of dependence are linear, which suggests that the retention of the electroneutral metal chelates be largely due to the solvophobic effect.

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A Reliability Study of Sit-to-walk for Dynamic Balance Assessment in Stroke Patient (뇌졸중환자의 동적 균형 평가를 위한 sit-to-walk의 신뢰도 연구)

  • Kim, Da-Yeon;Choi, Jong-Duk;Ki, Kyong-Il
    • The Journal of Korean Physical Therapy
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    • v.25 no.5
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    • pp.303-310
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    • 2013
  • Purpose: The purposes of this study were to evaluate the correlation of clinical tools for assessment of balance and ability of gait, in order to discriminate the phases of sit-to-walk movement of patients with stroke using the motion analysis system, and to investigate the reliability of the phase of sit-to-walk movement according to functional ability of patients with stroke. Methods: Twenty -one patients participated (men 17, women 4) in this study. Sit-to-walk movement of all patients was recorded by the motion analysis system. Berg Balance Scale, Timed Up and Go test, Functional Reach Test, 10 meter Walk Timed Test, and Performance-Oriented Mobility Assessment were used as functional assessment tools. Results: The results of this study showed significant correlation between the phase I, II, IV and total phase duration of sit-to-walk movement and functional assessment tools. In addition, the intraclass correlation coefficient (ICC) showed high reliability in accordance with the functional ability of patients with stroke (Pearson's r 0.93 to 1.00). Conclusion: In conclusion, there is high reliability between measures of the phase of sit-to-walk movement of chronic stroke patients and the clinical assessment tool. Results of this study suggest that measurement of the phase of sit-to-walk movement can be used significantly as an intervention and a clinical tool for patients with stroke.

The Effect of Korean Red Ginseng Water-extract on Aging-related Changes in the Xenobiotic Metabolizing Enzyme System in the Liver of Rats (홍삼의 물추출물이 노화에 따른 흰쥐 간의 이물질대사 효소계에 미치는 영향)

  • Lee, Dong-Wook;Lim, Heung-Bin
    • Korean Journal of Medicinal Crop Science
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    • v.14 no.6
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    • pp.329-335
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    • 2006
  • The present study was designed to investigate aging-related effects on the activities of xenobiotic metabolizing enzymes of rat liver by dietary supplementation of Korean red ginseng water-extract. Rat did not show any discernible signs of the rejection symptoms, and blood GOT and GPT levels were not influenced by ginseng water extracts, Cytochrome 450 levels and NADPH cytochrome P45O reductase, p-450 dependent ethoxycoumarin O-deethylase, and benzphetamine N-demethylase activities were decreased with aging, however, these phase I system enzymes activities in the ginseng group of24 months were well maintained compared with normal group. But, Levels of cytochrome bs and NADH-cytochrome b$_5$ reductase activities were also decreased with aging and were not found a clear difference between two groups. Glutathione-s-transferase activity, phase II enzyme system, in liver cytosols was also decreased in old ages, but the degree of decrease was higher in normal group than in giuseng supplemented group. These results indicate that long-term supplementation of red ginseng water extracts from weaning to 24 months do not show any side effects to rats, and retard age-related deteriorations of xenobiotic metabolizing enzymes activities in old ages.

A Study on the Development of Analytical Methods and Behaviors of Environmental Pollutants(II) : Optimization for Separation of Alkylphenols by Reversed-Phase Liquid Chromatography (환경 오염물질의 정량법 개발과 거동에 관한 연구(II) : 역상 액체 크로마토그래피에서 알킬페놀류의 분리 최적화)

  • Lee, Dae Woon;Lee, Yong-Ju;Park, Young Hun;Kim, Ho Seob
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.25-31
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    • 1994
  • As for analytes which did not represent the differences of the selectivity on the stationary and mobile phase, secondary chemical equilibrium theory was applied to study pH effects on the separation of alkylphenols. Mobile phase was consisted of an aqueous sodium carbonate-bicarbonate buffer and acetonitrile. The maximum selectivity for adjacent peak pairs was predicted from those values of $k^{\prime}_{HA}/k^{\prime}_{A-}$ and ${\Delta}pK$. The optimum pH determined by this method was 11.18 pH and solvent selectivity were considered at the same time to invoke the full range of selectivity effects possible for separations. Quaternary mixture composed of methanol, acetonitrile, tetrahydrofuran and water was adjusted to optimum pH 11.18. As the statistical simplex technique of an overlapping resolution map (ORM) was used to predict the optimized solvent system. The optimum solvent, which gives complete separation of alkylphenols, was determined as follws MeOH : ACN : THF = 14.4 : 81.8 : 2.8.

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Simulation of Two-Phase Fluid Flow in a Single Fracture Surrounding an Underground LPG Storage Cavern: II. Verification of Numerical Model and Field Application (지하 LPG 저아공동에 인접한 단일절리에서의 이상유체거동해석: II. 수치모형의 검증 및 적용)

  • Han, Il-Yeong;Seo, Il-Won
    • Journal of Korea Water Resources Association
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    • v.34 no.5
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    • pp.449-458
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    • 2001
  • In order to verify the numerical model, which was developed to simulate the behavior of the two-phase fluid flow in a single fracture, the characteristic equation of relative permeability was incorporated into the developed numerical model, and the computed results were compared with the experimental results of the model test. As results of the sensitivity analysis on the roughness and the aperture size of fracture, the gas velocity was inversely proportional to the fracture roughness, and not proportional to the square of aperture size which is usually observed in single phase flow in a single fracture. The numerical model was applied to the underground LPG storage terminal in order to check the field applicability. The simultaneous flow of water and gas in accordance with the operation pressures in a single fracture near cavern was simulated by the model. It was shown that the leaked gas was able to be controlled in a single fracture neither by the pressure of operation nor by that of groundwater in case the fracture became smoother in roughness and smaller in aperture size.

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Study on Morphology Control of Polymeric Membrane with Clathrochelate Metal Complex (Clathrochelate계 금속 착물을 이용한 고분자 멤브레인 구조 제어)

  • Kim, Nowon;Jung, Boram
    • Membrane Journal
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    • v.24 no.6
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    • pp.472-483
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    • 2014
  • This study is preparation of microporous membranes by using macrocyclic metal ion complexes and extended cage complexes. It is a more favorable way to existing methods because polymer and metal ion-ligand complex system provides a fine control over the phase transition behavior. Chemical functionalization of the polar surface can be obtained. Metal-templated condensation of cyclohexanedione dioxime, hydroxyphenylboronic acid in the presence of metal salts proceeds cleanly in methanol to furnish the metal clathrochelate complexes. Organic/inorganic hybrid membranes were prepared with polyethersulfone (PES), polyvinylpyrrolidone (PVP), ethyleneglycol butyl ether (BE), metal clathrochelate s and DMF by using nonsolvent induced phase inversion method. The structure of membranes was characterized with scanning electron microscopy (SEM) and microflow permporometer. The addition of Fe(II) clathrochelate complex with p-hydroxyphenyl group leads to changes of membrane morphology such as narrow mean pore size distribution, increase of surface pore density and decrease of the largest pore size.

Sailing Characteristics of a Model Ship of Weis-Fogh Type (Weis-Fogh형 모형선의 주행특성)

  • Ro, Ki-Deok;Seok, Jae-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.1
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    • pp.45-52
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    • 2010
  • A model of the propulsion mechanism, I, II, III was based on a two-dimensional model of the Weis-Fogh mechanism and consisted of one or two wings in a square channel. The sailing and vibration performance characteristics of model ships were tested to compare with each other. we took results as follow. Thrust of propulsion model, I and III was increased by 31% and 43%, the speed of model ship by 20% and 23%, When compared to model II in same condition. The thrust improvement using the elastic spring wing was effective not only on all models but also in the real ship. The maximum amplitude and RMS were largest at the opening angle ${\alpha}=15^{\circ}$ and smallest at ${\alpha}=30^{\circ}$ on the vibration of model ship. The thrust of propulsion model III with opening angle ${\alpha}=30^{\circ}$, phase ${\Delta}T=0^{\circ}$ was large, but the amplitude of vibration was small relatively.