• 제목/요약/키워드: petrochemistry

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석유화학 공정에 적용하기 위한 산업프로토콜 개선방법 연구 (A Study on the Method of Industrial Protocol Improvement for Application in Petrochemistry Process)

  • 심현;문지훈;이규수;오재철
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 심포지엄 논문집 정보 및 제어부문
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    • pp.128-130
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    • 2007
  • The research degined model which was integrated Cache technical for improvement of modebus protocol. The mode bus it leads and it does not solve in existing to shorten the tank data computing time. It desigine the algorithm which discriminates the shift time of the petrochemistry process tank m following. It is an objective of dissertation.

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석유화학용 Ball Valve 유동 및 강도 수치해석 (A Numerical Analysis on Flow and Strength of Ball Valve for petrochemistry)

  • 이중섭;정휘원;장성철;남태희;박중호;윤소남
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 동계학술발표대회 논문집
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    • pp.357-362
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    • 2008
  • This study have goal with reverse engineering for petrochemistry of high pressure ball valve for localization. Ball valve for development accomplished with flow analysis based on provision of ANSI B16.34, ANSI B16.10, ANSI B16.25 In order to localize the petrochemistry high pressure control valve. Numerical simulation using CFD(Computational Fluid Dynamic) in order to predict a mass flow rate and a flow coefficient form flow dynamic point of view. The working fluid assumed the water($H_2O$). The valve inlet and outlet setup a pressure boundary condition. The outlet pressure was fixed by atmospheric pressure and calculated inlet velocity 5m/s. CFD solver used STAR-CCM+ which is commercial code. The result shows change of mass flow rate according to opening and closing angle of valve. Flow decrease observed open valve that equal percentage flow paten which is general inclination of ball valve. The structural analysis used ANSYS which is a commercial code. Stress analysis result of internal pressure in valve showed lower than yield strength. This is expect to need more detail design and verification for stem and seat structure.

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파주(波州) 산성화성암체(酸性火成岩體)의 암석학적(岩石學的) 연구(硏究) (Petrology and Petrochemistry of Pajoo Acidic Igneous pluton)

  • 오민수
    • 자원환경지질
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    • 제11권1호
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    • pp.1-9
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    • 1978
  • The study is on petrology and petrochemistry of Pajoo Acidic Igneous pluton which intruded into Precambrian metasediments of basement of the area. The geologic sequence of studied area was shown in table 1 and 10 modal analyses and 7 chemical analyses on the rock samples taken from the body. Pajoo Acidic Igneous rock consist of hypersthene-quartz-diorite and porphyritic adamellite which based on the classification of the subcommision on systematics of igneous rocks of IUGS. And porphyritic adamellite which occured as a small stock was intruded into hypersthene quartz diorite. The rock forming minerals of hypersthene quartz diorite are composed of plagioclase, perthite, quartz, hypersthene, hornblende, biotite and porphyritic adamellite is composed of perthite, quartz, plagioclase and biotite. And the former is hypidiomorphic granular texture and later is porphyritic texture with microcline phenocrysts. In silica-oxides variation diagram, the Pajoo acidic igneous rocks are similar to the trend of Daly's average composition and equivalent to the calc-alkalic rock series. In AMF diagram, these rocks are stock of fissure filling vein type by cooling in magmatic differentiation.

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경산칼데라 동부지역에 분포하는 백악기 화산암류의 암석학적 특징 (Petrology of the Cretaceous Volcanic Rocks in Eastern Part of the Kyeongsan Caldera)

  • 박성옥;장윤득;황상구;김정진
    • 암석학회지
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    • 제15권2호
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    • pp.90-105
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    • 2006
  • 연구지역의 백악기 화산암류는 경산 칼데라의 동부지역에 분포하고 있다. 연구지역의 화산암류는 층서적인 하위에서 상부로 안산암 I, 안산암질 응회암, 안산암 II, 안산암질 각력 응회암 그리고 안산암질 반암으로 구성된다. 안산암 I은 암색, 조직, 반정광물, 암석화학에서 안산암 II와 구분된다. 안산암 I은 치밀하고 암녹색을 띠나 안산암 II는 적색이며 반상조직을 보인다. 안산암 I은 $SiO_2$$K_2O$의 함량이 낮으며 사장석과 휘석반정 외에 감람석 반정을 가지는 것이 특징이며, 안산암 II는 $SiO_2$$K_2O$의 함량은 높은 반면에 CaO, MgO, MnO, $TiO_2,\;Fe_2O_3$, 및 $P_2O_5$의 함량은 낮다. 주원소를 이용하여 분석한 연구지역 화산암의 마그마 계열은 칼크알칼리에서 알칼리계열에 이르기까지 분산된 양상을 보여준다. 비호정 원소들은 일관되게 칼크알칼리 계열을 지시하고 있으므로 알칼리 원소의 부화는 2차적 변질에 의한 결과임을 시사하고 있다. 미량원소 판별도에 의하면 연구지역 화산암의 조구조적인 위치는 대륙연변부의 칼크알칼리 계열의 화산호인 것으로 판단된다.

1,3-부타디엔 제조 및 취급 근로자의 노출특성에 관한 연구 (Exposure Characteristics of 1,3-Butadiene Exposed Workers)

  • 최호춘;안선희;이현석;박영욱;김경순
    • 한국산업보건학회지
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    • 제19권4호
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    • pp.321-327
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    • 2009
  • 1,3-butadiene is classified as suspected human carcinogen, group A2(American Conference of Governmental Industrial Hygienists, ACGIH). In Korea, 1,3-butadiene has been used as a raw material; monomer, homopolymer, polybutadiene latex, acrylonitrile-butadiene-styrene(ABS) and styrene-butadiene rubber(SBR), in the petrochemistry and precision chemistry industry. As petrochemistry industry in Korea has been developed, the potential exposure possibility of 1,3-butadiene to workers can be increased. Therefore the purpose of this study is to evaluate airborne 1,3-butadiene concentration and workers' exposure levels in the workplace using 1,3-butadiene. Air samples were collected with 4-tert-butyl catechol(TBC) charcoal tube(100 mg/50 mg) and were analyzed by gas chromatograph/flame ionization detector(GC/FID) according to the Choi's method(2002). Geometric mean (GM) and arithmetic mean (AM) of total 59 workers' exposure concentrations to airborne 1.3-butadiene were 0.042 ppm and 1.51 ppm, respectively. Although most samples were lower than 1ppm, 2 samples(21.5ppm and 33.1ppm as 8hr-TWA) were exceeded the Korean standard(2ppm) over 10 times at the repair process in synthetic rubber and resin manufacture industry. 14 samples(41%) of total 34 short-term air samples were exceeded the Korean standard(10ppm as STEL) of Ministry Labor. 1,3-butadiene concentration(GM) in the synthetic rubber and resin manufacture industry(7.87ppm) was significantly higher than that in the monomer manufacure industry (0.35ppm)(p<0.05). Also in the sampling and repair process, each GM(range) was 1.39ppm(N.D.-469.6ppm) and 7.85ppm(N.D.-410.2ppm). In conclusion, it depends on the industry and process, 1,3-butadiene can be exposed to workers as high concentration for short-term.

1994년부터 2006년까지 한국 석면취급 사업장의 석면 노출농도 (Airborne Asbestos Fiber Concentration in Korean Asbestos-Related Industry from 1994 to 2006)

  • 이광용;신용철;윤충식;박두용
    • 한국산업보건학회지
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    • 제23권2호
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    • pp.123-136
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    • 2013
  • Objectives: This paper was prepapred to report airborne asbestos fiber concentrations in asbestos textile, brake-lining, commutator, and building materials manufacturing industries, and some other asbestos related industries in Korea from 1994 to 2006. Methods: Airborne asbestos data that have been sampled and analyzed in the above industries during 1994-2006 were collected. These data were reviewed to scrutinize the qualified data based on the records such as sampling and analyzed method and quality control procedures. All asbestos data were generated using the National Institute for Occupational Safety & Health (NIOSH) Method 7400. Results: Average concentration of asbestos fiber was 2.14 fibers/cc(0.02-15.6 fibers/cc) in the asbestos textile industry, 0.26 fibers/cc(0.01-1.01 fibers/cc) in the building-materials industry, 0.15 fibers/cc(0.01-0.93 fibers/cc) in the brake-lining manufacturing industry, and 0.14 fibers/cc(0.03-1.36 fibers/cc) in the commutator producing industry. For these industries, the percentage of samples of which asbestos fiber concentrations above the limit of exposure(0.1 fibers/cc) was 97.6% in the asbestos textile industry, 62.3% in the building-materials industry, 53.5% in the brake-lining manufacturing industry, and 34.3% in the commutator producing industry. Asbestos fiber concentration was below the limit of exposure in the gasket producing, petrochemistry, musical instrument producing industries, and the brake-lining exchange operations. Conclusions: Airborne asbestos fiber level in the asbestos textile, brake-lining producing, commutator and building-material producing industries was above the limit of exposure, but in the gasket producing, petrochemistry, musical instrument producing industries and the brake-lining exchange operations were below the limit of exposure.

한반도 서남부에 분포하는 중성-염기성 심성암류에 대한 암석학적 연구 (Petrological Study on the Intermediate-basic Plutonic Rocks in the Southwestern Part of the Korean Peninsula)

  • 김용준;박재봉;박병규
    • 한국지구과학회지
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    • 제27권5호
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    • pp.528-538
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    • 2006
  • 이 연구의 목적은 한반도 서남부에 분포하는 중성-염기성 심성암류의 지화학적 특성과 성인을 밝히는데 있다. 이들 중성-염기성암류는 주로 선캠브리아기의 회장암-반려암, 트라이아스기의 각섬석반려암(지리산 지역), 쥬라기의 섬록암-섬장암(지리산 지역과 북부 지역) 그리고 백악기 반려암-섬록암(남부 지역)으로 구성되어 있다. 암괴형의 회장암은 많은 관입체로 구성되어 있으며 반려암-노라이트-트록토라이트와 우백질 반려암으로 이루어진 반려암질암에 의해 관입되어 있다. 주 성분-미량 성분의 변화도, AMF 삼각도와 Pl-Px-Ol 삼각도에서, 우리는 한반도 서남부에 분포하는 중성-염기성암류가 Daly의 값과 유사한 경향을 보이며 칼크-알카리질암류에 속함을 보여준다. REE (La/Yb)cw와 Eu/Sm 값에 따르면 이들 암류는 경희토류가 중희토류보다 부화되어 있으며, 이는 대륙 연변부의 지구조에서 정치한 화성암류의 특징이다.