• Title/Summary/Keyword: permeability barrier

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Elastomeric High Barrier Materials for Vehicle (고차단성 자동차 부품용 고무소재)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.2-9
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    • 2011
  • Permeability to gases and vapors is an important function in tires, rubber tubes and diaphragms. It mainly depends on the rubber material. Generally, permeability increases in the following order: silicone rubber > NR > EPDM > SBR > NBR > FPM > ECO > IIR. And, for an elastomer permeability is also very much dependent on compounding. Many research works are reported in the area of gas permeability for formed rubber,$^{1-7}$ however, few studies are found for unformed elastomer products. Incorporation of nano-particles, use of thermoplastic elastomers and applying high barrier multilayer coatings are the main approaches to obtain a high barrier elastomeric product. In this paper, barrier article for vehicle is introduced.

A Study on the Textile for Protective Clothing of Fire Fighters (한국 소방대원 방수피복의 소재특성에 관한 비교 연구)

  • 정정숙;이연순
    • Journal of the Korean Home Economics Association
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    • v.40 no.5
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    • pp.15-24
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    • 2002
  • The following research conclusions were made, relative to the experiments of the textiles of fire fighters Protective Clothing. 1. When the body protection efficiency such as the thickness, the strength and heat resistance are considered, Nomex(N) is tuned out the best outer shelf, Gore-tex(KG) the best moisture barrier, and Wool-felt(WC) the best thermal barrier. 2. In the hygienic and sanitary efficiency also, N is turned out the best outer shelf, KG the best moisture barrier, and WC the best thermal barrier in its degree of water resistance, water vapour permeability, and air permeability. 3. In the washing and maintenance efficiency, too. N is turned out the best outer shell, KG the best moisture barrier, and WC the best thermal barrier, being considered the material's rate of contraction, the changing rate of frame resistance, water resistance, and water vapour permeability. 4. When considered the frame resistance against the reflection tape and reflection efficiency, O is the best material for it marks the highest score in the frame resistance and reflective effect.

Changes of Performance of Soil-Cement Barrier due to Migration of Acids (산 이동에 따른 심층혼합기둥체 차수벽의 성능변화)

  • 정문경;천찬란;이주형;김강석
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.189-196
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    • 2003
  • Soil-cement column is often used as a contaminant barrier. This study presents the results of experimental study performed to investigate the changes of properties of soil-cement column under the attack of acids. Sulfuric nitric, and ascetic acid were used as contaminants. Specimen were made of clayey and sandy soils with addition of cement and water Permeability of soil-cement decreased with time during permeability test. When significant amount of acid percolated the specimen, permeability increased and compressive strength decreased due to the dissolution and leaching of cement and its chemical reaction compounds. Sulfuric and nitric acid were more effective than ascetic acid in deteriorating soil-cement column. Amount of acid required to lower the pH of soil cement below 12 was calculated from the results of permeability tests. This leads to a conclusion that, under the conditions employed in this study, the chemical stability of soil-cement column could be maintained against acid attack for longer than generally accepted lifetime of contaminant barriers.

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The Preparation of Sol-Gel Derived Aminoalkoxysilane Films and its Application for Oxygen Barrier (솔-젤법을 이용한 aminoalkoxysilane 산소차단필름의 제조)

  • Kim, Hyun-Joon
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.3 s.16
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    • pp.17-21
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    • 2006
  • The oxygen barrier films were formed on poly(ethylene terephthalate) (PET) substrate by a sol-gel process using aminoalkoxysilanes. The coating layers were characterized by FT-IR and SEM. The oxygen permeability coefficients of coating films were measured by variable volume method, and then the influences of solvent ratio in sol and film drying temperature on the oxygen barrier properties were investigated. The aminoalkoxysilane coating films exhibited much higher oxygen barrier properties than PET film. The oxygen permeability coefficient of the film coated with each of APTEOS and APTMOS was measured to be $2.96{\times}10^{-6}$ and $3.05{\times}10^{-5}\;GPU$, respectively, while that of PET film was $1.16{\times}10^{-4}\;GPU$.

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The Effect of Multi-lamellar Emulsion (MLE) on Skin Barrier Function: Can an Improve Permeability Barrier Provide a Solution for Itching due to Skin Barrier Malfunction\ulcorner

  • Youm, Jong-kyung;Kim, Yang-hee;Park, Byeong-deog;Jeong, Se-kyoo;Park, Eung-ho;Ahn, Sung-ku;Lee, Seung-hun
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.765-779
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    • 2003
  • Physiological lipid mixtures comprised of cholesterol, ceramide and free fatty acid better maintain epidermal homeostasis and have been recently used for dermatoses induced by skin barrier damage, for example for atopic dermatitis and xerotic skin. Itching and dry atopic dermatitis of the skin may be related to altered skin barrier function. In a previous study, the use of multi-lamellar emulsion (MLE), which is a lipid mixtures containing cholesterol, pseudoceramide and free fatty acid, has been shown to accelerate the recovery of the epidermal permeability barrier. In this study, we assessed the efficacy of MLE compared with a currently used anti-itch moisturizer (AIM), the active ingredients of which are menthol and camphor, on barrier recovery after barrier disruption. To clarify the effect of MLE and AIM after acute barrier perturbation, we measured the relation between transepidermal water loss (TEWL) and the barrier recovery rate at 3, 6, 24, and 48 hours after tape stripping hairless mice and then observed changes in the stratum corneum (SC), including the intercellular lipid structure and secretion of lamellar bodies, by electron microscopy. MLE treated skin recover skin barrier function more rapidly, and AIM treated skin delayed barrier repair. Morphological changes in the epidermis, of MLE treated skin revealed well-conserved lipid multi-lamellar structures at 24 h after tape stripping, whereas AIM treated skin showed altered lamellar bilayers within the SC interstices at 48 h. In addition, MLE treated skin showed an increase in the number of LBs and in their secretions and a decrease in the number of SC layers versus AIM treated skin. These results suggest that MLE may accelerate the production of an epidermal permeability barrier in hairless mice by increasing the number and secretion of LB and improve the dryness and itch associated with an altered epidermal permeability barrier.

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Epidermal Homeostasis and Dry Skin Management (표피항상성과 건조피부의 관리)

  • Park, Chang-Seo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.1
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    • pp.1-8
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    • 2008
  • Epidermis is one of the most dynamic organs in the human body. Multiple layers of keratinocytes in the epidermis continuously undergo proliferation, differentiation, and desquamation cycles, which is the bases of maintaining the epidermal homeostasis. Epidermal homeostasis eventually leads to establish and maintain permeability barrier homeostasis, the most important function of the epidermis. The permeability barrier is located in the stratum corneum. Tightly coordinated regulations are required for the sustained normal barrier function. Extensive studies have established that several nuclear hormone liposensors, including peroxisome proliferator-activated receptor a PPARa, PPARb/d, PPARg and LXRs are expressed in keratinocyte. Activation of PPARs and LXRs could provide a mechanism to coordinate the formation of the corneocytes and extracellular lipid membranes that constitute the stratum corneum. Topical application of PPAR/LXR ligands to murine skin results in the increased expression of keratinocyte differentiation-related proteins, such as involucrin, loricrin, profilaggrin, and trans-glutaminase 1, which would stimulate cornified envelope formation. In conclusion, topical application of ligands or activators of PPAR/LXR as an epidermotherapy would be a promising option to deal dry skin conditions such as atopy.

Prediction of Gas Permeability by Molecular Simulation

  • Yoo, Jae ik;Jiang, Yufei;Kim, Jin Kuk
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.175-181
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    • 2019
  • The research and development of high-performance polymer materials with excellent gas barrier properties has gained considerable attention from the viewpoint of expanding their applications in various fields, including tire automobile parts and the polymer film industry. Natural rubber (NR) has been widely used as a rubber material in real-life, but its application is limited owing to its poor gas barrier properties. In this paper, we study the gas barrier properties of NR, epoxidized natural rubber (ENR), and their blend compositions by using molecular simulation. The results show that ENR-50 has superior oxygen barrier properties than those of NR. Moreover, the oxygen barrier properties of a blend of NR/ENR-50 improve with increasing volume fraction of ENR-50. The trend of improved oxygen barrier properties of NR, ENR-50, and their blend is in good agreement with experimental observations.

The permeability charateristic of Z-type sheet pile joints under water sealing conditions (Z형 강널말뚝의 오염물질 차단효과)

  • Hong, Seung-Seo;Lee, Yong-Soo;Chung, Ha-Ik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1283-1288
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    • 2009
  • In general steel sheet piles are used in the containment system, which are vertical barrier systems for waste disposal and landfill purposes, and roads in excavation for temporary structure. This paper presents case study of the use of an interlocking sheet pile for water and containment. Cut-off Z-type sheet pile joints are investigated to determine their permeability from the field test. Four different joint sealing materials are used in field test. The results showed joint permeability is significant time-dependent and joint-dependent. These are explored and conclusions on permeability characteristics of different sealants are noted. A case study gives a design example as well as suggestion on permeability and water tightness can be implemented in using the sheet pile barrier in civil and environment works. From the test results, the effective sealing programs of sheet pile interlocks are suggested.

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An assessment of the mechanical behavior of zeolite tuff used in permeable reactive barriers

  • Cevikbilen, Gokhan
    • Geomechanics and Engineering
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    • v.31 no.3
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    • pp.305-318
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    • 2022
  • Permeable reactive barriers used for groundwater treatment require proper estimation of the reactive material behavior regarding the emplacement method. This study evaluates the dry emplacement of zeolite (clinoptilolite) to be used as a reactive material in the barrier by carrying out several geotechnical laboratory tests. Dry zeolite samples, exhibited higher wetting-induced compression strains at the higher vertical stresses, up to 12% at 400 kN/m2. The swelling potential was observed to be limited with a 3.5 swell index and less than 1% free swelling strain. Direct shear tests revealed that inundation reduces the shear strength of a dry zeolite column by a maximum of 10%. Falling head permeability tests indicate decreasing permeability values with increasing the vertical effective stress. Regarding self-loading and inundation, the porosity along the zeolite column was calculated using a proposed 1D numerical model to predict the permeability with depth considering the laboratory tests. The calculated discharge efficiency was significantly decreased with depth and less than 2% relative to the top for barrier depths deeper than 20 m. Finally, the importance of directional dependence in the permeability of the zeolite medium for calibrating 2D finite element flow analysis was highlighted by bench-scale tests performed under 2D flow conditions.

Permeability Characteristics of Geosynthetics Vertical Barrier Connections for the Prevention of Contaminants Diffusion (오염물질 확산방지를 위한 토목섬유 연직차수벽 연결부의 투수성능 평가)

  • Park, Jeong Jun
    • Journal of the Society of Disaster Information
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    • v.18 no.1
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    • pp.1-9
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    • 2022
  • Purpose: In this study, we used hydrophilic waterstop used in geosynthetics vertical barrier system to evaluate the performance of impermeability under sealing conditions. Method: ASTM D5887 and ASTM D6766 were applied to determine the capability of the connection during the geosynthetics vertical barrier system. Hydrophilic waterstop was saturated in each solution and the weight, thickness, and volume changes were analyzed over elapsed time. Hydrophilic waterstop was installed at the geosynthetics vertical barrier system connection to evaluate the permeability characteristics. Results: As the expansion reaction time of hydrophilic waterstop increased relatively under saline conditions, the decrease in permeability also showed a smaller decrease in fresh water. Furthermore, the method of engagement of the geosynthetics vertical barrier system showed somewhat better performance of the impermeability due to the large pressure resistance caused by the roll joint type than interlock type. Conclusion: In urban pollutants, which can estimate the outflow of pollutants such as oil storage facilities and industrial complexes, proactive response technologies that can prevent the contaminant diffusion can significantly reduce the damage.