• 제목/요약/키워드: permeation property

검색결과 130건 처리시간 0.023초

역청콘크리트의 성질과 아스팔트 시멘트 크로마토그램과의 상관관계 (Correlation between Property of Bituminous Concrete and Chromatogram of Asphalt Cement Used)

  • 김광우;연규석;박제선
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1990년도 가을 학술발표회 논문집
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    • pp.107-112
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    • 1990
  • Chromatograms of asphalt cements were observed using high pressure - gel permeation chromatography (HP-GPC). The chromatogram characterzed profile of molecular size distribution of asphalt cements. Bituminous concretes using the asphalt cements were prepared in laboratory to measure mechanical properties, tensile strength (TS) and resilient modulus (MR), in dry and wet conditions. Three sources of AC-20 Asphalt cements and one aggregates were used for GPC test and strength test. Results of mechanical property tests and GPC tests were analyzed to evaluate correlation between those two results. Regression analysis showed strong correlation between a mechanical property and sliced percent areas of GPC profile. Mathematical models were developed for estimating mechanical properties of asphalt cement concrete based on HP-GPC data.

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상전환법에 의한 다양한 기공크기를 갖는 폴리비닐리덴플루오라이드 막의 제조와 수계 및 비수계 용액 내에서의 막 성능 (Formation of Poly(vinylidene difluoride) Membranes with Various Pore Sizes by a Phase Inversion Process and Membrane Performance of Aqueous and Non-aqueous Solution System)

  • 이규호;김인철
    • 멤브레인
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    • 제15권1호
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    • pp.22-33
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    • 2005
  • 비대칭 폴리비닐리덴플루오라이드(PVDF) 막을 상전환법으로 제조하였다. 도포용액은 PVDF를 용매인 N-ethyl-2-pyrrolidone (NMP)와 비용매인 1,4-dioxane, diethyleneglycol dimethyl ether (DGDE), acetone, (equation omitted)-butyrolactone(GBL)의 혼합용매에 녹여서 제조한다. 여러 첨가제가 도포용액 특성, 투과특성과 막 구조에 미치는 영향을 조사하였다. 응고제인 물과 1,4-dioxane, DGDE, acetone과의 상용성이 NMP보다 낮아서 기공크기가 작아진다. 첨가제의 양을 조절하여 기공크기를 변화시켰다. 혼합용매(수계 및 비수계)가 막의 투과성능에 미치는 영향을 살펴보았다. 용액점도뿐만 아니라 표면장력도 용매 투과특성에 영향을 끼침을 알 수 있었다.

아스팔트 시멘트의 분자립도 분포특성에 따른 아스팔트의 성질분석 (Estimation of Bituminous Concrete Property Based on Molecular Size Distribution of Asphalt Cement)

  • 김광우;연규석
    • 콘크리트학회지
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    • 제3권1호
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    • pp.71-78
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    • 1991
  • 3종류의 AC-20 아스팔트 시멘트의 분자입자분포를 고압-겔투수 크로마토그래프(HP-GPC)를 이용하여 관찰하였다. 건조상태의 습윤상태의 인장강도와 뤠질리언계수 측정을 위하여 한종류의 골재와 아스팔트 시멘크를 사용하여 실험실에서 역청콘크리트 공시체를 제조하였다. 이들의 역학적 성질시험결과와 아스팔트 시멘트 크로마토그램의 형태를 분석하여 상호간의 관계를 조사하였다. 희귀분석 결과는 역학적 성질과 크로마토그램의 분할면적비율간에 강한 상관관계가 있음을 보여주었다. 이 희귀분석 결과로부터 수학적 추정모델이 얻어졌다. 연구결과 아스팔트 크로마토그램의 특성이 정해진 아스팔트콘크리트의 역학적 성질추정이 잘 사용될 수 있음을 보여주었다.

표면 개질된 나노복합막의 투과 특성 (Permeation Property of Surface Modified Nanofiltration Membrane)

  • 박형규;탁태문;장경국;김은영;장하원;배태현
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 춘계 총회 및 학술발표회
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    • pp.153-155
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    • 2004
  • 상전이법으로 제조된 비대칭막은 세공의 크기를 nm이하의 수준으로 줄여 주면 막 여과저항이 크게 증가하여 경제성이 떨어지는 문제점을 가지고 있다. 이에 대한 대안으로 복합막이 제조되어 사용되고 있는데, 복합막은 우수한 투과도와 높은 배제율을 달성하기 위한 적극적인 대안이 되고 있다. 정수처리 및 수질환경 분야에 사용되는 나노복합막의 경제성을 더욱 향상시키기 위해서는 나노막의 투과유속을 증가시켜야 하는데, 복합막의 투과 성능은 지지체의 특성과 스킨층을 형성시키는 기술에 의해 좌우된다.(중략)

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Gas permeation property of organic-inorganic hybrid membrane made by ion-beam irradiation

  • Kawakami, Hiroyoshi
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.90-93
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    • 2004
  • In this study, we have reported an organic-inorganic hybrid membrane, which exhibits an asymmetric structure consisted of a carbonized skin layer and a polyimide porous substructure, to synthesize a novel gas separation membrane combining high gas permeability and selectivity. Both the gas permeability and selectivity of the carbonized layer significantly enhanced when compared with those determined in the control polyimide.

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Anomalous Permeation Observed in Fluoropolymer

  • Lee, Sang-Wha
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.140-143
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    • 2004
  • Compatibility of polymeric materials governs their suitability for nearly all potential applications. An aspect of compatibility that is frequently important for fluoropolymers is their ability to isolate fluids by serving as a barrier to mass transport. This property is commonly expressed as permeability. In ideal cases, both solubility and diffusivity are constant at any given temperature and so the permeability is also a constant.(omitted)

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Sputter etching에 의한 각종 섬유의 대전방지에 관한 연구 (A Study of Anti-Static Property of Several Fibers Treated with Sputter Etching)

  • Kim, Yong Hae;Koo, Bon Sik;Cho, Yeun Chung;Koo, Kang;Son, Tae Won
    • 한국염색가공학회지
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    • 제9권6호
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    • pp.10-17
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    • 1997
  • In order to improve the anti-static property of several hydrophobic fibers by sputter etching, polyester, polypropylene and poly(p-phenylene sulfide) have been etched by sputtering in the presence of argon gas and the resulting anti-static property investigated by half time decay, the time of water permeation, weight loss rate and scanning electron microscope(SEM). The temporary change and durability of anti-static property of samples treated with sputter etching were evaluated. The results were as follows; 1) Half time decay of samples treated with sputter etching were decreased about 18~38%. According to increasing sputter etching time, half time decay is decreased. 2) The wettability and weight loss rate of treated samples were increased remarkably. According to the SEM photographs, many microcraters on the substrate surface by the sputter etching were observed. 3) Although the washing treatment and the time elapsed after treatment are allowed longer, the variation of half time decay hardly can find.

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Nitrogen Permeation Treatment of Duplex and Austenitic Stainless Steels

  • Yoo, D.K.;Joo, D.W.;Kim, Insoo;Kang, C.Y.;Sung, J.H.
    • 열처리공학회지
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    • 제15권2호
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    • pp.57-64
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    • 2002
  • The 22%Cr-5%Ni-3%Mo duplex and 18%Cr-8%Ni austenitic stainless steels have been nitrogen permeated under the $1Kg/cm^2$ nitrogen gas atmosphere at the temperature range of $1050^{\circ}C{\sim}1150^{\circ}C$. The nitrogen-permeated duplex and austenitic stainless steels showed the gradual decrease in hardness with increasing depth below surface. The duplex stainless steel showed nitrogen pearlite at the outmost surface and austenite single phase in the center after nitrogen permeation treatment, while the obvious microstructural change was not observed for the nitrogen-permeated austenitic stainless steel. After solution annealing the nitrogen-permeated stainless steels(NPSA treatment) at $1200^{\circ}C$ for 10 hours, the hardness of the duplex and austenitic stainless steels was constant through the 2 mm thickness of the specimen, and the ${\alpha}+{\gamma}$ phase of duplex stainless steel changed to austenite single phase. Tensile strengths and elongations of the NPSA-treated duplex stainless steel remarkably increased compared to those of solution annealed (SA) duplex stainless steel due to the solution strengthening effect of nitrogen and the phase change from a mixture of ferrite and austenite to austenite single phase, while the NP-treated austenitic stainless steel displayed the lowest value in elongation due to inhomogeneous deformation by the hardness difference between surface and interior.