• Journal of environmental and Sanitary engineering
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• v.15 no.1
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• pp.102-108
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• 2000

Seasonal variation of $NO_2$ and $SO_2$ concentration was investigated at the underground shopping center in Chonan from October 1997 to August 1998. $NO_2$ and $SO_2$ was collected by personal air sampler at $0.4{\ell}/min$ and $0.5{\ell}/min$ respectively and analyzed using UV spectrophotometer at 550nm and 548nm individually. The results were as follows. 1. The concentration of $NO_2$ was 0.070 ppm in spring, 0.068 ppm in summer, 0.074 ppm in autumn and 0.085 ppm in winter. There was no significant difference. 2. The concentration of $SO_2$ was 0.0233 ppm in spring, 0.0216 ppm in summer, 0.0188 ppm in autumn and 0.0621 ppm in winter. There was significant difference (p<0.01). 3. The higher concentration of $NO_2$ and $SO_2$ gases were shown near the cafeteria (p<0.001, p<0.05). 4. The higher concentration of $NO_2$ was observed at indoor than the underground passage. There was significant difference between two values (p<0.01).

• Journal of Preventive Medicine and Public Health
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• v.20 no.2 s.22
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• pp.255-260
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• 1987

The digital dust indicator (Sibata P-5), one of the direct·reading instruments was evaluated for the respirable dust in the underground coal mine environments. As a reference, respirable dust was determined using three cyclones and/or impactors. All the tests were performed on aerosol in twenty underground coal mines. The coefficients of mass-relative concentration were $0.067{\pm}0.054$ (Mean$\pm$Standard deviation) (range: 0.006-0.172). The relationship between relative concentration and temperature was not significant statistically. Also, the relationship of relative concentration and relative humidity was not significant. Mass concentration and relative concentration were $5.31{\pm}5.22mg/m^3$ and $162{\pm}163$ CPM ($Mean{\pm}Standard$ deviation) respectively. The range of mass concentration was $1.22-22.69mg/m^3$; relative concentration 16-628 CPM. The relationship of mass concentration and relative concentration was not significant in these ranges.

• Safety and Health at Work
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• v.7 no.2
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• pp.150-155
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• 2016

Background: Shipbuilding involves intensive welding activities, and welders are exposed to a variety of metal fumes, including manganese, that may be associated with neurological impairments. This study aimed to characterize total and size-fractionated manganese exposure resulting from welding operations in shipbuilding work areas. Methods: In this study, we characterized manganese-containing particulates with an emphasis on total mass (n = 86, closed-face 37-mm cassette samplers) and particle size-selective mass concentrations (n = 86, 8-stage cascade impactor samplers), particle size distributions, and a comparison of exposure levels determined using personal cassette and impactor samplers. Results: Our results suggest that 67.4% of all samples were above the current American Conference of Governmental Industrial Hygienists manganese threshold limit value of $100{\mu}g/m^3$ as inhalable mass. Furthermore, most of the particles containing manganese in the welding process were of the size of respirable particulates, and 90.7% of all samples exceeded the American Conference of Governmental Industrial Hygienists threshold limit value of $20{\mu}g/m^3$ for respirable manganese. Conclusion: The concentrations measured with the two sampler types (cassette: total mass; impactor: inhalable mass) were significantly correlated (r = 0.964, p < 0.001), but the total concentration obtained using cassette samplers was lower than the inhalable concentration of impactor samplers.

• Analytical Science and Technology
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• v.26 no.5
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• pp.315-325
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• 2013

The possibility of acute hepatotoxicity caused by dimethylformamide (DMF) requires regular monitoring of the workers who are using DMF to prevent the occupational disease. The authors performed ambient and biological monitoring of workers involved in synthetic leather manufacturing processes using DMF to assess the correlation between the markers of ambient and biological monitoring of DMF. The authors monitored 142 workers occupationally exposed to DMF from 19 workshops in the synthetic leather and ink manufacturing industries located in northern region of Gyeonggi-do. The subjects answered questionnaire on work procedure and use of personal protective equipment to be classified by exposure type. DMF in air samples collected using personal air samplers, diffusive and active sampler, was analysed using gas chromatograph-flame ionization detector (GC-FID) with DB-FFAP column (length 30 m, i.d. 0.25 mm, film thickness 0.25 ${\mu}m$). Urinary N-methylformamide (NMF) was analysed using gas chromatograph-mass selective detector (GC-MSD) at selected ion monitoring (SIM) mode with DB-624 column (length 60 m, i.d. 0.25 mm, film thickness 1.40 ${\mu}m$). Geometric mean (GM) and geometric standard deviation (GSD) of the ambient DMF was $6.85{\pm}3.43$ ppm, and GM and GSD of urinary NMF was $42.3{\pm}2.7$ mg/L. The ratio of subjects with DMF level over 10 ppm was 44%, and those with urinary NMF over 15 mg/L was 87%. NMF in urine adjusted by DMF in air was $4.61{\pm}2.57$ mg/L/ppm and $9.50{\pm}2.41$ mg/L/ppm, respectively, with or without respirator. There was seasonal differences of NMF in urine adjusted by DMF in air, $7.63{\pm}2.74$ mg/L/ppm in summer and $4.53{\pm}2.29$ mg/L/ppm in winter. The urinary NMF concentration which corresponds to 10 ppm of ambient DMF was 52.7 mg/L (r=0.650, n=128). Considering the difference of the route of exposure which resulted from the compliance of wearing personal protective equipment, the estimated contribution of respiratory and dermal exposure route for DMF was 48.5% vs. 51.5%.

• Journal of Preventive Medicine and Public Health
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• v.26 no.1 s.41
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• pp.65-73
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• 1993

This study was carried out to evaluate the relationship between the biological lead exposure indices and air lead concentrations measured by personal air samplers. The 72 occupationally lead exposed workers were observed and the bioiogical lead Exposure indices chosen for this study were blood lead(PbB), urine lead(PbU), zinc protoporphyrin in whole blood(ZPP), $\delta$-aminolevulinic acid in urine(ALAU), $\delta$-aminolevulinic acid dehydratase activity (ALAD), coproporphyrin in urine(CPU) and hemoglobin(Hb). The workers were divided into four groups by air lead concentrations: Group I; under $0.05mg/m^3$, Group II; $0.05-0.10mg/m^3$, Group III; $0.10-0.15mg/m^3$ and Group IV; and over $0.15mg/m^3$. For evaluation the relationship between the biological lead exposure indices and air lead concentrations was used as correlation coefficients. The results obtained were as follows: 1. In Group I, II, III and IV, the mean value of PbB were $25.45{\pm}1.84{\mu}g/dl,\;27.87{\pm}3.53{\mu}g/dl,\;31.21{\pm}1.76{\mu}g/dl\;and\;47.02{\pm}13.96{\mu}g/dl$. Between Group IV and other groups showed statistically significant difference(p<0.05). 2. There was an increasing tendency of PbB, PbU, ALAU and ZPP according to the increase the mean air lead concentration, while ALAD has decreasing tendency. CPU and Hb did not show any constant tendency. 3. Correlation coefficients between PbB, PbU, ZPP, ALAU, ALAD, CPU, Hb and air lead concentration were 0.95, 0.83, 0.89, 0.72, -0.83, 0.51 and -0.45 respectively, and regression coefficient between PbB(Y) and PbA(X) was Y=126.8746X+16.9996(p<0.01).

• Journal of Preventive Medicine and Public Health
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• v.21 no.1 s.23
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• pp.132-151
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• 1988

This study was conducted to establish the control program for preventing unfavorable health effects of nitrogen dioxide($NO_2$) exposure in homes by preparing the fundamental data for evaluation of relation-ships between $NO_2$ levels and influencing factors through measurements of indoor-outdoor $NO_2$ levels and personal $NO_2$ exposures for housewives with questionnaire survey on 172 homes in Pusan area from April to June, 1987 $NO_2$ measurements were made by using diffusion tube samplers(Palmes tube $NO_2$ sampler) for one week at 4 sites in homes ; kitchen(KIT), bedroom(BED), living room(LIV), outdoor(OUT) and near the collar of housewives(personal exposure livel, PNO). The details of questionnaire were number of household members(FAM), number of regular smokers (SMOKER), daily number of meals eaten(MEAL), type of housing units(HOUSE), location of house with distance from the heavy traffic roads as walking time(DIST), and of kitchen(KAREA), kind of cooking fuels(FUEL), cooking time of each meal(CTIME), usage of kitchen fan for cooking(FAN), type of heating facilities(HEAT) and so on of subject homes. The Obtained results were as fellows : 1) The mean $NO_2$ level was significantly higher at indoors than outdoors(p<0.01) and the kitchen $NO_2$ level was the highest with $33.7{\pm}13.6ppb$(9.5-81.5ppb). The mean personal exposure level of $NO_2$ for housewives was $20.6{\pm}8.8ppb$(3.1-46.9ppb). 2) The mean indoor $NO_2$ level was significantly higher in the group of household members above 5 than below 4(p<0.05), in detached dwellings than apartments(p<0.001), within 5 minutes of distance than over 5 minutes(p<0.001), in the group of unusing fan(p<0.001), in the group of longer cooking time(p<0.001), and it was in order of coal briquette, gas, electricity and oil by kind of cooking fuels(p<0.05). 3) Variables showing significant correlation(p<0.001) with indoor $NO_2$ level were kitchen $NO_2$ level(r=0.8677), cooking time(r=0.5921), outdoor $NO_2$ level(r=0.5192), personal $NO_2$ exposure level(r=0.4615), usage of kitchen fan(r=0.3573) and location of house(r=-0.2988) 4) As a result of multiple regression analysis, the most significant influencing variable to the kitchen $NO_2$ level was cooking time[KIT=$-0.378{\pm}11.772$(CTIME)+0.298(OUT)+3.102(FAN)], it was kitchen $NO_2$ level to the indoor $NO_2$ level[IND=6.996+0.458(KIT)+0.230(OUT)-1.127(KAREA)], and it was indoor $NO_2$ level to the personal $NO_2$ exposure level[PNO=15.562+0.729(IND)-4.542(DIST)-0.200(KIT)] 5) It was recognized that aritificial ventilation in the kitchen, suppression of unnecessary combustion and replacement of cooking fuel, as much as possible, were effective means for decreasing indoor $NO_2$ levels in homes.

• 대한예방의학회:학술대회논문집
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• 1994.02a
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• pp.585-595
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• 1994

The region of the respiratory tract where inhaled particles deposit can have important implications for the causation of local or systemic toxic effects. For most aerosols of occupational importance, respiratory tract deposition can be predicted from the aerodynamic diameter of the particles. With the advent of cascade impactors, particularly those of personal sampler size, the determination of the aerodynamic diameters of aerosols has become more common. Some limitations of cascade impactor use are well recognized (e.g., particle bounce and substrate overloading) and are generally correctable. However, two important limitations of the instruments may not be receiving adequate attention: relative humidity effects on potentially hygroscopic aerosols and the collection characteristics of fibrous aerosols as compared to their actual deposition site potential. The results of this study, when compared to results of previous controlled laboratory trials, suggest that, while potentially hygroscopic lead aerosols from lead acid battery plant operations do not appear to be affected by changes in plant environmental humidity levels, the potential - exists for significant size changes upon inhalation. Secondly, fibers were detected in aerodynamic size ranges that would be associated with deep lung deposition; however, upon microscopic examination, these same fibers would actually be predicted to deposit in the upper airways. This study suggests that the physicalchemical properties and morphological features of an aerosol should be carefully considered by industrial hygienists before cascade impactors are used in attempts to predict the effects of inhaled aerosols.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.30 no.1
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• pp.10-17
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• 2020

Objectives: This study was performed to evaluate the total dust, size-selective dust, and heavy metal concentrations generated inside and outside toll booths on an expressway and to identify the source through analysis of the components of the deposited dust. Methods: A total of 32 samples were collected from eight expressway toll booths. Each total dust sample was collected using a 37 mm PVC filter attached to a personal air sampler. Heavy metal samples were collected according to NIOSH method 7300. The size-selective dust concentrations were identified using a DustMate, and deposited dust was analyzed by WD-XRF and UHR-FE-SEM. Results: The geometric mean concentrations of the total dust inside and outside the toll booths were 337.5 ㎍/㎥ and 342.7 ㎍/㎥, respectively. The overall concentrations of TSP, PM₁₀, PM_2.5, and PM1 were higher on the outside of the toll booths, as the particle size of dust was larger, and higher in the underground passage as the dust size was smaller. The real-time analysis of the dust concentrations of TSP, PM₁₀, PM_2.5, and PM1 revealed to be higher at morning and evening times than other times because of heavy traffic. The element components of deposited dust in the toll booth were related to natural sources rather than artificial sources. Among the chemical components in the deposited dust analyzed by WD-XRF, SiO₂ was the highest. For the elements analyzed by UHR-FE-SEM, C was the highest, followed by O, and Si. Conclusions: In order to reduce the dust concentrations around toll booths on an expressway, it is necessary to periodically clean surrounding areas such as underground passages, and it is also necessary to remove deposited dust inside the toll booth from time to time.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.3 no.2
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• pp.188-193
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• 1993

Toluene in air and blood and hippuric acid in urine were checked for the 41 female workers who are exposed to toluene and have normal liver function in shoe making factories in July, 1993. Toluene in air was sampled with charcoal by personal air sampler at least 4 times and analyzed by gas chromatography. At the end of shift, blood and spot urine were collected with a vacuum tube containing EDTA and a polyethylene bottle for detecting blood toluene and urine hippuric acid and analyzed by gas chromatography and high performance liquid chromatography. Means of air and blood toluene and urine hippuric acid concentrations were 34.35ppm, 0.360mg/L, and 1.78g/g creatinine, respectively. Toluene in air showed a good correlation with hippuric acid in urine(r=0.4503) and toluene in blood(r=0.4596). The hippuric acid in urine and toluene in blood corresponded 10 exposure of 100ppm toluene in air were 2.628g/g creatinine and 0.481mg/L. Blood toluene and urine hippuric acid expected ratio were not correlated to the obesity index and working duration, however increased with age.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.1
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• pp.79-83
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• 1988

To improve working environment for the toll workers who were working at Kyungbu expressway in outskirts of Seoul and Suwon, the status of air pollution surrounding toll booth were measured from March 28 through June 14, 1986. The results were as follows: 1. The amount of TSP (total suspended particle) surrounding toll booth was directly proportional to the traffic load. The ratio of traffic load at Seoul and Suwon toll was 3.2:1 and of TSP was 2.6:1. 2. The proportion of particle larger than 5$\mum$ was 24.8 $\sim$ 34.9% of TSP at Seoul toll and 19.2 $\sim$ 32.7% at Suwon. The proportion of particle less than 2$\mum$ was 38.7 $\sim$ 51.8% of TSP at Seoul toll and 34.8 $\sim$ 54.8% at Suwon. 3. The concentration of respirable particle les than 7$\mum$ measured by personal air sampler was higher in Seoul toll booth than that of Suwon and it seems to be influenced by the exhausion of diesel engine. Especially the concentration of respirable particle of reformed toll booth with air curtain was 20% lower than unreformed one. 4. Concentration of Pb among suspended particles around Seoul toll was 5 times higher than Pb of Suwon toll. So it is considered that there were other possible pollution source of Pb beyond heavy traffic in Seoul toll area. The amount of Pb inside toll booth was extremely small but the concentration of benzo(a)pyrene showed a trend of increase according to traffic stagnation. 5. The concentration of $SO_2$ arround toll showed no difference between weekday and weekend and also showed no relation with traffic load. But the concentration of $NO_2$ was affected by traffic load.