• Title/Summary/Keyword: percolation

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Nano-Scale Observation of Nanomaterials by In-Situ TEM and Ultrathin SiN Membrane Platform

  • An, Chi-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.657-657
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    • 2013
  • In-situ observations of nano-scale behavior of nanomaterials are very important to understand onthe nano-scale phenomena associated with phase change, atomic movement, electrical or optical properties, and even reactions which take place in gas or liquid phases. We have developed on the in-situ experimental technologies of nano-materials (nano-cluster, nanowire, carbon nanotube, and graphene, et al.) and their interactions (percolation of metal nanoclusters, inter-diffusion, metal contacts and phase changes in nanowire devices, formation of solid nano-pores, melting behavior of isolated nano-metal in a nano-cup, et al.) by nano-discovery membrane platform [1-4]. Between two microelectrodes on a silicon nitride membrane platform, electrical percolations of metal nano-clusters are observed with nano-structures of deposited clusters. Their in-situ monitoring can make percolation devices of different conductance, nanoclusters based memory devices, and surface plasmonic enhancement devices, et al. As basic evidence on the phase change memory, phase change behaviors of nanowire devices are observed at a nano-scale.

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Modelling of the Electrochemical Performance of Functionally Graded Fuel Cell Electrodes by Discrete Simulations

  • Schneider, L.C.R.;Martin, C.L.;Bultel, Y.;Kapelski, G.;Bouvard, D.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.916-917
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    • 2006
  • Solid Oxide Fuel Cell technology uses powder processes to produce electrodes with residual porosity by partially sintering a mixture of electronically and ionically conducting particles. We model porous fuel cell electrodes with 3D packings of monosized spherical particles. These packings are created by numerical sintering. Each particle-particle contact is characteristic for an ionic, electronic or electrochemical resistance. The numerical packing is then discretized into a resistor network which is solved by using Kirchhoff's current law to evaluate the electrode's electrochemical performance. We investigate in particular percolation effects in functionally graded electrodes as compared to other types of electrodes.

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Dielectric characteristics of PMMA-PZT coated Ni Composites (PMMA-PZT coated Ni 복합체의 유전특성)

  • Jeong, Won-Chae;Lee, Hee Young;Kim, Jeong-Joo;Im, Eun-Seop
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.349-349
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    • 2005
  • 수동소자를 PCB(Printed Circuit Board) 안으로 집적하기 위한 방법의 일환으로 polymer-metal, polymer-ceramic composite에 연구가 국내외 연구 국내외 연구기관에서 광범위하게 진행되고 있다. 본 연구에서는 polymer-metal-ceramic composite 에서 PZT-coated Ni의 volume fraction에 따른 유전율 변화에 대하여 조사하였다. 원료로는 PZT(52/48) solution. 니켈금속분말, PMMA(polymethyl methacrylate)를 사용하였다. 전기적 특성은 임피던스분석기를 이용하여 측정하였으며 mixing rule과 percolation theory를 이용하여 결과를 해석하였다.

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CONDUCTIVITY of a-C:H FILMS MODIFIED WITH Ag NANOCLUSTERS

  • Sarsembinov, Sh.Sh.;Mahmoud, F.A.;Prikhodko, O.Yu.;Ryaguzov, A.P.;Maksimova, S.Ya.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.403-404
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    • 2005
  • The conductivity of diamond like carbon films embedded with silver nanoclusters were investigated as a function of silver concentrations in the film. By increasing the concentration of silver in the film from 0 to 20 at% the conductivity varied from $10^{-13}$ to $10^2\;ohm^{-1}\;cm^{-1}$. The data have been discussed within the model of a dielectric matrix containing conductive inclusions. The conductivity data analysis using percolation theory has been showed that percolation threshold occurred at Ag percentage in the film $x_c$ =5 at %.

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Dielectric Characteristics of PMMA-Ni-PZT Composite (PMMA-Ni-PZT 복합체의 유전 특성)

  • Jung, Won-Chae;Lee, Hee-Young;Kim, Jeong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.343-343
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    • 2006
  • 집적회로기판의 소형화 추세에 따라 커패시터, 인덕터, 저항과 같은 수동소자를 PCB 기판내부에 임베딩하는 연구가 국내외에서 활발하게 진행되고 있다. 본 논문에서는 polymer-metal-ceramic의 3상 복합체 구조를 가지는 임베디드 커패시터에서 Bimodal PZT분말에 따른 유전 특성에 대하여 고찰하였다. 매트릭스를 형성하는 고분자 재료로는 PMMA(polymethyl methacrylate)를 사용하였으며, 충분히 혼합된 분말을 고온에서 프레싱하여 시편을 제조하였다. 유전특성은 임피던스분석기 및 LCZ 미터를 이용하여 측정하였으며, 실험결과는 혼합법칙과 Percolation 이론을 이용하여 해석하였다.

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Study on the Electrical Conductivity in Polysiloxane/Metal Composite Containing Metal Oxide (금속산화물을 포함한 변성폴리실록산/금속 복합체의 전기 전도성 연구)

  • Im, Hyungu;Kim, Jooheon
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.307-312
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    • 2009
  • The block-co-polymer type thermosetting polysiloxane coordinated with metal oxide was synthesized to investigate the effect of metal oxide on the dispersity of metal powder in the polysiloxane/metal composite material. The metal powder in the polysiloxane/metal composite materials is better dispersed with metal oxide complex polysiloxane than the case without metal oxide. To understand the effect of quantities of metal oxide on the polysiloxane chain, the various polysiloxanes with different ratios of block unit were synthesized. Electrical conductivity was interpreted by percolation threshold theory to understand the dispersity of dense composite. The behavior of conductivity was in good agreement with theoretical value. The critical value was decreased as the quantities of metal oxide are increased. As a result, as the metal oxide increased on the polymer chain, the dispersity of metal filler was increased.

Percolation Analysis On Porous Concrete Using Microstructural CT Image Processing and Probability Distribution Functions (투수 콘크리트의 미세구조 CT 이미지와 확률 분포 함수를 사용한 투수성 분석)

  • Chung, Sang-Yeop;Han, Tong-Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1A
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    • pp.31-37
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    • 2012
  • The phase distribution in concrete materials strongly affects its material properties. It is important to identify the spatial distribution of void in concrete because the void in concrete materials affects mechanical behavior and permeability significantly. Therefore, a proper method to describe the void distribution of a material is needed. In this research, CT(computed tomography) is used to examine and to quantify the void distribution of porous concrete specimens. 3D concrete digital specimens are created by subsequent stacking of 2D cross-sectional images from CT. Then, probability distribution functions such as two-point correlation, lineal-path and two-point cluster functions are used for void distribution characterization. It is confirmed that probability distribution functions obtained from CT images are effective in characterizing void distributions including the anisotropy and percolation.