• Title/Summary/Keyword: permeation flow

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Permeation Behavior of Semiconductor Rinsing Wastewater Containing Si Particles in Ultrafiltration System -I. Permeation Characteristics of Polysulfone Flat Plate Membrane- (Si 입자를 함유한 반도체 세정폐수의 한외여과 특성[I] -Polysulfone 평판막에 의한 투과분리-)

  • 곽순철;이석기;전재홍;남석태;최호상
    • Membrane Journal
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    • v.8 no.2
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    • pp.102-108
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    • 1998
  • Permeation behavior of the semiconductor rinsing wastewater containing Si particles was examined by ultrafiltration using the polysulfone plate membrane. The permeation flux was gradually decreased with time. It was due to the growth of cake deposited on the membrane surface and the pore plugging by Si particles. Permeation flux of cross flow type was 1.4 times higher than that of the dead end flow type. Nitrogen back flushing which is the removing method of membrane fouling was superior to the water sweeping. With nitrogen back flushing, the decrease of permeation flux due to the fouling was recovered about 85 % to the initial flux in the flat plate membrane system. The rejection rate of Si particles was about 90 % and the size of Si particle in the permeate was about 70 nm.

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The observation of permeation grouting method as soil improvement technique with different grout flow models

  • Celik, Fatih
    • Geomechanics and Engineering
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    • v.17 no.4
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    • pp.367-374
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    • 2019
  • This study concluded the results of a research on the features of cement based permeation grout, based on some important grout parameters, such as the rheological properties (yield stress and viscosity), coefficient of permeability to grout ($k_G$) and the inject ability of cement grout (N and $N_c$ assessment), which govern the performance of cement based permeation grouting in porous media. Due to the limited knowledge of these important grout parameters and other influencing factors (filtration pressure, rate and time of injection and the grout volume) used in the field work, the application of cement based permeation grouting is still largely a trial and error process in the current practice, especially in the local construction industry. It is seen possible to use simple formulas in order to select the injection parameters and to evaluate their inter-relationship, as well as to optimize injection spacing and times with respect to injection source dimensions and in-situ permeability. The validity of spherical and cylindrical flow model was not verified by any past research works covered in the literature review. Therefore, a theoretical investigation including grout flow models and significant grout parameters for the design of permeation grouting was conducted in this study. This two grout flow models were applied for three grout mixes prepared for w/c=0.75, w/c=1.00 and w/c=1.25 in this study. The relations between injection times, radius, pump pressure and flow rate for both flow models were investigated and the results were presented. Furthermore, in order to investigate these two flow model, some rheological properties of the grout mixes, particle size distribution of the cement used in this study and some geotechnical properties of the sand used in this work were defined and presented.

Permeation Behavior of Semiconductor Rinsing Wastewater Containing Si Particles in Ultrafiltration System -II. Permeation Characteristics of Tubular Membrane (Si 입자를 함유한 반도체 세정폐수의 한외여과 특성 [II] -Polyolefin 관형막에 의한 투과분리-)

  • 남석태;여호택;전재홍;이석기;최호상
    • Membrane Journal
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    • v.9 no.1
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    • pp.36-42
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    • 1999
  • Permeation behavior of the semiconductor rinsing wastewater contammg Si particles was examined by ultrafiltration using the polyolefin tubular membrane. Flux decline with time was due to the growth of Si cake deposited on the membrane surface and the pore plugging by Si particles. Cake filtration from the cross flow application is compared to the combination of pore blocking and cake filtration from the dead-end application. The cake resistance is 3.16 x $10^{12}$ -4.34 X $\times$$10^{12}$ $m^{-1}$ for the cross flow and 6.6 x $\times$$10^{12}$ -12.19 X $\times$$10^{12}$ $\times$$m^{-1}$for the dead-end flow, respectively. At the initial stage of operation, permeation flux of cross flow type was 1.7 time higher than that of the dead end flow type. Permeation flux of cross flow was about 42 e 1m2 hr and the rejection rate of Si particles was about 96 %. The average particle size of Si particle in the permeate was 20 nm.

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Evaluation of Gas Transport Parameters through Dense Polymeric Membranes by Continuous-Flow Technique (연속흐름방식에 의한 기체투과특성 측정 및 분석)

  • 염충균;이정민;홍영택;김성철
    • Membrane Journal
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    • v.9 no.3
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    • pp.141-150
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    • 1999
  • A novel permeation apparatus was developed which could make the on-line measurements of both flux transient and permeate composition in gas permeation. The measurement by using the per¬meation apparatus was based on the continuous-flow technique. The transient measurement allowed the simultaneous determinations of permeation characteristics, such as, permeability, diffusion and solubility coefficients, and activation energies only with one experiment. The apparatus performance was illustrated by conducting the permeation of pure gases through two glassy polyimides and a rubbery poly (dimethyl¬siloxane) membranes, respectively. A comparison of the permeation characteristics determined from the flux transients was made with the literature values for verifying the confidence and accuracy of the measurement. Also, the analysis of the permeation transients obtained was carried out for the close investigation of the permeation behaviors of gases through membrane.

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Gas Permeation Characteristics of Porous Alumina Membrane Prepared by Anodic Oxidation (양극산화에 의한 다공성 알루미나 막의 기체투과 특성)

  • 함영민
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.72-78
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    • 1998
  • For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

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Mechanism of Action of Various Vehicles That Enhance the Permeation of Ketoprofen (케토프로펜의 피부투과도를 증진시키는 다양한 용매의 작용기전)

  • Cho, Young-Joo;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.28 no.3
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    • pp.165-169
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    • 1998
  • The effect of various vehicles on the permeation of a model drug, ketoprofen in solution formulation was evaluated using a flow-through diffusion cell system at $37^{\circ}C$. To investigate the mechanism of permeation rate enhancement, the effects of pretreatment with various vehicles on the permeation of the drug were evaluated using 5 mg/ml solution and saturated solution. The order of permeation rate of ketoprofen across hairless mouse skin after pretreatment with various vehicles was similar to the case where the vehicles and the drug were coadministered except ethanol and oleic acid. The results indicate that the mechanism of enhancement can be direct action of the vehicles on the barrier property of the skin and/or carrier mechanism.

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Modelling and Simulation of H2 separation in Pd Membrane System with Co-current and Current-current Flow (병류와 향류 흐름에서 수소분리를 위한 Pd 분리막 시스템의 모델링 및 모사)

  • Yi, Yong;Noh, Seunghyo;Oh, Min
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.598-602
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    • 2010
  • In this paper, we carried out CFD modelling and simulation for the membrane system to separate H2 gas from the multi-component feed gas. The membrane system is of the annulus tubular type consisting of the external lumen side for the feed gas and the internal permeation side for the sweeping gas. The operating temperature and pressure of the lumen side inlet flow are $374^{\circ}C$ and 7 bar respectively and those of the sweeping gas are $374^{\circ}C$ and 3 bar, and considering these conditions, Pd membrane system was employed. CFD simulations were performed for the co-current flow and counter-current flow membrane system based on the flow directions between the feed and the sweeping gas. Comparisons and discussions were made for the H2 partial pressure, H2 mole fraction and H2 flux for both cases. Furthermore, we executed CFD simulations for the each case of the various inlet flow rates of the feed gas at the lumen side. Accordingly, we reviewed the effects of the flow rate and residence time on the performance of the membrane system.

Effect of Analytical Parameters of Gel Permeation Chromatography on Molecular Weight Measurements of Urea-Formaldehyde Resins

  • Jeong, Bora;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.4
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    • pp.471-481
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    • 2017
  • As the molecular weight (MW) of urea-formaldehyde (UF) resins had a great impact on their properties, this work was conducted to study effect of analytical parameters of gel permeation chromatography (GPC) on the MW measurement of UF resins. GPC parameters such as flow rate, column, detector temperature, and sample injection temperature were selected to compare number-average molecular weight (Mn), weight-average molecular weight (Mw), molecular weight distribution (MWD) and polydispersity index (PDI) of two UF resins with different viscosities. As expected, UF resin with higher viscosity resulted in greater Mn and Mw than those of low viscosity UF resin. When the flow rate increased, both Mn and Mw of UF resins decreased and MWD became narrower. By contrast, both Mn and Mw increased and MWD became wide when the column, detector, and sample injection temperature increased. The column, detector, and sample injection temperature of $50^{\circ}C$ at a flow rate of $0.5m{\ell}/min$ resulted in the highest MW and broadest MWD for the GPC analysis. These results suggest that the apparent molecular size or a hydrodynamic radius of UF resin molecules dissolved in the mobile phase affect to Mn, Mw and MWD.

Concentration of Citrus Essence Aroma Model Solution by Pervaporation (투과증발법을 이용한 감귤 Essence Aroma 모델액의 농축)

  • Lee Yong-Taek;Park Joong-Won;Shin Dong-Ho
    • Membrane Journal
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    • v.16 no.1
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    • pp.68-76
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    • 2006
  • This is the research about the concentration of trace citrus flavor components in water by pervaporation. We have investigated the permeation characteristics depending on the material and formation of membranes using four siloxane-based polymer composite membranes. We have also chosen the optimal membrane and investigated the permeation characteristics depending on the feed temperature, concentration and flow rate. And then it has been analyzed by using resistance-in series model. In the permeation experiment of citrus essence aroma model solution through the four siloxane-based polymer composite membranes, PVDF/POMS membranes have showed the best flavor flux and enrichment factor. As a result of the permeation experiment depending on the feed temperature, concentration and flow rate, we can find that as the feed temperature and concentration increase, the flavor flux increases while the enrichment factor decreases. And the flavor flux and enrichment factor increased as the flow rate increases.

Influence of Concentration Polarization Phenomenon on the Vapor Permeation Behavior of VOCs/$N_2$ Mixture Through PDMS Membrane (VOCs/$N_2$ 혼합물의 PDMS막을 통한 증기투과시 농도분극 현상이 투과거동에 미치는 영향)

  • 염충균;이상학;송해영;이정민
    • Membrane Journal
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    • v.11 no.1
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    • pp.50-59
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    • 2001
  • Influence of concentration polarization has been investigated on the vapor permeation of VOCs/$N_2$ mixture. Po]y(dimethylsiloxane)(PD,vIS) membrane which had a good affinit~, toward VOCs was emploj,'c'Cl in this study. The chlorinated hydmcarbons which were part of homologous series of chrolomelhane and chrolocthane were used as organic vapor. The vapor permeation experiments were calTied out at various VOCs feed concentrations. operating temperatures and feed flow rates. With decreasing feed flow rate. the membrane perfonnance, that is. penneation rate and selectivity were reduced in the permeation of VOCs/$N_2$ mixture. Especially the reducing of the membrane performance was founel to be more significant when the condensibility of voe was greater. voe content in the feed mixture was higher or operating temperature was lower. These observations were discussed in terms of the influence of con-centration polarizalion on the permeation of VOCSINl mixture through the PDMS membrane.

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